Chapter 17: Problem 22
A chemist prepares dilute solutions of equal molar concentrations of \(\mathrm{NH}_{3}, \mathrm{NH}_{4} \mathrm{Br}, \mathrm{NaF}\), and \(\mathrm{NaCl}\). Rank these solutions from highest \(\mathrm{pH}\) to lowest \(\mathrm{pH}\).
Short Answer
Expert verified
Order is: \(\text{NH}_3\), \(\text{NaF}\), \(\text{NaCl}\), \(\text{NH}_4\text{Br}\).
Step by step solution
01
Understand the substances
The substances involved are \(\text{NH}_3\), an ammonia solution known as a weak base; \(\text{NH}_4\text{Br}\), an ammonium bromide that acts mainly as a source of \(\text{NH}_4^+\), a weak acid; \(\text{NaF}\), which releases \(\text{F}^-\), a weak base; and \(\text{NaCl}\), a neutral salt.
02
Determine Acid-Base Characteristics
\(\text{NH}_3\) is a weak base, which means it has a \(\text{pH}\) greater than 7. \(\text{NH}_4^+\) from \(\text{NH}_4\text{Br}\) will slightly increase acidity, so \(\text{NH}_4\text{Br}\) is mildly acidic. \(\text{NaF}\) dissociates into \(\text{F}^-\), which slightly raises the \(\text{pH}\) as a weak base. \(\text{NaCl}\) contains \(\text{Na}^+\) and \(\text{Cl}^-\), neither of which affect \(\text{pH}\), making it neutral.
03
Rank the solutions based on pH
Based on their nature, rank the solutions from highest \(\text{pH}\) to lowest. \(\text{NH}_3\) should have the highest \(\text{pH}\) due to its basic nature, followed by \(\text{NaF}\), which is a weak base. \(\text{NaCl}\) comes next as it is a neutral salt, and \(\text{NH}_4\text{Br}\) will have the lowest \(\text{pH}\) due to the presence of the acidic \(\text{NH}_4^+\).
04
Final pH Order
From highest to lowest \(\text{pH}\), the order is: \(\text{NH}_3\), \(\text{NaF}\), \(\text{NaCl}\), \(\text{NH}_4\text{Br}\). \(\text{NH}_3\) is the most basic, \(\text{NaF}\) is slightly basic, \(\text{NaCl}\) is neutral, and \(\text{NH}_4\text{Br}\) is acidic.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Acid-Base Characteristics
When discussing the pH of a solution, it is important to consider the acid-base characteristics of the components involved. The pH scale measures how acidic or basic a solution is, with values ranging from 0 to 14. A pH less than 7 indicates acidity, a pH of 7 is neutral, and a pH greater than 7 indicates basicity.
Understanding the nature of the substances helps predict their effect on pH:
Understanding the nature of the substances helps predict their effect on pH:
- Weak Acids: These partially dissociate in water, contributing to a lower pH. Ammonium ion \(\text{NH}_4^+\) is an example, as it releases \(\text{H}^+\) ions, increasing the solution's acidity.
- Weak Bases: These do not fully dissociate and slightly increase the pH. Substances like ammonia \(\text{NH}_3\) and fluoride ion \(\text{F}^-\) fall into this category, as they can accept protons, resulting in a more basic solution.
- Neutral Salts: Compounds made from neutral ions, such as \(\text{NaCl}\), have no significant impact on pH, remaining around 7.
Weak Bases and Acids
Weak bases and acids are common in chemistry and play a critical role in predicting the behavior of solutions. A weak base only partially accepts protons, which makes them less effective than strong bases like \(\text{NaOH}\). For example, ammonia \(\text{NH}_3\) acts as a weak base when dissolved in water because it does not completely ionize.
Similarly, fluoride ions \(\text{F}^-\), originating from \(\text{NaF}\), also function as a weak base because they slightly increase the pH by accepting protons to form hydrogen fluoride \(\text{HF}\).
On the other hand, weak acids like the ammonium ion \(\text{NH}_4^+\) partially dissociate in water, meaning they do not completely release \(\text{H}^+\) ions. This results in a less acidic solution compared to strong acids like hydrochloric acid \(\text{HCl}\). However, the presence of even weak acids can influence the overall acidity of a solution.
Similarly, fluoride ions \(\text{F}^-\), originating from \(\text{NaF}\), also function as a weak base because they slightly increase the pH by accepting protons to form hydrogen fluoride \(\text{HF}\).
On the other hand, weak acids like the ammonium ion \(\text{NH}_4^+\) partially dissociate in water, meaning they do not completely release \(\text{H}^+\) ions. This results in a less acidic solution compared to strong acids like hydrochloric acid \(\text{HCl}\). However, the presence of even weak acids can influence the overall acidity of a solution.
- Ammonium Ion (\(\text{NH}_4^+\)): Slightly acidic, releases \(\text{H}^+\) ions, lowering the pH of the solution.
- Fluoride Ion (\(\text{F}^-\)): A weak base, increases pH slightly by accepting \(\text{H}^+\) ions.
- Ammonia (\(\text{NH}_3\)): Acts as a weak base, increasing pH by accepting protons from the solution.
Neutral Salts
Neutral salts, such as sodium chloride \(\text{NaCl}\), play a distinctive role in chemistry as they do not affect the acidity or basicity of a solution. These salts are formed when a strong acid reacts with a strong base, resulting in ions that neither donate nor accept protons.
For instance, in the case of \(\text{NaCl}\), sodium ions \(\text{Na}^+\) and chloride ions \(\text{Cl}^-\) do not alter the water's pH, maintaining it at a neutral level of around 7.
Understanding neutral salts is useful for chemical assessments where pH constancy is necessary. They are generally formed from:
For instance, in the case of \(\text{NaCl}\), sodium ions \(\text{Na}^+\) and chloride ions \(\text{Cl}^-\) do not alter the water's pH, maintaining it at a neutral level of around 7.
Understanding neutral salts is useful for chemical assessments where pH constancy is necessary. They are generally formed from:
- Strong Acids and Strong Bases: Their typical reactions lead to the formation of neutral salts, as the ions produced do not react further with water.
- Sodium Chloride (\(\text{NaCl}\)): A classic example, resulting from the reaction between hydrochloric acid \(\text{HCl}\) and sodium hydroxide \(\text{NaOH}\).