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You make solutions of ammonia and sodium hydroxide by adding the same moles of each solute to equal volumes of water. Which solution would you expect to have the higher \(\mathrm{pH}\) ?

Short Answer

Expert verified
Sodium hydroxide solution will have a higher pH.

Step by step solution

01

Understanding the Problem

We need to determine which solution will have a higher pH when given equal moles of ammonia (NH鈧) and sodium hydroxide (NaOH) are added to equal volumes of water.
02

Identify Nature of Compounds

Ammonia is a weak base and sodium hydroxide is a strong base. This categorization will play a crucial role in determining the pH of their solutions.
03

Effect of Weak vs Strong Base

A weak base, like ammonia, partially ionizes in water to produce hydroxide ions, whereas a strong base, like sodium hydroxide, fully ionizes in water, generating more hydroxide ions per mole of solute.
04

Calculate Expected pH Change

Since NaOH fully ionizes, it will contribute more \([OH^-]\) ions to the solution than NH鈧 under the same conditions, resulting in a higher pH for the NaOH solution.
05

Conclusion

The solution of sodium hydroxide will have a higher pH compared to the solution of ammonia due to its nature as a strong base.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Strong vs Weak Base
In chemistry, the classification of bases as "strong" or "weak" is essential when predicting how a solution will behave. A strong base, such as sodium hydroxide (NaOH), dissociates completely in water. This means that it breaks down fully into its ions, releasing hydroxide ions (OH鈦) into the solution. On the other hand, a weak base like ammonia (NH鈧) only partially disassociates in water. This means that only a fraction of the ammonia molecules will release hydroxide ions when dissolved.

The degree of ionization affects the pH of the resulting solution. The more hydroxide ions present, the higher the pH and thus the more basic the solution. Because sodium hydroxide completely ionizes, it contributes a larger number of OH鈦 ions to the solution, making it more basic compared to an equal concentration of ammonia, which only partially releases OH鈦 ions. Therefore, understanding the strength of a base is key to predicting the pH of its solution.
Hydroxide Ion Concentration
Hydroxide ion concentration is a critical factor in determining the pH of a solution. The pH is a measure of how acidic or basic a solution is, with higher pH values indicating a more basic solution.

For bases, the presence of hydroxide ions (OH鈦) plays a significant role. In a strong base like sodium hydroxide, the complete ionization leads to a high concentration of OH鈦 ions. To give an idea of the effect, the equation \[ \text{NaOH (aq)} \to \text{Na}^+ (aq) + \text{OH}^- (aq) \] illustrates that each mole of sodium hydroxide produces one mole of hydroxide ions.

In contrast, with a weak base like ammonia, the equation looks like this:
\[ \text{NH}_3 (aq) + \text{H}_2\text{O} (l) \rightleftharpoons \text{NH}_4^+ (aq) + \text{OH}^- (aq) \]Ammonia does not ionize completely, thus fewer OH鈦 ions are released. As a result, the hydroxide ion concentration, and hence the pH of the solution, is lower for ammonia compared to sodium hydroxide, given the same initial conditions.
Solution Ionization
Solution ionization refers to the process where molecules dissolve in a solvent, typically water, and form ions. This process is especially important for predicting the behavior of acid and base solutions.

A strong base like sodium hydroxide undergoes complete ionization. This means as soon as it is dissolved in water, it separates entirely into sodium ions (Na鈦) and hydroxide ions (OH鈦). This complete dissociation results in a significant increase in hydroxide ions in the solution, leading to a high pH.
In contrast, the weak base ammonia only partially ionizes. When ammonia is added to water, some molecules form ions, but many molecules remain in their original form. The equilibrium is established where the formation and dissociation occur simultaneously but not to completion. This partial ionization determines the degree of basicity for weak bases.

Hence, examining how thoroughly a solution ionizes gives a clear understanding of the potential basicity of a solution. Strong bases create more complete ionization, increasing OH鈦 concentration, while weak bases only slightly alter the hydroxide ion concentration due to limited ionization.

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Most popular questions from this chapter

Obtain the \(\mathrm{pH}\) corresponding to the following hydronium-ion concentrations. a. \(1.0 \times 10^{-8} M\) b. \(5.0 \times 10^{-12} M\) c. \(7.5 \times 10^{-3} M\) d. \(6.35 \times 10^{-9} M\)

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Give the conjugate acid to each of the following species regarded as bases. a. \(\mathrm{ClO}^{-}\) b. \(\mathrm{AsH}_{3}\) c. \(\mathrm{H}_{2} \mathrm{PO}_{4}^{-}\) c. \(\mathrm{TeO}_{3}^{2-}\)

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