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Maltose, \(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\), is a sugar produced by malting (sprouting) grain. A solution of maltose at \(25^{\circ} \mathrm{C}\) has an osmotic pressure of \(5.50 \mathrm{~atm}\). What is the molar concentration of maltose?

Short Answer

Expert verified
The molar concentration of maltose is approximately 0.225 M.

Step by step solution

01

Understand Osmotic Pressure Formula

Osmotic pressure can be calculated using the formula \( \Pi = iMRT \), where \( \Pi \) is the osmotic pressure, \( i \) is the van 't Hoff factor (which is 1 for non-electrolytes like maltose), \( M \) is the molar concentration, \( R \) is the gas constant (0.0821 L·atm/mol·K), and \( T \) is the temperature in Kelvin.
02

Convert Temperature to Kelvin

Since the temperature given is \(25^{\circ} C \), convert it to Kelvin by adding 273.15. Thus, \( T = 25 + 273.15 = 298.15 \text{ K} \).
03

Rearrange Formula to Find Molar Concentration

Rearrange the formula to solve for molar concentration \( M \): \( M = \frac{\Pi}{iRT} \).
04

Substitute the Known Values

Substitute the known values into the formula: \( M = \frac{5.50 \text{ atm}}{1 \times 0.0821 \text{ L·atm/mol·K} \times 298.15 \text{ K}} \).
05

Calculate the Molar Concentration

Perform the calculation: \( M = \frac{5.50}{24.455815} \approx 0.22494 \). Therefore, the molar concentration of maltose is approximately \( 0.225 \text{ M} \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molar Concentration
Molar concentration is a measure of the amount of solute present in a solution per unit volume. It is often expressed in moles per liter (mol/L) and is a crucial concept in chemistry.

When dealing with solutions like maltose in water, knowing the molar concentration helps to understand how much of the sugar is present in the given volume of liquid. This is especially important in applications like food sciences and chemical reactions where precise measurements can impact outcomes.

To find the molar concentration, the formula for osmotic pressure, \( \Pi = iMRT \), is rearranged to solve for \( M \) (molarity). The molarity is the unknown variable found by using the known values of osmotic pressure, gas constant, van 't Hoff factor, and temperature in Kelvin.
van 't Hoff factor
The van 't Hoff factor, denoted as \( i \), is a crucial part of the osmotic pressure formula. It accounts for the number of particles the solute dissociates into when in solution.

For non-electrolytes like maltose, the van 't Hoff factor is typically 1, meaning that the solute does not dissociate when dissolved. In contrast, electrolytes can have higher values of \( i \) due to the dissociation of compounds in the solution, which increases the number of particles.

Understanding the van ‘t Hoff factor is vital for calculating accurate solution properties, especially when dealing with osmotic pressure. If the factor is miscalculated, the entire calculation could be off, affecting experimental results and theoretical predictions.
Temperature Conversion
Temperature conversion is essential in chemistry calculations because different formulas may require temperature in different units.

In this exercise, temperature needed to be converted from Celsius to Kelvin. The Kelvin scale is an absolute temperature scale used in scientific calculations and conversions. To convert from Celsius to Kelvin, you simply add 273.15 to the Celsius temperature.

The conversion in this problem was straightforward: from \(25^{\circ} C\) to Kelvin, resulting in 298.15 K. This step is essential since the gas constant used has units compatible with Kelvin, which ensures all calculations are done correctly.
Gas Constant
The gas constant \( R \) is a fundamental constant in chemistry that appears in various equations involving gases. In this context, \( R \) is used in the formula for osmotic pressure and is given as 0.0821 L·atm/mol·K.

This value allows for the integration of units relating to pressure, volume, and temperature in calculations. The proper use of \( R \) ensures that the units involving pressure (atm), volume (L), and temperature (K) are consistent, which is crucial in avoiding errors during the calculation.

The value of \( R \) can vary based on the units employed. However, it is crucial to match \( R \) units with those being used in the problem to maintain accuracy and consistency throughout the calculation process.

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