Chapter 9: Problem 90
The amide ion, \(\mathrm{NH}_{2}^{-}\), is a Brønsted base. Represent the reaction between the amide ion and water in terms of Lewis structures.
Short Answer
Expert verified
The reaction is \(\mathrm{NH}_2^{-} + \mathrm{H}_2\mathrm{O} \rightarrow \mathrm{NH}_3 + \mathrm{OH}^-\).
Step by step solution
01
Understand the Reactants
The amide ion, \(\mathrm{NH}_2^{-}\), functions as a Brønsted base, meaning it can accept a proton (\(\mathrm{H}^+\)). Water, \(\mathrm{H}_2\mathrm{O}\), can donate a proton, making it a Brønsted acid in this reaction.
02
Draw Lewis Structures of Reactants
Draw the Lewis structure of the amide ion, \(\mathrm{NH}_2^{-}\): it has two hydrogen atoms bonded to a nitrogen atom. The nitrogen atom has one lone pair and a negative charge. For water, \(\mathrm{H}_2\mathrm{O}\), draw two hydrogen atoms bonded to an oxygen atom, which has two lone pairs.
03
Identify Proton Transfer
In the reaction, the lone pair on the nitrogen in \(\mathrm{NH}_2^{-}\) will attack the hydrogen atom of one of the \(\mathrm{H}-\)O bonds in water. This represents the proton being transferred from \(\mathrm{H}_2\mathrm{O}\) to \(\mathrm{NH}_2^{-}\).
04
Draw Lewis Structures of Products
The proton (\(\mathrm{H}^+\)) attaches to the nitrogen in \(\mathrm{NH}_2^{-}\), forming \(\mathrm{NH}_3\) (ammonia), which has a trigonal pyramidal shape without any charge. Water, after losing a hydrogen, becomes hydroxide (\(\mathrm{OH}^-\)), represented by an oxygen bonded to a hydrogen atom with three lone pairs and a negative charge.
05
Complete the Reaction Equation
Combine the reactants and products to complete the equation: \(\mathrm{NH}_2^{-} + \mathrm{H}_2\mathrm{O} \rightarrow \mathrm{NH}_3 + \mathrm{OH}^-\). This equation illustrates how the \(\mathrm{NH}_2^{-}\) accepts a proton from water, resulting in the formation of ammonia and hydroxide ion.
Unlock Step-by-Step Solutions & Ace Your Exams!
-
Full Textbook Solutions
Get detailed explanations and key concepts
-
Unlimited Al creation
Al flashcards, explanations, exams and more...
-
Ads-free access
To over 500 millions flashcards
-
Money-back guarantee
We refund you if you fail your exam.
Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!
Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Brønsted Acid
In chemistry, a Brønsted acid is a substance that can donate a proton (\(\mathrm{H}^+\)) to another substance. Named after Johannes Brønsted, this concept is central to understanding how acids behave in various chemical reactions.
In the example of the amide ion reaction, water (\(\mathrm{H}_2\mathrm{O}\)) acts as a Brønsted acid. This means that water donates a hydrogen ion to the amide ion.
In the example of the amide ion reaction, water (\(\mathrm{H}_2\mathrm{O}\)) acts as a Brønsted acid. This means that water donates a hydrogen ion to the amide ion.
- This causes one of its hydrogen atoms to be transferred from the oxygen, where it forms a \(\mathrm{O-H}\) bond, to the nitrogen in the \(\mathrm{NH}_2^-\) ion.
Brønsted Base
Conversely, a Brønsted base is a compound that readily accepts a proton. In our scenario, the amide ion (\(\mathrm{NH}_2^-\)) assumes this role. When acting as a base, \(\mathrm{NH}_2^-\) has an additional pair of electrons situated on the nitrogen atom that allows it to accept a hydrogen ion.
This willingness to accept a proton makes \(\mathrm{NH}_2^-\) an excellent Brønsted base. By acquiring a proton from water, it transforms into ammonia (\(\mathrm{NH}_3\)). This transaction exemplifies how a Brønsted base behaves during chemical reactions and highlights the # Characteristics of a Brønsted Base:
This willingness to accept a proton makes \(\mathrm{NH}_2^-\) an excellent Brønsted base. By acquiring a proton from water, it transforms into ammonia (\(\mathrm{NH}_3\)). This transaction exemplifies how a Brønsted base behaves during chemical reactions and highlights the # Characteristics of a Brønsted Base:
- Proton acceptance ability
- Presence of a lone electron pair
Proton Transfer
Proton transfer is the process by which a hydrogen ion (\(\mathrm{H}^+\)) migrates from one molecule to another during a chemical reaction. This fundamental mechanism is observed in many interactions, including acid-base reactions.
In the case of the amide ion and water, the proton moves from the \(\mathrm{H}_2\mathrm{O}\) molecule to the \(\mathrm{NH}_2^-\) ion. Here is how it happens:
In the case of the amide ion and water, the proton moves from the \(\mathrm{H}_2\mathrm{O}\) molecule to the \(\mathrm{NH}_2^-\) ion. Here is how it happens:
- The lone pair of electrons on the nitrogen atom in \(\mathrm{NH}_2^-\) reaches out and forms a bond with a hydrogen atom from water.
- This transfer substantially alters the chemical structure of the reactants, resulting in new compounds: ammonia and hydroxide ion.
Amide Ion
The amide ion (\(\mathrm{NH}_2^-\)) is a negatively charged species commonly involved in various chemical reactions due to its capability to act as a strong base. Composed of two hydrogen atoms bonded to a nitrogen atom, its structure is critical to its properties:
- The nitrogen in \(\mathrm{NH}_2^-\) holds a lone pair of electrons, endowing the ion with a negative charge.
- This lone pair is responsible for its role as a Brønsted base because it can readily accept a hydrogen ion (proton).
- It neutralizes acids by accepting their protons.
- Turns into a neutral ammonia molecule (\(\mathrm{NH}_3\)).