Chapter 7: Problem 84
Write the ground-state electron configurations for the following elements: Ge, Fe, \(\mathrm{Zn}\), \(\mathrm{Ni}\), \(\mathrm{W}, \mathrm{Tl}\).
Short Answer
Expert verified
Ge: [Ar] 3d鹿鈦 4s虏 4p虏; Fe: [Ar] 3d鈦 4s虏; Zn: [Ar] 3d鹿鈦 4s虏; Ni: [Ar] 3d鈦 4s虏; W: [Xe] 4f鹿鈦 5d鈦 6s虏; Tl: [Xe] 4f鹿鈦 5d鹿鈦 6s虏 6p鹿.
Step by step solution
01
Understanding Electron Configuration
Electron configurations describe the distribution of electrons in an atom. We refer to the periodic table to determine the number of electrons in an element, as this corresponds to its atomic number. The arrangement typically follows the order dictated by filling orbitals in the sequence of increasing atomic number.
02
Element Ge (Germanium)
Germanium has an atomic number of 32. Its electron configuration can be filled using the Aufbau principle as follows: start from 1s and progress through each subshell - 1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鹿鈦 4p虏.
03
Element Fe (Iron)
Iron has an atomic number of 26. Its configuration starts with 1s虏 and proceeds to fill up in the following order: 1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鈦
04
Element Zn (Zinc)
Zinc has an atomic number of 30. Its electron arrangement is completed as follows: 1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鹿鈦.
05
Element Ni (Nickel)
Nickel has an atomic number of 28. The electron configuration is filled in the order: 1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鈦.
06
Element W (Tungsten)
Tungsten has an atomic number of 74, giving it a configuration as follows: 1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鹿鈦 4p鈦 5s虏 4d鹿鈦 5p鈦 6s虏 4f鹿鈦 5d鈦.
07
Element Tl (Thallium)
Thallium has an atomic number of 81. The electron configuration is: 1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鹿鈦 4p鈦 5s虏 4d鹿鈦 5p鈦 6s虏 4f鹿鈦 5d鹿鈦 6p鹿.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Aufbau Principle
The Aufbau Principle is fundamental for understanding how electrons are arranged in an atom's electron configuration. The term "Aufbau" is German for "building up", reflecting the idea of filling electron orbitals from the lowest energy level to higher ones. This principle helps us determine the order in which electrons fill the atomic orbitals, starting with the 1s orbital, followed by the 2s, 2p, 3s, 3p, and so on.
The electronic configuration is written in a sequence where each level is filled before moving to the next higher energy level:
The electronic configuration is written in a sequence where each level is filled before moving to the next higher energy level:
- The 1s orbital is filled first, followed by the 2s orbital.
- The 2p orbitals come next, followed by 3s, and so forth.
- This filling order continues until all of the atom's electrons are accounted for.
Atomic Number
The atomic number is a fundamental property of an element. It represents the number of protons in an atom's nucleus, and thus defines the element itself. In a neutral atom, the atomic number is also equal to the number of electrons. This is crucial because the electron configuration of an atom is determined based on its atomic number.
For example, for the element iron (Fe), the atomic number is 26. This means an iron atom has 26 electrons. These electrons will be arranged following the Aufbau principle and fill each available orbital up to the 26th electron.
For example, for the element iron (Fe), the atomic number is 26. This means an iron atom has 26 electrons. These electrons will be arranged following the Aufbau principle and fill each available orbital up to the 26th electron.
- The atomic number essentially dictates the electron arrangement.
- It is the most basic classification for organizing elements on the periodic table.
Ground-state Electron Configuration
The ground-state electron configuration describes the lowest energy arrangement of electrons in an atom. This configuration is critical for understanding an element's behavior in chemical reactions and reactivity.
To determine the ground-state electron configuration:
To determine the ground-state electron configuration:
- Start with the atomic number, which tells you how many electrons you have.
- Utilize the Aufbau principle to arrange these electrons in the lowest energy levels first.
- Write the configuration in a sequence, indicating which subshells are filled.
Periodic Table
The periodic table is an organized chart of elements. It is a powerful tool in chemistry, arranging elements in a manner that highlights patterns in properties such as electron configurations.
Key features of the periodic table:
Key features of the periodic table:
- Elements are arranged in order of increasing atomic number.
- Vertical columns, known as groups, contain elements that have similar chemical properties.
- Horizontal rows, called periods, follow the progression of electron configurations.