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A quantity of gas weighing \(7.10 \mathrm{~g}\) at 741 torr and \(44^{\circ} \mathrm{C}\) occupies a volume of \(5.40 \mathrm{~L}\). What is its molar mass?

Short Answer

Expert verified
The molar mass of the gas is approximately 47 g/mol.

Step by step solution

01

Understand the problem

To solve this problem, we need to find the molar mass of a gas given its weight, pressure, temperature, and volume. We'll use the ideal gas law, which is \( PV = nRT \), where \( P \) is pressure, \( V \) is volume, \( n \) is the number of moles, \( R \) is the ideal gas constant, and \( T \) is temperature in Kelvin.
02

Convert values to the appropriate units

Convert the pressure from torr to atmospheres because the ideal gas constant \( R \) is usually given as \(0.0821 \ \mathrm{L} \cdot \mathrm{atm}/\mathrm{mol} \cdot \mathrm{K} \). \( 741 \ \mathrm{torr} = \frac{741}{760} \ \mathrm{atm} \approx 0.975 \ \mathrm{atm} \). For temperature, convert the Celsius to Kelvin: \( T = 44 + 273.15 = 317.15 \ \mathrm{K} \). The volume is already in liters and the mass is in grams, so they are already in the correct units.
03

Use the ideal gas law to find moles

Rearrange the ideal gas law to solve for \( n \), the number of moles: \[ n = \frac{PV}{RT} \]. Substitute the known values into the equation: \[ n = \frac{(0.975 \ \mathrm{atm}) \times (5.40 \ \mathrm{L})}{(0.0821 \ \mathrm{L} \cdot \mathrm{atm}/\mathrm{mol} \cdot \mathrm{K}) \times (317.15 \ \mathrm{K})} \]. Calculate \( n \).
04

Find the molar mass

Calculate the moles from the previous step. Let's denote the moles as \( n \). The molar mass \( M \) is calculated by the formula \( M = \frac{\text{mass}}{\text{moles}} \) where the mass is \( 7.10 \ \mathrm{g} \). Substitute \( n \) and calculate \( M \): \( M = \frac{7.10 \ \mathrm{g}}{n} \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molar Mass Calculation
Calculating the molar mass of a gas is a crucial aspect when dealing with gas properties. The molar mass is the measure of the mass of one mole of a substance. For gases, you can find the molar mass using the relationship between mass, moles, and the given mass of the gas. Look at it this way: you already have the mass of the gas given as 7.10 grams, and by using the ideal gas law, you can calculate the number of moles of the gas.
Once you have the number of moles, the formula for molar mass is as follows:
  • Molar Mass (M) = \( \frac{\text{mass}}{\text{moles}} \)
This is a ratio where the mass is divided by moles, derived from the ideal gas law calculations. This quick calculation helps in converting the physical attributes of the gas into a more usable form in molecular chemistry.
Pressure Conversion
Pressure conversion is necessary when solving problems related to gases because different pressure units can be used, like torr, atmospheres, pascals, etc. The ideal gas law equation uses atmospheres as the standard unit for pressure.
The given problem has the pressure in torr (741 torr). To convert torr to atmospheres, you use the conversion factor where 1 atm = 760 torr. Thus:
  • Pressure in atm = \( \frac{741 \ \text{torr}}{760 \ \text{torr/atm}} \approx 0.975 \ \text{atm} \)
Converting these units ensures that the other constants and units in the ideal gas law equation align correctly, so your calculations are accurate and meaningful.
Temperature Conversion
Temperature needs to be accurately converted when dealing with gas laws, specifically the ideal gas law. The ideal gas law requires Kelvin as the temperature unit because it's an absolute temperature scale, avoiding any negative values which are present in Celsius.
In the problem, the temperature is provided as 44°C, which needs conversion. The conversion formula from Celsius to Kelvin is:
  • Temperature in Kelvin = Celsius + 273.15
Therefore:
  • Temperature in Kelvin = 44 + 273.15 = 317.15 K
Using Kelvin ensures that the ideal gas law behaves consistently across various conditions, which is critical for understanding the behavior of gases.
Moles Calculation
To find how many moles of gas are present, which is denoted by \( n \), you rearrange the ideal gas law equation, which is\( PV = nRT \).
This rearrangement becomes \( n = \frac{PV}{RT} \).
For our problem:
  • \( P = 0.975 \ \text{atm} \)
  • \( V = 5.40 \ \text{L} \)
  • \( R = 0.0821 \ \text{L atm/mol K} \)
  • \( T = 317.15 \ \text{K} \)
Substituting into the formula:
  • \( n = \frac{0.975 \times 5.40}{0.0821 \times 317.15} \)
Perform this calculation to determine the moles of gas. This value is pivotal for further calculations, such as determining the molar mass, by linking physical attributes of the sample to its chemical properties.

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Most popular questions from this chapter

A mixture of gases contains \(\mathrm{CH}_{4}, \mathrm{C}_{2} \mathrm{H}_{6},\) and \(\mathrm{C}_{3} \mathrm{H}_{8} .\) If the total pressure is \(1.50 \mathrm{~atm}\) and the numbers of moles of the gases present are 0.31 mole for \(\mathrm{CH}_{4}\), 0.25 mole for \(\mathrm{C}_{2} \mathrm{H}_{6}\), and 0.29 mole for \(\mathrm{C}_{3} \mathrm{H}_{8}\), calculate the partial pressures of the gases.

Describe how a barometer and a manometer are used to measure gas pressure.

Explain why a helium weather balloon expands as it rises in the air. Assume that the temperature remains constant

An ideal gas originally at \(0.85 \mathrm{~atm}\) and \(66^{\circ} \mathrm{C}\) was allowed to expand until its final volume, pressure, and temperature were \(94 \mathrm{~mL}, 0.60 \mathrm{~atm},\) and \(45^{\circ} \mathrm{C}\), respectively. What was its initial volume?

A stockroom supervisor measured the contents of a partially filled 25.0 -gallon acetone drum on a day when the temperature was \(18.0^{\circ} \mathrm{C}\) and atmospheric pressure was \(750 \mathrm{mmHg}\), and found that 15.4 gallons of the solvent remained. After tightly sealing the drum, an assistant dropped the drum while carrying it upstairs to the organic laboratory. The drum was dented and its internal volume was decreased to 20.4 gallons. What is the total pressure inside the drum after the accident? The vapor pressure of acetone at \(18.0^{\circ} \mathrm{C}\) is \(400 \mathrm{mmHg}\). (Hint: At the time the drum was sealed, the pressure inside the drum, which is equal to the sum of the pressures of air and acetone, was equal to the atmospheric pressure.)

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