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For the complete redox reactions given here, (i) break down each reaction into its half-reactions; (ii) identify the oxidizing agent; (iii) identify the reducing agent. (a) \(2 \mathrm{Sr}+\mathrm{O}_{2} \longrightarrow 2 \mathrm{SrO}\) (b) \(2 \mathrm{Li}+\mathrm{H}_{2} \longrightarrow 2 \mathrm{LiH}\) (c) \(2 \mathrm{Cs}+\mathrm{Br}_{2} \longrightarrow 2 \mathrm{CsBr}\) (d) \(3 \mathrm{Mg}+\mathrm{N}_{2} \longrightarrow \mathrm{Mg}_{3} \mathrm{~N}_{2}\)

Short Answer

Expert verified
(a) SrO: agent Sr; agent O2. (b) LiH: agent Li; agent H2. (c) CsBr: agent Cs; agent Br2. (d) Mg_3N_2: agent Mg; agent N2.

Step by step solution

01

Understand the Redox Process

In a redox reaction, oxidation and reduction occur simultaneously. Oxidation refers to the loss of electrons, while reduction refers to the gain of electrons. Thus, we need to identify which species is oxidized and which is reduced in each reaction.
02

Identify the Half-reactions

For each reaction, determine the oxidation and reduction halves by identifying which species lose and gain electrons:(a) \(2 \mathrm{Sr} + \mathrm{O_2} \rightarrow 2 \mathrm{SrO}\)- Oxidation half-reaction: \(\mathrm{Sr} \rightarrow \mathrm{Sr^{2+}} + 2e^-\)- Reduction half-reaction: \(\mathrm{O_2} + 4e^- \rightarrow 2\mathrm{O^{2-}}\)(b) \(2 \mathrm{Li} + \mathrm{H_2} \rightarrow 2 \mathrm{LiH}\)- Oxidation half-reaction: \(\mathrm{Li} \rightarrow \mathrm{Li^+} + e^-\)- Reduction half-reaction: \(\mathrm{H_2} + 2e^- \rightarrow 2\mathrm{H^-}\)(c) \(2 \mathrm{Cs} + \mathrm{Br_2} \rightarrow 2 \mathrm{CsBr}\)- Oxidation half-reaction: \(\mathrm{Cs} \rightarrow \mathrm{Cs^+} + e^-\)- Reduction half-reaction: \(\mathrm{Br_2} + 2e^- \rightarrow 2\mathrm{Br^-}\)(d) \(3 \mathrm{Mg} + \mathrm{N_2} \rightarrow \mathrm{Mg_3 N_2}\)- Oxidation half-reaction: \(\mathrm{Mg} \rightarrow \mathrm{Mg^{2+}} + 2e^-\)- Reduction half-reaction: \(\mathrm{N_2} + 6e^- \rightarrow 2\mathrm{N^{3-}}\).
03

Identify the Oxidizing Agent

The oxidizing agent is the substance that gets reduced by gaining electrons:(a) \(\mathrm{O_2}\) is reduced to \(\mathrm{O^{2-}}\), so it is the oxidizing agent.(b) \(\mathrm{H_2}\) is reduced to \(\mathrm{H^-}\), making it the oxidizing agent.(c) \(\mathrm{Br_2}\) is reduced to \(\mathrm{Br^-}\), thus it is the oxidizing agent.(d) \(\mathrm{N_2}\) is reduced to \(\mathrm{N^{3-}}\), which means it acts as the oxidizing agent.
04

Identify the Reducing Agent

The reducing agent is the substance that gets oxidized by losing electrons:(a) \(\mathrm{Sr}\) is oxidized to \(\mathrm{Sr^{2+}}\), so it is the reducing agent.(b) \(\mathrm{Li}\) loses electrons to form \(\mathrm{Li^+}\), thus it is the reducing agent.(c) \(\mathrm{Cs}\) is oxidized to \(\mathrm{Cs^+}\), making it the reducing agent.(d) \(\mathrm{Mg}\) transforms to \(\mathrm{Mg^{2+}}\), which means it is the reducing agent.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Oxidation and Reduction
In the realm of chemistry, oxidation and reduction are key processes, often occurring together in what are known as redox reactions. To understand these reactions fully, let's start with the basics:
Oxidation is the process where a compound or element loses electrons. When we say a substance is oxidized, it primarily undergoes a loss of electrons.
Reduction, on the other hand, is when a substance gains electrons. Thus, a reduced substance acquires more electrons.

In a redox reaction, both these processes happen simultaneously. As one substance gets oxidized, another gets reduced. For example, in the reaction \( 2 \mathrm{Sr} + \mathrm{O}_2 \rightarrow 2 \mathrm{SrO} \), \( \mathrm{Sr} \) is oxidized as it loses electrons, and \( \mathrm{O}_2 \) is reduced as it gains electrons.
To determine which substance is oxidized or reduced in a chemical reaction, look at the changes in oxidation states of the elements involved. If the oxidation state increases, the element is oxidized. If it decreases, the element is reduced. By keeping these principles in mind, identifying and understanding redox reactions becomes a much simpler task.
Half-Reactions
Half-reactions are a great tool to view the individual oxidation and reduction processes separately. They demonstrate the flow of electrons in a redox reaction and are particularly useful in balancing redox equations.
In any redox reaction, such as \( 2 \mathrm{Li} + \mathrm{H}_2 \rightarrow 2 \mathrm{LiH} \), we separate this into two half-reactions.
  • Oxidation half-reaction: This represents the species that is losing electrons, which in this case is \( \mathrm{Li} \rightarrow \mathrm{Li^+} + e^- \).
  • Reduction half-reaction: This shows the species gaining electrons. For \( \mathrm{H}_2 \), it becomes \( \mathrm{H}_2 + 2e^- \rightarrow 2\mathrm{H^-} \).
These half-reactions help us track the electron exchange clearly. When these are combined correctly, they should yield the original balanced overall equation without any electron imbalance. Breaking down reactions into half-reactions is a key skill in predicting the products of oxidation and reduction processes.
Oxidizing and Reducing Agents
Understanding oxidizing and reducing agents in a redox reaction further illuminates the electron dynamics.
An oxidizing agent is a substance that gains electrons and is thus reduced in a reaction. It plays a crucial role as it "oxidizes" another substance by taking in its electrons. For instance, in \( 2 \mathrm{Cs} + \mathrm{Br}_2 \rightarrow 2 \mathrm{CsBr} \), \( \mathrm{Br}_2 \) acts as the oxidizing agent because it gains electrons and forms \( \mathrm{Br^-} \).
A reducing agent is the opposite. It donates electrons and becomes oxidized. This means the substance is effectively "reducing" another by giving up its electrons. In the same reaction, \( \mathrm{Cs} \) becomes the reducing agent, as it gets oxidized to \( \mathrm{Cs^+} \).
Identifying these agents is straightforward: the substance being reduced is the oxidizing agent, and the substance being oxidized is the reducing agent. This conceptual framework is widely applicable and critical for analyzing redox processes in various chemical reactions.

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