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Identify each of the following species as a Br酶nsted acid, base, or both: (a) \(\mathrm{PO}_{4}^{3-},\) (b) \(\mathrm{ClO}_{2}^{-},\) (c) \(\mathrm{NH}_{4}^{+}\) (d) \(\mathrm{HCO}_{3}^{-}\).

Short Answer

Expert verified
(a) base, (b) base, (c) acid, (d) both

Step by step solution

01

Understand the Concept of Br酶nsted Acid and Base

A Br酶nsted acid is a species that can donate a proton (H鈦), and a Br酶nsted base is a species that can accept a proton. Some species can act as both, depending on the reaction context.
02

Analyze the Species \( \mathrm{PO}_{4}^{3-} \)

The phosphate ion, \( \mathrm{PO}_{4}^{3-} \), has a negative charge, which allows it to accept protons. Therefore, \( \mathrm{PO}_{4}^{3-} \) acts as a Br酶nsted base.
03

Analyze the Species \( \mathrm{ClO}_{2}^{-} \)

The chlorite ion, \( \mathrm{ClO}_{2}^{-} \), has a negative charge, making it capable of accepting a proton. Hence, \( \mathrm{ClO}_{2}^{-} \) acts as a Br酶nsted base.
04

Analyze the Species \( \mathrm{NH}_{4}^{+} \)

The ammonium ion, \( \mathrm{NH}_{4}^{+} \), has a positive charge and an acidic proton, which it can donate. Thus, \( \mathrm{NH}_{4}^{+} \) functions as a Br酶nsted acid.
05

Analyze the Species \( \mathrm{HCO}_{3}^{-} \)

The bicarbonate ion, \( \mathrm{HCO}_{3}^{-} \), can accept a proton to form \( \mathrm{H}_{2}\mathrm{CO}_{3} \), or donate a proton to become \( \mathrm{CO}_{3}^{2-} \). This makes \( \mathrm{HCO}_{3}^{-} \) both a Br酶nsted acid and base (amphiprotic).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Br酶nsted acid
A Br酶nsted acid is a fundamental concept in chemistry referring to a substance that can donate a hydrogen ion, also known as a proton ( H鈦 ). The donation of a proton is what gives a Br酶nsted acid its characteristic acidic properties. These species often have a positive charge or one that can easily lose an H鈦 atom.

For instance, the ammonium ion ( NH鈧勨伜 ) is a classic example. It carries a proton ready to be donated in a reaction, showcasing its ability to act as a Br酶nsted acid. When NH鈧勨伜 loses a proton, it forms NH鈧 , ammonia, effectively behaving as an acid in the process.

Understanding these principles helps in predicting the behavior of molecules in acid-base reactions. It's crucial to identify the potential of a given species to donate a proton to facilitate various chemical processes.
Br酶nsted base
Br酶nsted bases are substances that have the ability to accept protons ( H鈦 ). This property defines their basic nature in chemistry. Typically, these species possess a negative charge, which allows them to attract and bind with a proton.

Consider the phosphate ion ( PO鈧刕{3-} ). With its negative charge, it readily accepts protons, demonstrating its role as a Br酶nsted base. Similarly, the chlorite ion ( ClO鈧傗伝 ) behaves as a base by accepting a proton due to its negative charge.

Identifying Br酶nsted bases is essential for understanding reactions, such as neutralization, where they interact with acids. By accepting protons, they form different compounds, highlighting the fundamental nature of these reactions.
Amphiprotic species
Amphiprotic species are unique in that they can both donate and accept protons ( H鈦 ), depending on the reaction context. This dual function means that they can act as either an acid or a base.

A perfect example is the bicarbonate ion ( HCO鈧冣伝 ). It can donate a proton, transforming into CO鈧僞{2-} , showcasing its acidic property. Simultaneously, it can accept a proton to become H鈧侰O鈧 (carbonic acid), which illustrates its basic property.

This flexible behavior of amphiprotic species is crucial in buffer solutions, which maintain pH levels in various systems, including biological systems. By switching between donating and accepting protons, they help stabilize the environment, making amphiprotic species especially important in chemistry and biology.

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