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Name these compounds: (a) \(\mathrm{KClO}\) (b) \(\mathrm{Ag}_{2} \mathrm{CO}_{3}\) (c) \(\mathrm{FeCl}_{2},\) (d) \(\mathrm{KMnO}_{4},\) (e) \(\mathrm{CsClO}_{3},\) (f) \(\mathrm{HIO},(\mathrm{g}) \mathrm{FeO}\) (h) \(\mathrm{Fe}_{2} \mathrm{O}_{3},\) (i) \(\mathrm{TiCl}_{4},\) (j) \(\mathrm{NaH},(\mathrm{k}) \mathrm{Li}_{3} \mathrm{~N},\) (1) \(\mathrm{Na}_{2} \mathrm{O},(\mathrm{m})\) \(\mathrm{Na}_{2} \mathrm{O}_{2},(\mathrm{n}) \mathrm{FeCl}_{3} \cdot 6 \mathrm{H}_{2} \mathrm{O}\)

Short Answer

Expert verified
(a) Potassium Hypochlorite, (b) Silver Carbonate, (c) Iron(II) Chloride, (d) Potassium Permanganate, (e) Cesium Chlorate, (f) Hypoiodous Acid, (g) Iron(II) Oxide, (h) Iron(III) Oxide, (i) Titanium(IV) Chloride, (j) Sodium Hydride, (k) Lithium Nitride, (l) Sodium Oxide, (m) Sodium Peroxide, (n) Iron(III) Chloride Hexahydrate.

Step by step solution

01

Compound (a) - KClO

Potassium Chloride salts contain an oxyanion, which in this case is hypochlorite. Therefore, the compound KClO is named Potassium Hypochlorite.
02

Compound (b) - Ag鈧侰O鈧

Silver carbonate is composed of two silver ions and one carbonate ion. The compound is named Silver Carbonate.
03

Compound (c) - FeCl鈧

The compound FeCl鈧 contains iron in the +2 oxidation state paired with chloride ions. It is named Iron(II) Chloride, specifying the oxidation state with a Roman numeral.
04

Compound (d) - KMnO鈧

KMnO鈧 is a compound of potassium with the permanganate ion. It is named Potassium Permanganate.
05

Compound (e) - CsClO鈧

Cesium combined with the chlorate ion forms CsClO鈧, which is named Cesium Chlorate.
06

Compound (f) - HIO

Hydrogen and hypoiodite ions combine to form HIO, known as Hypoiodous Acid.
07

Compound (g) - FeO

Iron(II) Oxide comprises iron in the +2 oxidation state with oxygen, named Iron(II) Oxide.
08

Compound (h) - Fe鈧侽鈧

In Fe鈧侽鈧, iron is in the +3 oxidation state. Therefore, it is named Iron(III) Oxide.
09

Compound (i) - TiCl鈧

Titanium tetrachloride contains titanium in the +4 oxidation state, named Titanium(IV) Chloride.
10

Compound (j) - NaH

Sodium Hydride consists of sodium and hydrogen, and it is simply named Sodium Hydride.
11

Compound (k) - Li鈧僋

Lithium Nitride is the combination of lithium and nitrogen, and its name is accordingly Lithium Nitride.
12

Compound (l) - Na鈧侽

Sodium and oxygen form Na鈧侽, which is named Sodium Oxide.
13

Compound (m) - Na鈧侽鈧

Na鈧侽鈧 consists of sodium and the peroxide ion, and it is named Sodium Peroxide.
14

Compound (n) - FeCl鈧兟6H鈧侽

The formula indicates iron(III) chloride hexahydrate, naming the compound Iron(III) Chloride Hexahydrate.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ionic Compounds
Ionic compounds are a fundamental topic in chemistry. They are formed from the electrostatic attraction between positively charged ions, called cations, and negatively charged ions, known as anions. This bond results in a compound that has overall neutral charge.
A classic example of ionic compounds is salt (\(\mathrm{NaCl}\)). Here, sodium (Na) loses one electron to become a Na鈦 cation while chlorine (Cl) gains that electron to become a Cl鈦 anion.
Ionic compounds typically form between metals and non-metals. Metals, like sodium, lose electrons to form cations, while non-metals, such as chlorine, gain electrons to form anions. This electron transfer creates a strong ionic bond.
  • The crystal lattice structure is a hallmark of ionic compounds, leading to properties like high melting and boiling points.
  • They are usually soluble in water and conduct electricity when dissolved or melted due to the mobility of the charged ions.
Understanding the formation and characteristics of ionic compounds is essential for grasping many chemical reactions and processes.
Oxidation State
Oxidation state, also known as oxidation number, is a concept that helps in understanding the transfer of electrons in chemical reactions. It is a hypothetical charge an atom would have if all bonds to atoms of different elements were completely ionic.
Determining the oxidation state involves a set of rules:
  • Elements in their natural form have an oxidation state of zero. For example, O鈧 and H鈧 both have oxidation states of zero.
  • For simple ions, the oxidation state is the charge of the ion, e.g., Na鈦 has an oxidation state of +1.
  • In a compound, the sum of oxidation states must equal the total charge of the compound.
  • Oxygen generally has an oxidation state of -2, except in peroxides like \( \mathrm{Na}_2\mathrm{O}_2 \) where it is -1.
  • Hydrogen usually has an oxidation state of +1, except when bonded to metals in compounds like \(\mathrm{NaH}\), where it is -1.
Using these rules, one can determine individual oxidation states, which are important for naming compounds, especially transition metals with multiple possible states like iron in FeCl鈧 and FeCl鈧.
Naming Rules for Compounds
Chemical nomenclature is the systematic naming of chemical compounds. Inorganic compounds, like ionic compounds, follow specific naming conventions:
For binary ionic compounds (compounds of two elements), the name is composed of the cation followed by the anion. The cation retains the element name, and the anion ends with the suffix 'ide'. For example, in sodium chloride (\(\mathrm{NaCl}\)), sodium is the cation, and "chloride" replaces chlorine as the anion.
When it comes to transition metals, which have multiple oxidation states, the oxidation state is specified using Roman numerals in parentheses. For example, Iron(II) Chloride for \(\mathrm{FeCl}_2\) and Iron(III) Chloride for \(\mathrm{FeCl}_3\).
For polyatomic ions, the name derives from the ion itself. For example, carbonate is used in naming compounds like silver carbonate (\(\mathrm{Ag}_2\mathrm{CO}_3\)). Prefixes like hypo- and per- are used to indicate fewer or more oxygen atoms compared to the base polyatomic ion. Hypochlorite and perchlorate are examples of such usage.
  • Acids are named depending on the presence of an oxygen atom. Those with oxygen, like hypoiodous acid (\(\mathrm{HIO}\)), use the root of the anion name plus "-ous" or "-ic".
  • Naming rules ensure clarity and help chemists communicate complex information succinctly.
Utilizing these naming conventions allows for the straightforward identification and understanding of chemical substances.

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