Chapter 14: Problem 53
Are enzyme-catalyzed reactions examples of homogeneous or heterogeneous catalysis?
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Chapter 14: Problem 53
Are enzyme-catalyzed reactions examples of homogeneous or heterogeneous catalysis?
These are the key concepts you need to understand to accurately answer the question.
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Reactions can be classified as unimolecular, bimolecular, and so on. Why are there no zero-molecular reactions?
The rate of the reaction $$ \begin{aligned} \mathrm{CH}_{3} \mathrm{COOC}_{2} \mathrm{H}_{5}(a q) &+\mathrm{H}_{2} \mathrm{O}(l) \\ \longrightarrow & \mathrm{CH}_{3} \mathrm{COOH}(a q)+\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(a q) \end{aligned} $$ When methyl phosphate is heated in acid solution, it reacts with water: $$ \mathrm{CH}_{3} \mathrm{OPO}_{3} \mathrm{H}_{2}+\mathrm{H}_{2} \mathrm{O} \longrightarrow \mathrm{CH}_{3} \mathrm{OH}+\mathrm{H}_{3} \mathrm{PO}_{4} $$ If the reaction is carried out in water enriched with \({ }^{18} \mathrm{O}\) the oxygen- 18 isotope is found in the phosphoric acid product but not in the methanol. What does this tell us about the bond-breaking scheme in the reaction?
The following gas-phase reaction was studied at \(290^{\circ} \mathrm{C}\) by observing the change in pressure as a function of time in a constant-volume vessel: $$ \mathrm{ClCO}_{2} \mathrm{CCl}_{3}(g) \longrightarrow 2 \mathrm{COCl}_{2}(g) $$ Determine the order of the reaction and the rate constant based on the following data: $$ \begin{array}{rc} \text { Time (s) } & \boldsymbol{P} \text { (mmHg) } \\ \hline 0 & 15.76 \\ 181 & 18.88 \\ 513 & 22.79 \\ 1164 & 27.08 \end{array} $$ where \(P\) is the total pressure.
The following expression shows the dependence of the half-life of a reaction \(\left(t_{\frac{1}{2}}\right)\) on the initial reactant concentration \([\mathrm{A}]_{0}:\) $$ t_{\frac{1}{2}} \propto \frac{1}{[\mathrm{~A}]_{0}^{n-1}} $$ where \(n\) is the order of the reaction. Verify this dependence for zero-, first-, and second-order reactions.
The rate constant for the second-order reaction $$ 2 \mathrm{NO}_{2}(g) \longrightarrow 2 \mathrm{NO}(g)+\mathrm{O}_{2}(g) $$ is \(0.54 / M \cdot \mathrm{s}\) at \(300^{\circ} \mathrm{C}\). (a) How long (in seconds) would it take for the concentration of \(\mathrm{NO}_{2}\) to decrease from \(0.62 M\) to \(0.28 M ?\) (b) Calculate the half-lives at these two concentrations.
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