Chapter 2: Problem 55
Nitrogen has two naturally occurring isotopes, \({ }^{14} \mathrm{~N}\) and \({ }^{15} \mathrm{~N}\), with isotopic masses of \(14.0031\) and \(15.0001\), respectively. The average atomic mass of nitrogen is \(14.0067\). Use these data to compute the percentage of \({ }^{15} \mathrm{~N}\) in naturally occurring nitrogen.
Short Answer
Step by step solution
Express the Average Atomic Mass
Simplify the Equation
Rearrange to Solve for x
Calculate x
Convert Fraction to Percentage
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Average Atomic Mass
- Each isotope of an element has a different mass because of the differences in neutrons.
- The average atomic mass takes into account how often each isotope appears in nature.
- To calculate it, we use the formula: \[ \text{Average atomic mass} = ( \text{Fraction of }^{14}\mathrm{N} \times \text{Mass of }^{14}\mathrm{N} ) + ( \text{Fraction of }^{15}\mathrm{N} \times \text{Mass of }^{15}\mathrm{N} ) \]
By understanding how these averages work, students gain a deeper appreciation of chemical behavior, particularly in how elements combine and react.
Nitrogen Isotopes
- \( ^{14}\mathrm{N} \) with a mass of approximately 14.0031 amu.
- \( ^{15}\mathrm{N} \) with a mass of approximately 15.0001 amu.
The presence of these isotopes provides nitrogen with unique physical properties while maintaining its chemical identity.
The Role of Isotopes in Chemistry
- Each isotope behaves slightly differently in reactions, particularly when involving nuclear processes, due to differences in nuclear mass.
- In nature, \( ^{14}\mathrm{N} \) is much more abundant than \( ^{15}\mathrm{N} \), giving it a greater impact on calculations concerning average atomic mass.
Percentage Composition
- Consider the calculated fraction or proportion of \( ^{15}\mathrm{N} \) which was found to be approximately 0.003611.- To convert this fraction into a percentage, multiply it by 100:\[ \text{Percentage of } ^{15}\mathrm{N} = 0.003611 \times 100 = 0.3611\% \]Understanding percentage composition helps recognize the dominance or scarcity of specific isotopes.
Applications of Percentage Composition
- In biological studies, isotopic compositions can aid in understanding metabolic pathways.
- In industry, they may be used to ensure the correct proportions in chemical reactions or product formulations.
Learning these details influences everything from environmental science to forensic investigations.