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The dissolution of ammonium chloride in water is endothermic. Would you predict ammonium chloride to be more soluble in warm or cool water?

Short Answer

Expert verified
Ammonium chloride is predicted to be more soluble in warm water.

Step by step solution

01

Understand the Problem

The problem is asking us to determine if ammonium chloride (NH4Cl) is more soluble in warm or cool water. We need to use our knowledge of how temperature affects solubility.
02

Consider the Nature of the Process

We are told that the dissolution of ammonium chloride in water is endothermic. This means that the process absorbs heat from its surroundings.
03

Apply Le Chatelier's Principle

Le Chatelier's Principle states that if a system at equilibrium is disturbed, it will adjust to minimize that disturbance. In the case of an endothermic process, increasing temperature adds heat to the system, which favors the dissolution process.
04

Draw a Conclusion

Since the dissolution of ammonium chloride is endothermic, adding heat (by increasing temperature) will favor solubility. Therefore, ammonium chloride is predicted to be more soluble in warm water.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Endothermic Process
When we talk about an endothermic process, we mean that the reaction or event absorbs heat from its surroundings. This is the opposite of an exothermic process, which releases heat.
In the context of solubility, if a substance like ammonium chloride dissolves in water through an endothermic process, it means it needs energy to proceed. The energy typically comes in the form of heat.
Imagine you're mixing sugar into a glass of iced tea. To dissolve that sugar efficiently, you may want to warm the tea. The same concept applies to endothermic processes.
  • Endothermic processes absorb heat.
  • They require energy to proceed.
  • This energy often comes from increased temperature.
When a reaction is endothermic, increasing the surrounding temperature often helps it to proceed more effectively by supplying the necessary energy.
Le Chatelier's Principle
Le Chatelier's Principle is a fundamental concept in chemistry that explains how equilibria respond to changes or 'disturbances' in their systems. Essentially, if a change is imposed on a system at equilibrium, the system will adjust in such a way as to counteract the effect of that change.
For an endothermic process like the dissolution of ammonium chloride, when we increase the temperature (add heat), the system responds by favoring the process that absorbs heat—here, the dissolution.
  • If we add heat to an endothermic reaction, it shifts to favor dissolving more solute.
  • Conversely, reducing temperature would make it less soluble.
By understanding this principle, we can predict the behavior of different chemical systems when subjected to external changes such as temperature shifts.
Temperature Effect on Solubility
The effect of temperature on solubility varies depending on whether the dissolution process is endothermic or exothermic.
In endothermic processes, increasing the temperature typically increases solubility. That's because the added heat serves as energy to help dissolve the solute. For instance, in the case of ammonium chloride, as we raise the temperature of the water, more ammonium chloride can dissolve.
Let's break it down:
  • For endothermic dissolutions, higher temperatures increase solubility.
  • For exothermic dissolutions, higher temperatures might decrease solubility.
  • The nature of the solute and solvent relationship can affect these outcomes.
By understanding how temperature impacts solubility, particularly in endothermic reactions, we can make more accurate predictions and optimize conditions for dissolving substances like ammonium chloride in various temperature settings.

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Most popular questions from this chapter

When \(2.46\) grams of barium reacts with chlorine, \(-15.4 \mathrm{~kJ}\) of energy is evolved as heat. Calculate the energy evolved as heat (in kilojoules) when \(1.00\) mole of barium chloride is formed from barium and chlorine.

One of the most famous equations in science is \(E=m c^{2}\), which comes from Einstein's theory of relativity. Einstein was the first to show that mass can be converted into energy, and that energy can be converted into mass. This equation relates the amount of energy produced when the mass of a system decreases, or conversely, the amount of energy that is required to increase the mass of a system. In either case, the equation relates the change in energy associated with a change in mass, and in the notation of this chapter, Einstein's mass-energy relation is written as $$ \Delta U=c^{2} \Delta m $$ where \(\Delta U\) is the change in energy and \(\Delta m\) is the change in mass. Calculate the amount of energy produced when a \(1.00\) gram mass is converted into energy. Compare this result to the magnitude of the energy changes in chemical reactions that are from about \(-400 \mathrm{~kJ} \cdot \mathrm{mol}^{-1}\) to \(600 \mathrm{~kJ} \cdot \mathrm{mol}^{-1}\).

Explain why chemists collecting thermodynamic data create tables of enthalpy changes for chemical reactions rather than listing the energy transferred in the form of heat and work for chemical reactions.

In this problem, we shall show that work is a path function. Let's start with an ideal gas enclosed in a one-liter container at a pressure of \(10.0\) bar. Calculate the work done by the gas if it expands against a constant pressure of \(1.0\) bar to a final volume of \(10.0\) liters, as shown in (a) below. Now let's carry out this process in two steps. In the first step, let the gas expand against a constant pressure of \(5.0\) bar to a volume of \(2.0\) liters. In the second step, let the gas expand against a constant pressure of \(1.0\) bar to a final volume of \(10.0\) liters, as shown in (b) below. Note that the final state in the one-step expansion and in the two-step expansion is the same \((10.0\) liters at \(1.0\) bar \(),\) and so \(\Delta U\), which is a state function, is the same for both processes. Now calculate the work done by the gas in the two-step expansion and compare your result to the one that you obtained for the onestep expansion.

A \(100.0\) -mL sample of \(0.200\) -M aqueous hydrochloric acid is added to \(100.0 \mathrm{~mL}\) of \(0.200-\mathrm{M}\) aqueous ammonia in a calorimeter with a total heat capacity of \(480 \mathrm{~J} \cdot \mathrm{K}^{-1} .\) The temperature increase is \(2.34 \mathrm{~K}\). Calculate the value of \(\Delta H_{\mathrm{rxn}}^{\circ}\) for the equation $$ \mathrm{HCl}(a q)+\mathrm{NH}_{3}(a q) \rightarrow \mathrm{NH}_{4} \mathrm{Cl}(a q) $$ which describes the reaction that occurs when the two solutions are mixed.

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