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Under normal conditions, why is it relatively easy to compress a gas, but much more difficult to compress a liquid?

Short Answer

Expert verified
Gases are easier to compress due to the greater space between molecules compared to closely packed molecules in liquids.

Step by step solution

01

Understand the Molecular Arrangement in Gases

In gases, molecules are widely spaced apart compared to liquids. This large amount of space between molecules gives gases a great deal of freedom to move around. Consequently, when pressure is applied to a gas, its molecules can be moved closer together, reducing its volume.
02

Understand the Molecular Arrangement in Liquids

In liquids, molecules are much more closely packed together than in gases. There is very little space between the molecules of a liquid, which restricts their movement. Therefore, when pressure is applied, there is minimal room for the molecules to compress further.
03

Compare Compressibility of Gases and Liquids

The compressibility of a substance depends on how its molecules are arranged. Because gas molecules are further apart compared to the close proximity of molecules in liquids, gases can be compressed much more easily than liquids.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molecular Arrangement
In understanding why gases are more compressible than liquids, it is essential to examine the molecular arrangement.
Gas molecules are notably dispersed with large spaces in between. This expansive distance allows gas molecules the freedom to move about freely in different directions. The arrangement means that when external pressure is applied, these large spaces between molecules can be reduced significantly, leading to a decrease in volume.
  • Gases have large intermolecular spaces
  • Molecules are in constant motion
  • Very adaptable to changes in pressure
On the other hand, liquid molecules are tightly packed with minimal space maintaining their proximity. This close-packed arrangement limits the ability of the molecules to move closer when pressure is increased. Therefore, there is hardly any room to reduce their volume, making liquids significantly less compressible than gases.
Compressibility
Compressibility is the measure of how much a substance can decrease in volume under pressure. A substance's compressibility is greatly affected by its molecular arrangement. For gases, the large gaps between molecules mean they can be pushed closer together easily.
Thus, gases exhibit high compressibility. You can imagine squeezing a balloon—the air inside, mainly composed of gases like nitrogen and oxygen, compresses with ease.
  • Large intermolecular distances in gases
  • High adaptability to volume changes
  • More compressible due to space between particles
In contrast, liquids have molecules that are already so close that additional pressure barely decreases their volume. Liquids, therefore, have low compressibility. This can be likened to trying to compress water in a bottle - little to no volume decrease is observed due to the tightly packed molecules.
Pressure and Volume Relationship
The relationship between pressure and volume in gases is described by Boyle's Law, which states that the volume of a gas is inversely proportional to its pressure, if the temperature remains constant. As you increase pressure, the volume of gas decreases and vice versa.
This principle is more pronounced in gases because of their molecular arrangement and high compressibility. For instance, when you press down a bicycle pump, you're compressing the air inside, which increases the pressure and decreases the volume of the air.
  • Volume decreases with increased pressure
  • Boyle's Law: \( P_1V_1 = P_2V_2 \)
  • Practical applications in everyday tools like pumps
In liquids, however, the pressure-volume relationship is less noticeable due to their low compressibility. If you apply pressure to a liquid-filled container, the volume barely changes. That’s why liquids are often incompressible in practical scenarios, making them ideal for hydraulic systems.

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Most popular questions from this chapter

Upon chemical analysis, a gaseous hydrocarbon is found to contain \(88.82 \%\) carbon and \(11.18 \%\) hydrogen by mass. A \(62.6\) -milligram sample of the gas occupies \(34.9\) milliliters at 772 Torr and \(100.0^{\circ} \mathrm{C}\). Determine the molecular formula of the hydrocarbon.

Lactic acid is produced by the muscles when insufficient oxygen is available and is responsible for muscle cramps during vigorous exercising. It also provides the acidity found in dairy products. Chemical analysis shows that lactic acid is \(39.99 \%\) carbon, \(6.73 \%\) hydrogen, and \(53.28 \%\) oxygen by mass. A 0.3338-gram sample of lactic acid was vaporized in a sealed \(300.0\) -milliliters container at \(150.0^{\circ} \mathrm{C}\), producing a pressure of 326 Torr. Use these data to determine the molecular formula of lactic acid.

A certain gaseous hydrocarbon was determined to be \(82.66 \%\) carbon and \(17.34 \%\) hydrogen by mass. A \(6.09\) -gram sample of the gas occupied \(2.48\) liters at \(1.00\) atm and \(15^{\circ} \mathrm{C}\). Determine the molecular formula of the hydrocarbon.

The minimum velocity necessary for objects to leave the earth's gravitational field and escape into space is \(11.2 \mathrm{~km} \cdot \mathrm{s}^{-1} .\) Calculate \(v_{\mathrm{rms}}\) for He at \(2500^{\circ} \mathrm{C}\) in units of kilometers per second. Assuming that this is the average temperature of the helium in the earth's upper atmosphere, can any of this helium escape into space?

Nitroglycerin decomposes according to the equation $$ \begin{array}{r} 4 \mathrm{C}_{3} \mathrm{H}_{5}\left(\mathrm{NO}_{3}\right)_{3}(s) \rightarrow \\\ 12 \mathrm{CO}_{2}(g)+10 \mathrm{H}_{2} \mathrm{O}(l)+6 \mathrm{~N}_{2}(g)+\mathrm{O}_{2}(g) \end{array} $$ What is the total volume of the gases produced when collected at \(1.00\) bar and \(25^{\circ} \mathrm{C}\) from the decomposition of \(10.0\) grams of nitroglycerin? What pressure is produced if the reaction is confined to a volume of \(0.500\) liters at \(25^{\circ} \mathrm{C} ?\) Assume that you can use the ideal-gas equation. Neglect any pressure due to water vapor.

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