/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 5 A gas bubble has a volume of \(0... [FREE SOLUTION] | 91Ó°ÊÓ

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A gas bubble has a volume of \(0.650\) milliliters at the bottom of a lake, where the pressure is \(3.46 \mathrm{~atm}\). What is the volume of the bubble at the surface of the lake, where the pressure is \(1.00 \mathrm{~atm}\) ? What are the diameters of the bubble at the two depths? Assume that the temperature is constant and that the bubble is spherical.

Short Answer

Expert verified
The volume increases to 2.249 mL at the surface; diameters are 1.14 mm at the bottom and 1.69 mm at the surface.

Step by step solution

01

Understand Boyle's Law

Boyle's Law states that for a given amount of gas at a constant temperature, the volume of the gas is inversely proportional to its pressure. Mathematically, this can be expressed as: \( P_1 V_1 = P_2 V_2 \), where \( P_1 \) and \( V_1 \) are the pressure and volume at one state, and \( P_2 \) and \( V_2 \) are the pressure and volume at another state.
02

Identify Known Values

We are given \( P_1 = 3.46 \) atm, \( V_1 = 0.650 \) mL, and \( P_2 = 1.00 \) atm. We need to find \( V_2 \), the volume of the bubble at the surface.
03

Apply Boyle's Law

Using the formula \( P_1 V_1 = P_2 V_2 \), substitute the known values to find \( V_2 \):\[ V_2 = \frac{P_1 V_1}{P_2} = \frac{3.46 \times 0.650}{1.00} \]
04

Calculate New Volume

Calculate \( V_2 \) using the expression from Step 3:\[ V_2 = \frac{3.46 \times 0.650}{1} = 2.249 \text{ mL} \]So, the volume of the bubble at the surface is 2.249 mL.
05

Relate Volume to Diameter of a Sphere

The volume of a sphere is given by \( V = \frac{4}{3} \pi r^3 \). The diameter \( d \) of a sphere is exponentially related to its volume by \( d = 2 \left( \frac{3V}{4\pi} \right)^{1/3} \). We can use this formula to find the diameters at both depths.
06

Calculate Initial Diameter

Use the initial volume \( V_1 = 0.650 \) mL to calculate the initial diameter:\[ d_1 = 2 \left( \frac{3 \times 0.650}{4\pi} \right)^{1/3} \]Calculating, we find \( d_1 \approx 1.14 \text{ mm} \) (Note conversion from mL to solid volume units).
07

Calculate Final Diameter

Using \( V_2 = 2.249 \) mL to calculate the final diameter:\[ d_2 = 2 \left( \frac{3 \times 2.249}{4\pi} \right)^{1/3} \]Calculating, we find \( d_2 \approx 1.69 \text{ mm} \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Gas Laws
Gas laws describe the behavior of gases and are foundational in understanding changes in pressure, volume, and temperature. Boyle's Law is one of the fundamental gas laws. It explains the relationship between the pressure and volume of a gas.
Boyle's Law states that at a constant temperature, the volume of a gas is inversely proportional to its pressure. This means:
  • When you increase the pressure on a gas, its volume decreases.
  • Conversely, when you decrease the pressure, the volume increases.
This can be mathematically written as \( P_1 V_1 = P_2 V_2 \). Here, \( P_1 \) and \( V_1 \) represent the initial pressure and volume, while \( P_2 \) and \( V_2 \) represent the pressure and volume at a different state.
This exercise was solved by applying Boyle's Law to a gas bubble rising in a lake, allowing us to determine the changes in volume as the pressure decreased.
Pressure-Volume Relationship
The pressure-volume relationship is key in understanding how gases behave under different conditions. This relationship is built upon Boyle's Law.
The equation \( P_1 V_1 = P_2 V_2 \) describes this relationship. In the problem, the pressure decreases from 3.46 atm at the bottom of the lake to 1.00 atm at the surface. Accordingly, the volume of the gas bubble increases.
To find the final volume \( V_2 \) at the surface, we rearrange the equation:\[ V_2 = \frac{P_1 V_1}{P_2} \]By substituting the known values, \( V_2 = \frac{3.46 \times 0.650}{1.00} \), we calculate the new volume.
This formula highlights how pressure and volume are connected and shows the practical application of Boyle's Law. When pressure is reduced, as in this case where the bubble rises to the surface, the increase in volume is predictable and can be accurately calculated.
Spherical Volume Calculation
Calculating the volume of a sphere is crucial when dealing with spherical objects, like a gas bubble. The volume \( V \) of a sphere is determined by the formula:\[ V = \frac{4}{3} \pi r^3 \]Where \( r \) is the radius of the sphere. For practical purposes, particularly in this exercise, we need to relate the volume to the diameter \( d \). The diameter is twice the radius, given by:\[ d = 2 \left( \frac{3V}{4\pi} \right)^{1/3} \]For the bubble at the bottom of the lake with a volume of 0.650 mL, the diameter can be calculated as:\[ d_1 = 2 \left( \frac{3 \times 0.650}{4\pi} \right)^{1/3} \approx 1.14 \text{ mm} \]At the surface with volume 2.249 mL:\[ d_2 = 2 \left( \frac{3 \times 2.249}{4\pi} \right)^{1/3} \approx 1.69 \text{ mm} \]Understanding this calculation allows one to appreciate how changes in pressure and volume affect the physical dimensions of gas bubbles in a real-world context.

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Most popular questions from this chapter

Two glass bulbs are connected by a valve. One bulb has a volume of \(650.0\) milliliters and is occupied by \(\mathrm{N}_{2}(g)\) at 825 Torr. The other has a volume of \(500.0\) milliliters and is occupied by \(\mathrm{O}_{2}(g)\) at 732 Torr. The valve is opened and the two gases mix. Calculate the total pressure and the partial pressures of \(\mathrm{N}_{2}(g)\) and \(\mathrm{O}_{2}(g)\) in the resulting mixture.

Hydrogen and oxygen react violently with each other once the reaction is initiated. For example, a spark can set off the reaction and cause the mixture to explode. What volume of oxygen gas will react with \(0.55\) liters of hydrogen gas if both are at \(300^{\circ} \mathrm{C}\) and one bar? What volume of water vapor will be produced at \(300^{\circ} \mathrm{C}\) and one bar?

Gallium metal can be used as a manometer fluid at high temperatures because of its wide liquid range ( 30 to \(2400^{\circ} \mathrm{C}\) ). Compute the height of a column of liquid gallium in a gallium manometer when the temperature is \(850^{\circ} \mathrm{C}\) and the pressure is 1300 Torr. Take the density of liquid gallium to be \(6.0 \mathrm{~g} \cdot \mathrm{mL}^{-1}\)

Sulfur dioxide can combine with oxygen to form sulfur trioxide according to the equation $$ 2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \rightarrow 2 \mathrm{SO}_{3}(g) $$ A researcher studying the reaction under various conditions introduces \(725.0\) Pa of sulfur dioxide into a rigid stainless steel reaction chamber maintained at a constant temperature. She then introduces \(500.0 \mathrm{~Pa}\) of oxygen. Assuming that all the sulfur dioxide is converted to sulfur trioxide, calculate the final total pressure inside the chamber.

Lactic acid is produced by the muscles when insufficient oxygen is available and is responsible for muscle cramps during vigorous exercising. It also provides the acidity found in dairy products. Chemical analysis shows that lactic acid is \(39.99 \%\) carbon, \(6.73 \%\) hydrogen, and \(53.28 \%\) oxygen by mass. A 0.3338-gram sample of lactic acid was vaporized in a sealed \(300.0\) -milliliters container at \(150.0^{\circ} \mathrm{C}\), producing a pressure of 326 Torr. Use these data to determine the molecular formula of lactic acid.

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