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How many grams of lead(II) iodate, \(\mathrm{Pb}\left(\mathrm{IO}_{3}\right)_{2}(s)\), are precipitated when \(25.0\) milliliters of \(3.00 \mathrm{M} \mathrm{Pb}\left(\mathrm{NO}_{3}\right)_{2}(a q)\) are mixed with \(30.0\) milliliters of a \(5.00 \mathrm{M} \mathrm{KIO}_{3}(a q)\) solution?

Short Answer

Expert verified
41.78 grams of \(\mathrm{Pb(IO_3)_2}\) are precipitated.

Step by step solution

01

Write the Balanced Equation

First, write the balanced chemical equation for the reaction between lead(II) nitrate \(\mathrm{Pb(NO_3)_2}\) and potassium iodate \(\mathrm{KIO_3}\). The balanced equation is: \[\mathrm{Pb(NO_3)_2(aq) + 2KIO_3(aq) \rightarrow Pb(IO_3)_2(s) + 2KNO_3(aq)}\].
02

Calculate Moles of Each Reactant

Calculate the moles of \(\mathrm{Pb(NO_3)_2}\) and \(\mathrm{KIO_3}\) using their molarity and volume. For \(\mathrm{Pb(NO_3)_2}\): \[\text{Moles of } \mathrm{Pb(NO_3)_2} = 3.00 \, \mathrm{M} \times 0.0250 \, \mathrm{L} = 0.0750 \, \mathrm{mol}\]. For \(\mathrm{KIO_3}\): \[\text{Moles of } \mathrm{KIO_3} = 5.00 \, \mathrm{M} \times 0.0300 \, \mathrm{L} = 0.150 \, \mathrm{mol}\].
03

Determine the Limiting Reactant

According to the balanced equation, \(2\) moles of \(\mathrm{KIO_3}\) react with \(1\) mole of \(\mathrm{Pb(NO_3)_2}\). Thus, \(0.0750\) moles of \(\mathrm{Pb(NO_3)_2}\) would require \(0.150\) moles of \(\mathrm{KIO_3}\), just matching the available \(\mathrm{KIO_3}\) moles. Therefore, neither reactant is in excess but they are perfectly balanced.
04

Calculate Moles of Precipitate Formed

Based on the balanced equation, \(1\) mole of \(\mathrm{Pb(NO_3)_2}\) results in \(1\) mole of \(\mathrm{Pb(IO_3)_2}\). Since \(0.0750\) moles of \(\mathrm{Pb(NO_3)_2}\) reacted, \(0.0750\) moles of \(\mathrm{Pb(IO_3)_2}\) are precipitated.
05

Compute Mass of Lead(II) Iodate Precipitate

Calculate the molar mass of \(\mathrm{Pb(IO_3)_2}\): \(\mathrm{Pb} = 207.2\, \mathrm{g/mol}, \mathrm{I} = 126.9 \times 2 = 253.8 \mathrm{g/mol}, \mathrm{O_3} = 16 \times 6 = 96 \mathrm{g/mol}\). Therefore, \(\text{Molar Mass of } \mathrm{Pb(IO_3)_2} = 207.2 + 253.8 + 96 = 557.0 \, \mathrm{g/mol}\). Then, compute the mass: \[0.0750 \, \mathrm{mol} \times 557.0 \, \mathrm{g/mol} = 41.78 \, \mathrm{g}\].

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Balanced Chemical Equation
A balanced chemical equation is fundamental in understanding reactions, as it ensures the conservation of mass. In our example reaction, lead(II) nitrate \(\mathrm{Pb(NO_3)_2}\) reacts with potassium iodate \(\mathrm{KIO_3}\). This reaction can be summarized as follows: \[\mathrm{Pb(NO_3)_2(aq) + 2KIO_3(aq) \rightarrow Pb(IO_3)_2(s) + 2KNO_3(aq)}\].
Here, the equation is balanced because there is an equal number of each type of atom on both sides of the equation. For instance, we have 1 lead (Pb) atom, 2 iodine (I) atoms, and 6 oxygen (O) atoms on each side. No atoms are lost or gained, they are just rearranged.
Understanding how to balance a chemical equation is crucial for predicting the products of a reaction.
Limiting Reactant
When two or more reactants are involved in a chemical reaction, the limiting reactant determines the maximum amount of product that can be formed. It is the reactant that is completely used up first, stopping the reaction from proceeding further.
In our scenario, moles of \(\mathrm{Pb(NO_3)_2}\) and \(\mathrm{KIO_3}\) are calculated, yielding 0.0750 moles and 0.150 moles respectively. According to the chemical equation, 2 moles of \(\mathrm{KIO_3}\) are necessary for every mole of \(\mathrm{Pb(NO_3)_2}\). Thus, precisely 0.150 moles of \(\mathrm{KIO_3}\) will react with 0.0750 moles of \(\mathrm{Pb(NO_3)_2}\).
Interestingly, in this case, both reactants are in perfect stoichiometric balance.
Moles Calculation
Calculating moles is an essential step in stoichiometry to understand the relationships between different reactants and products. The number of moles can be determined using the molarity formula: \[\text{Moles} = \text{Molarity} \times \text{Volume (L)}\].
For \(\mathrm{Pb(NO_3)_2}\), with a molarity of 3.00 M and a volume of 25.0 mL (0.0250 L), the number of moles is \(3.00 \times 0.0250 = 0.0750\) mol. Similarly, for \(\mathrm{KIO_3}\), with 5.00 M and 30.0 mL (0.0300 L), it results in \(5.00 \times 0.0300 = 0.150\) mol.
This calculation provides a crucial foundation for further steps like identifying the limiting reactant and computing the mass of the precipitate.
Precipitate Mass
The mass of the precipitate formed is the final goal of this reaction analysis. Once we determine the moles of the precipitate \(\mathrm{Pb(IO_3)_2}\), we move to calculate its mass. With 0.0750 moles of \(\mathrm{Pb(IO_3)_2}\) formed, we multiply this by the molar mass to get the mass: \[\text{Mass} = \text{Moles} \times \text{Molar Mass}\].
The molar mass of \(\mathrm{Pb(IO_3)_2}\) is calculated by adding the atomic masses of its components: \(\mathrm{Pb} = 207.2\, \mathrm{g/mol}, \ 2 \times \mathrm{I} = 253.8\, \mathrm{g/mol}, \ \text{and} \ 6 \times \mathrm{O} = 96\, \mathrm{g/mol}\).
This totals to 557.0 g/mol. Multiplying by the moles gives us \(0.0750 \times 557.0 = 41.78\, \mathrm{g}\). This value represents the mass of the \(\mathrm{Pb(IO_3)_2}\) precipitate.

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Most popular questions from this chapter

Calculate the number of moles of solute in (a) \(25.46\) milliliters of a \(0.1255 \mathrm{M} \mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}(a q)\) solution (b) \(50 \mu \mathrm{L}\) of a \(0.020 \mathrm{M} \mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}(a q)\) solution

What volume of \(1.250 \mathrm{M} \mathrm{HCl}(a q)\) is required to react with \(11.78\) grams of \(\mathrm{Na}_{2} \mathrm{CO}_{3}(s) ?\) The equation for the reaction is $$ \begin{aligned} \mathrm{Na}_{2} \mathrm{CO}_{3}(s)+2 \mathrm{HCl}(a q) & \rightarrow \\ & 2 \mathrm{NaCl}(a q)+\mathrm{H}_{2} \mathrm{O}(l)+\mathrm{CO}_{2}(g) \end{aligned} $$

Calcium chloride forms a hexahydrate, \(\mathrm{CaCl}_{2} \cdot 6 \mathrm{H}_{2} \mathrm{O}(s) .\) How many grams of \(\mathrm{CaCl}_{2} \cdot 6 \mathrm{H}_{2} \mathrm{O}(s)\) are required to make 500 milliliters of a solution having the same concentration of \(\mathrm{Cl}^{-}(a q)\) as one that was prepared by dissolving \(75.6\) grams of \(\mathrm{NaCl}(s)\) in enough water to make exactly one liter of solution?

What molarity of a \(\mathrm{CaCl}_{2}(a q)\) solution should you use if you want the molarity of the \(\mathrm{Cl}^{-}(a q)\) ions in the solution to be \(0.100 \mathrm{M} ?\)

Suppose we have a solution of lead nitrate, \(\mathrm{Pb}\left(\mathrm{NO}_{3}\right)_{2}(a q)\). A solution of \(\mathrm{NaCl}(a q)\) is added slowly until no further precipitation of \(\mathrm{PbCl}_{2}(s)\) occurs. The \(\mathrm{PbCl}_{2}(s)\) precipitate is collected by filtration, dried, and weighed. A total of \(12.79\) grams of \(\mathrm{PbCl}_{2}(s)\) is obtained from \(200.0\) milliliters of the original solution. Calculate the molarity of the \(\mathrm{Pb}\left(\mathrm{NO}_{3}\right)_{2}(a q)\) solution.

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