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The arsenic in an ore sample was converted into water-soluble sodium arsenate, \(\mathrm{Na}_{9} \mathrm{AsO}_{4}(a q)\). From the solution of \(\mathrm{Na}_{9} \mathrm{AsO}_{4}(a q)\), insoluble silver arsenate, \(\mathrm{Ag}_{9} \mathrm{AsO}_{4}(s)\), was precipitated and weighed. \(\mathrm{A}\) \(5.00\) -gram ore sample produced \(3.09\) grams of silver arsenate. Calculate the mass percentage of arsenic in the ore sample.

Short Answer

Expert verified
The mass percentage of arsenic in the ore is approximately 4.62%.

Step by step solution

01

Calculate Molar Masses

First, we need to calculate the molar masses of silver arsenate, \( \mathrm{Ag}_{9}\mathrm{AsO}_{4} \), and arsenic, \( \mathrm{As} \). The molar mass of silver (\( \mathrm{Ag} \)) is \( 107.87 \, \text{g/mol} \), arsenic (\( \mathrm{As} \)) is \( 74.92 \, \text{g/mol} \), and oxygen (\( \mathrm{O} \)) is \( 16.00 \, \text{g/mol} \). Therefore, the molar mass of silver arsenate is calculated as follows:\[9(107.87) + 74.92 + 4(16.00) = 7(107.87) + 74.92 + 4(16.00) = 864.6 + 74.92 + 64.00 = 1003.52 \, \text{g/mol} \]
02

Determine Moles of Precipitate

Using the mass of \( 3.09 \, \text{g} \) of silver arsenate, calculate the moles:\[\text{Moles of } \mathrm{Ag}_{9}\mathrm{AsO}_{4} = \frac{3.09 \, \text{g}}{1003.52 \, \text{g/mol}} \approx 0.00308 \, \text{mol}\]
03

Calculate Moles of Arsenic in Precipitate

Since each formula unit of \( \mathrm{Ag}_{9}\mathrm{AsO}_{4} \) contains one arsenic atom, the moles of arsenic is equal to the moles of \( \mathrm{Ag}_{9}\mathrm{AsO}_{4} \):\[\text{Moles of As} = 0.00308 \, \text{mol}\]
04

Determine Mass of Arsenic

Now, we calculate the mass of arsenic:\[\text{Mass of As} = 0.00308 \, \text{mol} \times 74.92 \, \text{g/mol} \approx 0.231 \, \text{g}\]
05

Calculate Mass Percentage of Arsenic

Finally, determine the mass percentage of arsenic in the original ore sample. The ore sample weighs \( 5.00 \, \text{g} \):\[\text{Mass percentage of As} = \left(\frac{0.231 \, \text{g}}{5.00 \, \text{g}}\right) \times 100\% \approx 4.62\%\]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molar Mass
Calculating molar mass is fundamental in chemistry as it helps you understand how much one mole of a compound weighs. A "molar mass" is the weight of all atoms in a molecule expressed in grams per mole. For example, when determining the molar mass of silver arsenate \( \mathrm{Ag}_9\mathrm{AsO}_4 \), you must sum all the atomic masses from the periodic table:
  • Silver (Ag) has an atomic mass of 107.87 g/mol. There are nine silver atoms, so we calculate \( 9 \times 107.87 \).
  • Arsenic (As) has an atomic mass of 74.92 g/mol, and there is one arsenic atom.
  • Oxygen (O) has an atomic mass of 16.00 g/mol, with four oxygen atoms contributing \( 4 \times 16.00 \).
Add these values together to find the molar mass of \( \mathrm{Ag}_9\mathrm{AsO}_4 \), which equals 1003.52 g/mol. Understanding molar mass is crucial because it connects the mass of a substance to the amount of chemical substance in moles used in reactions.
Stoichiometry
Stoichiometry is the study of measuring quantities in chemical reactions. It allows us to calculate quantities like mass, volume, or number of particles. To apply stoichiometry in this exercise, we used it to convert the mass of silver arsenate into moles. Start with the formula:The moles of \( \mathrm{Ag}_9\mathrm{AsO}_4 \) are found by dividing the mass by its molar mass: \[ \text{Moles of } \mathrm{Ag}_9\mathrm{AsO}_4 = \frac{3.09 \, \text{g}}{1003.52 \, \text{g/mol}} \approx 0.00308 \, \text{mol} \]In stoichiometry, the relationship between reactants and products can be determined, like how many moles of arsenic are in 0.00308 moles of silver arsenate. Here, each unit of silver arsenate contributes one atom of arsenic, showing the power of stoichiometry to reveal quantitative relationships in chemical processes.
Chemical Precipitation
Chemical precipitation is a process where a liquid solution becomes a solid by forming an "insoluble" compound. It is commonly used to isolate compounds, as done with silver arsenate in this case. During this process, the silver arsenate separates as a solid crystal out of the liquid solution. This technique is key in preparing or purifying substances in chemistry. In our problem, we used precipitation is part of a strategy to weigh the quantity of arsenic from the ore. It allows us to determine the quantity of a substance based on the solid form created, which in the example resulted in a measurable mass of 3.09 grams of precipitated silver arsenate. Understanding chemical precipitation's role is crucial in various industrial and scientific applications, such as wastewater treatment, where unwanted ions form precipitates to be removed from solutions. Learning the fundamentals of this concept provides insight into its practical uses in chemistry and its importance in analytical procedures.

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Most popular questions from this chapter

II-92. (*) A 30.450-milligram sample of a chemical known to contain only carbon, hydrogen, oxygen, and sulfur is put into a combustion analysis apparatus, yielding \(54.246\) milligrams of carbon dioxide and \(22.206\) milligrams of water. In another experiment, \(23.725\) milligrams of the compound is reacted with excess oxygen to produce \(10.255\) milligrams of sulfur dioxide. What is the empirical formula of the compound?

II-88. A police forensics lab is analyzing a sample of white powder found at a crime scene to determine if it is cocaine. Elemental analysis of the powder shows that it is \(67.31 \%\) carbon, \(6.978 \%\) hydrogen, \(4.618 \%\) nitrogen, and \(21.10 \%\) oxygen by mass. The chemical formula of cocaine is \(\mathrm{C}_{17} \mathrm{H}_{21} \mathrm{NO}_{4} .\) From this evidence, can the investigators conclude that the white powder is cocaine?

Chlorine is produced industrially by the electrolysis of brine (a solution of naturally occurring salts and consists mainly of sodium chloride). The reaction is described by the equation $$ \begin{aligned} 2 \mathrm{NaCl}(a q)+2 \mathrm{H}_{2} \mathrm{O}(l) & \stackrel{\text { electrolysis }}{\longrightarrow} \\ & 2 \mathrm{NaOH}(a q)+\mathrm{Cl}_{2}(g)+\mathrm{H}_{2}(g) \end{aligned} $$ The other products, sodium hydroxide and hydrogen, are also valuable commercial compounds. How many kilograms of each product can be obtained from the electrolysis of \(1.00\) kilogram of salt that is \(95 \%\) sodium chloride by mass?

Small quantities of oxygen can be prepared in the laboratory by heating potassium chlorate, \(\mathrm{KClO}_{3}(s)\). The equation for the reaction is $$ 2 \mathrm{KClO}_{3}(s) \rightarrow 2 \mathrm{KCl}(s)+3 \mathrm{O}_{2}(g) $$ Calculate how many grams of \(\mathrm{O}_{2}(g)\) can be produced from heating \(10.0\) grams of \(\mathrm{KClO}_{3}(s)\).

The concept of determining which reactant is limiting and which is in excess is akin to determining the number of sandwiches that can be made from a set number of ingredients. Assuming that a cheese sandwich consists of 2 slices of bread and 3 slices of cheese, determine the number of cheese sandwiches that can be prepared from a loaf of 24 slices of bread and a package of 40 slices of cheese. Which of the two ingredients limits the number of sandwiches that can be made? What quantity of the ingredient in excess remains?

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