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A solution containing \(17.5\) grams of cadmium chloride is mixed with a solution containing \(35.5\) grams of silver perchlorate. (a) Write the balanced chemical equation for this reaction. (b) Determine how many grams of silver chloride are produced after the reaction comes to completion. (c) How many grams of the reactant in excess will remain after the reaction?

Short Answer

Expert verified
(a) CdCl₂ + 2AgClO₄ → 2AgCl + Cd(ClO₄)₂; (b) 24.54 grams of AgCl; (c) 1.80 grams of CdCl₂ remain.

Step by step solution

01

Write the Balanced Chemical Equation

The chemical reaction between cadmium chloride (CdClâ‚‚) and silver perchlorate (AgClOâ‚„) leads to the formation of silver chloride (AgCl) and cadmium perchlorate (Cd(ClOâ‚„)â‚‚). The balanced equation is:\[\text{CdCl}_2 + 2\text{AgClO}_4 \rightarrow 2\text{AgCl} + \text{Cd(ClO}_4)_2\]
02

Calculate the Moles of Reactants

First, calculate the molar mass of each reactant:- Cadmium chloride (CdClâ‚‚): \(112.41 + 2 \times 35.45 = 183.31\) g/mol.- Silver perchlorate (AgClOâ‚„): \(107.87 + 35.45 + 4 \times 16.00 = 207.32\) g/mol.Calculate the moles:- Moles of CdClâ‚‚: \(\frac{17.5}{183.31} \approx 0.0955\) moles.- Moles of AgClOâ‚„: \(\frac{35.5}{207.32} \approx 0.1713\) moles.
03

Identify the Limiting Reactant

From the balanced equation, we see that 1 mole of CdClâ‚‚ reacts with 2 moles of AgClOâ‚„. Therefore, the required moles of AgClOâ‚„ to react with 0.0955 moles of CdClâ‚‚ is \(2 \times 0.0955 = 0.191\) moles. Since we only have 0.1713 moles of AgClOâ‚„, it is the limiting reactant.
04

Calculate Grams of Silver Chloride Produced

From the balanced equation, 2 moles of AgCl are produced for every 2 moles of AgClOâ‚„ that react. Therefore, 0.1713 moles of AgClOâ‚„ will produce 0.1713 moles of AgCl.The molar mass of AgCl is:\(107.87 + 35.45 = 143.32\) g/mol.Grams of AgCl = \(0.1713 \times 143.32 = 24.54\) grams.
05

Calculate Excess Reactant Remaining

Initially, we calculated that we have 0.0955 moles of CdClâ‚‚. Using the limiting reactant (AgClOâ‚„), we find that all 0.1713 moles of it react, using \(0.1713 / 2 = 0.08565\) moles of CdClâ‚‚.Moles of CdClâ‚‚ remaining = \(0.0955 - 0.08565 = 0.00985\) moles.Grams of CdClâ‚‚ remaining = \(0.00985 \times 183.31 = 1.80\) grams.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Balanced Chemical Equation
In chemical reactions, a balanced chemical equation is crucial. It represents how substances interact. Every element in the reaction must be equal on both the reactant and product sides of the equation. This maintains the principle of conservation of mass, which states that matter cannot be created nor destroyed in a chemical reaction.
For example, consider the reaction between cadmium chloride \( \text{CdCl}_2 \) and silver perchlorate \( \text{AgClO}_4 \). The balanced chemical equation is:\[ \text{CdCl}_2 + 2 \text{AgClO}_4 \rightarrow 2 \text{AgCl} + \text{Cd(ClO}_4)_2 \].
This equation shows us that one molecule of cadmium chloride reacts with two molecules of silver perchlorate to produce two molecules of silver chloride and one molecule of cadmium perchlorate. Balancing equations helps to predict the amount of products formed and the reactants consumed.
Limiting Reactant
In any chemical reaction, the limiting reactant determines the amount of product formed. It is the reactant that is entirely consumed when the reaction goes to completion. Once the limiting reactant is used up, the reaction stops.
To identify the limiting reactant, compare the mole ratios of the reactants to those required by the balanced equation.
  • Use the balanced equation to find the moles each reactant should provide.
  • The smallest ratio indicates the limiting reactant.
In our example, silver perchlorate is the limiting reactant because it has fewer moles compared to what is needed to react completely with cadmium chloride. This determines the maximum amount of silver chloride that can be produced in the reaction.
Reactant in Excess
The reactant in excess is what remains after the limiting reactant has been fully consumed. It's the substance that is left over at the end of the reaction.
To find the excess amount, follow these steps:
  • Calculate the moles of the limiting reactant used.
  • Use the mole ratio from the balanced equation to find how much of the excess reactant should have reacted.
  • Subtract this amount from the initial moles of the excess reactant.
In the case of cadmium chloride reacting with silver perchlorate, since cadmium chloride is in excess, it will not all react. We found that \(0.00985\) moles or \(1.80\) grams of cadmium chloride remained unreacted.
Molar Mass Calculations
Molar mass is essential in stoichiometry for converting between grams and moles. Each element has a specific atomic mass, and the molar mass of a compound is the sum of the atomic masses of the elements in its formula.
To calculate the molar mass:
  • Identify all the elements in the compound.
  • Add up the atomic masses of each element according to their proportions in the compound.
For example, to find the molar mass of cadmium chloride \( \text{CdCl}_2 \), add cadmium's atomic mass (112.41 g/mol) and twice the atomic mass of chlorine, since there are two chlorine atoms \(2 \times 35.45 = 70.90\)g/mol, totaling \(183.31\) g/mol.
Perform similar calculations for other compounds involved to help quantify and compare reactants and products in chemical reactions.

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