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Name the following oxyacids: (a) \(\mathrm{HNO}_{2}(a q)\) (b) \(\mathrm{H}_{2} \mathrm{SO}_{2}(a q)\) (c) \(\mathrm{HClO}_{2}(a q)\) (d) \(\mathrm{HIO}_{3}(a q)\)

Short Answer

Expert verified
(a) Nitrous acid, (b) Hyposulfurous acid, (c) Chlorous acid, (d) Iodic acid.

Step by step solution

01

Identify the Root Anion

The first step in naming an oxyacid is to identify the polyatomic ion present in the formula. These ions typically have names ending in either '-ite' or '-ate'. For (a) HNO鈧, the polyatomic ion is nitrite (NO鈧傗伝). For (b) H鈧係O鈧, the polyatomic ion is hyposulfite (SO鈧偮测伝). For (c) HClO鈧, the polyatomic ion is chlorite (ClO鈧傗伝). For (d) HIO鈧, the polyatomic ion is iodate (IO鈧冣伝).
02

Determine the Acid Name Based on the Anion Ending

Oxyacids are named based on the suffix of the polyatomic ion name:- If the anion name ends in '-ite', the acid name changes to end in '-ous acid'.- If the anion name ends in '-ate', the acid name changes to end in '-ic acid'. (a) For nitrite (NO鈧傗伝), the acid is called nitrous acid. (b) For hyposulfite (SO鈧偮测伝), the acid is called hyposulfurous acid. (c) For chlorite (ClO鈧傗伝), the acid is called chlorous acid. (d) For iodate (IO鈧冣伝), the acid is called iodic acid.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Polyatomic ions
Polyatomic ions are charged particles consisting of multiple atoms bonded together. These ions can carry either a positive or negative charge, but in the context of oxyacids, we're particularly interested in negatively charged polyatomic ions that typically end in '-ite' or '-ate'.
For example, nitrite ( O鈧傗伝 ), chlorite ( ClO鈧傗伝 ), and iodate ( IO鈧冣伝 ) are all polyatomic ions that play a crucial role in determining the names of oxyacids. Each of these ions results from an acid losing a proton ( H鈦 ).
Understanding polyatomic ions is essential because they provide the base for naming oxyacids. Recognizing these ions in chemical formulas allows for the correct identification and naming of the corresponding oxyacids by noting their specific suffixes.
Acid naming
The process of naming oxyacids involves recognizing the suffix of the polyatomic ion and then modifying that suffix according to specific rules. When the polyatomic ion ends in '-ite', the ending of the oxyacid changes to '-ous'. When it ends in '-ate', the suffix switches to '-ic'.
For example:
  • Nitrite ( NO鈧傗伝 ) will form nitrous acid because of the '-ite' ending.
  • Chlorite ( ClO鈧傗伝 ) will become chlorous acid.
  • Iodate ( IO鈧冣伝 ) leads to iodic acid due to its '-ate' suffix.
This systematized approach provides consistency and helps chemists easily communicate the structure and properties of substances. The name directly hints at the original ion, aiding in understanding the chemical's behavior.
Chemical formulas
Chemical formulas are crucial for accurately representing substances, including oxyacids. These formulas convey vital information about the kinds and numbers of atoms in a compound. For oxyacids, the formulas include hydrogen ( H ), oxygen ( O ), and a central element which is part of the polyatomic anion.
Take for example HNO鈧 (nitrous acid), H鈧係O鈧 (hyposulfurous acid), and HClO鈧 (chlorous acid). Each formula begins with hydrogen, highlighting that these are acids. The composition and order of elements in the formula are significant, as they illustrate its structure and define its name through the polyatomic ion it derives from.
Understanding chemical formulas is crucial for interpreting not just the composition, but also the potential reactions and properties of the oxyacids.

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Most popular questions from this chapter

Complete and balance the equation for each of the following acid-base reactions, name the reaction products, and write the corresponding net ionic equation: (a) \(\mathrm{HClO}_{3}(a q)+\mathrm{Ba}(\mathrm{OH})_{2}(a q) \rightarrow\) (b) \(\mathrm{CH}_{3} \mathrm{COOH}(a q)+\mathrm{KOH}(a q) \rightarrow\) (c) \(\mathrm{HI}(a q)+\mathrm{Mg}(\mathrm{OH})_{2}(s) \rightarrow\) (d) \(\mathrm{H}_{2} \mathrm{SO}_{4}(a q)+\mathrm{RbOH}(a q) \rightarrow\)

Balance each equation and write the corresponding net ionic equation. (a) \(\mathrm{AgNO}_{3}(a q)+\mathrm{Na}_{2} \mathrm{~S}(a q) \rightarrow \mathrm{Ag}_{2} \mathrm{~S}(s)+\mathrm{NaNO}_{3}(a q)\) (b) \(\mathrm{H}_{2} \mathrm{SO}_{4}(a q)+\mathrm{Pb}\left(\mathrm{NO}_{3}\right)_{2}(a q) \rightarrow\) \(\mathrm{PbSO}_{4}(s)+\mathrm{HNO}_{3}(a q)\) (c) \(\mathrm{Hg}\left(\mathrm{NO}_{3}\right)_{2}(a q)+\mathrm{NaI}(a q) \rightarrow \mathrm{HgI}_{2}(s)+\mathrm{NaNO}_{3}(a q)\) (d) \(\mathrm{CdCl}_{2}(a q)+\mathrm{AgClO}_{4}(a q) \rightarrow\) \(\mathrm{AgCl}(s)+\mathrm{Cd}\left(\mathrm{ClO}_{4}\right)_{2}(a q)\)

Predict the products and write balanced chemical equations and net ionic equations for the following gas-forming reactions: (a) \(\mathrm{H}_{2} \mathrm{SO}_{4}(a q)+\mathrm{NaHCO}_{3}(s) \rightarrow\) (b) \(\mathrm{HNO}_{5}(a q)+\mathrm{CaS}(s) \rightarrow\) (c) \(\mathrm{HCl}(a q)+\mathrm{Na}_{2} \mathrm{SO}_{3}(a q) \rightarrow(\) Hint \(:\) Analogous to the reaction of acids with the carbonate ion.)

Complete and balance the equations for the following combination reactions: (a) \(\mathrm{Li}(s)+\mathrm{O}_{2}(g) \rightarrow\) (b) \(\mathrm{MgO}(s)+\mathrm{CO}_{2}(g) \rightarrow\) (c) \(\mathrm{H}_{2}(g)+\mathrm{O}_{2}(g) \rightarrow\) (d) \(\mathrm{N}_{2}(g)+\mathrm{H}_{2}(g) \rightarrow\)

Predict the products of the following reactions and write the balanced chemical equation. If no reaction occurs, then write "no reaction." (a) An aqueous solution of potassium chromate is mixed with an aqueous solution of lead(II) nitrate. (b) Hydrochloric acid is added to an aqueous solution of sodium sulfide. (c) An aqueous solution of barium hydroxide is mixed with an aqueous solution of zinc sulfate. (d) Solid calcium oxide is added to an aqueous solution of nitric acid.

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