Chapter 9: Problem 19
Which of the following contains both ionic and covalent bonds in the same compound? \(\mathrm{a} ) \mathrm{CO}_{3}{ }^{2-}\) b) \(\mathrm{BaSO}_{3}\) c) Sro d) HI e) \(\mathrm{MgS}\)
Short Answer
Expert verified
BaSO$_3$ has both ionic and covalent bonds.
Step by step solution
01
Identify Ionic Bonds
Ionic bonds form between metals and non-metals. Here, let's identify potential ionic compounds:
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**a) CO$_3^{2-}$:** Contains non-metals only (C and O), so no ionic bond.
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**b) BaSO$_3$:** Contains a metal (Ba) and non-metals (S and O), indicating the presence of an ionic bond between Ba and the sulfate group.
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**c) SrO:** Metal (Sr) and non-metal (O) combination, which indicates an ionic bond.
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**d) HI:** Contains different non-metals (H and I), which typically form covalent bonds.
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**e) MgS:** Metal (Mg) and non-metal (S), suggesting an ionic bond.
02
Identify Covalent Bonds
Covalent bonds form between non-metal atoms. Let's find out which compounds contain covalent bonds:
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**a) CO$_3^{2-}$:** The carbon and oxygen form covalent bonds within the carbonate ion (CO$_3^{2-}$).
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**b) BaSO$_3$:** The internal structure of the sulfate group (SO$_3^{2-}$) consists of covalent bonds between sulfur and oxygen.
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**c) SrO:** Does not contain distinct covalent bonds.
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**d) HI:** Consists of a covalent bond between hydrogen and iodine.
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**e) MgS:** Contains only ionic bonds.
03
Check for Both Bond Types in Single Compound
Determine which compound contains both ionic and covalent bonds:
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**a) CO$_3^{2-}$:** Only covalent bonds present.
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**b) BaSO$_3$:** Contains ionic bonds between Ba and SO$_3^{2-}$ and covalent bonds within SO$_3^{2-}$.
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**c) SrO:** Only ionic bonds.
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**d) HI:** Only covalent bonds.
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**e) MgS:** Only ionic bonds.
04
Conclusion
The compound that contains both ionic and covalent bonds is BaSO$_3$. This compound has ionic bonds between barium and the sulfate group, and covalent bonds within the sulfate group itself.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Ionic Bonds
Ionic bonds are a type of chemical bond formed between two atoms with opposing electric charges, typically a metal and a non-metal. In these bonds, the metal atom loses one or more electrons, becoming a positively charged ion, while the non-metal atom gains those electrons, becoming a negatively charged ion. This transfer of electrons results in an electrostatic attraction between the ions, which is the ionic bond.
Some key properties of ionic bonds include:
Some key properties of ionic bonds include:
- Formation between metals and non-metals
- High melting and boiling points due to strong bonds
- Conductivity when dissolved in water, as the ions are free to move
Covalent Bonds
Unlike ionic bonds, covalent bonds involve the sharing of electron pairs between atoms, typically non-metals. This sharing allows each atom to achieve a stable electron configuration, resembling that of a noble gas. Covalent bonds are generally found within molecules consisting of non-metal atoms.
Here are some characteristics of covalent bonds:
Here are some characteristics of covalent bonds:
- Formation between non-metal atoms
- Lower boiling and melting points compared to ionic compounds
- Poor electrical conductivity in solid and liquid forms
Compound Identification
To identify the type of bonds within a compound, one must first recognize the constituent elements and their properties. Knowing whether these elements are metals or non-metals aids in predicting the types of bonds they are likely to form.
A few steps for identifying compounds include:
A few steps for identifying compounds include:
- Determine the types of elements present (metal vs. non-metal)
- Recognize common ions, like sulfate (SO$_3^{2-}$) or carbonate (CO$_3^{2-}$)
- Identify the simplest whole-number ratio of elements in the compound
Bond Type Analysis
Bond type analysis involves dissecting a compound to identify its internal bonding characteristics. This includes determining the elements' positions in the periodic table and their typical bonding patterns.
To perform bond type analysis, consider these steps:
To perform bond type analysis, consider these steps:
- Evaluate whether elements are metals or non-metals
- Analyze if the compound contains polyatomic ions, which can involve a combination of bond types
- Look for internal structures within polyatomic ions to identify bond types