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Define an exothermic reaction and an endothermic reaction. Give an example of each.

Short Answer

Expert verified
Exothermic reactions release energy; example: combustion. Endothermic reactions absorb energy; example: photosynthesis.

Step by step solution

01

Understanding Exothermic Reactions

Exothermic reactions are chemical reactions that release energy, usually in the form of heat. During these reactions, the energy of the products is less than the energy of the reactants, resulting in a release of the excess energy to the surroundings.
02

Example of Exothermic Reaction

A common example of an exothermic reaction is combustion, such as the burning of natural gas. The reaction is: \( \text{CH}_4 + 2\text{O}_2 \rightarrow \text{CO}_2 + 2\text{H}_2\text{O} + \text{energy} \). This reaction releases a significant amount of heat.
03

Understanding Endothermic Reactions

Endothermic reactions are chemical reactions that absorb energy from their surroundings. In these reactions, the energy of the products is greater than the energy of the reactants, so they require an input of energy to occur.
04

Example of Endothermic Reaction

An example of an endothermic reaction is photosynthesis. In this process, plants absorb energy from sunlight to convert carbon dioxide and water into glucose and oxygen: \( 6\text{CO}_2 + 6\text{H}_2\text{O} + \text{energy} \rightarrow \text{C}_6\text{H}_{12}\text{O}_6 + 6\text{O}_2 \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Exothermic Reactions
Exothermic reactions are fascinating phenomena in chemistry where energy is released into the environment. Imagine lighting a match. The warmth you feel is due to an exothermic reaction.

When these reactions occur, the energy level of the reactants is higher than that of the products. The excess energy, often felt as heat, is then liberated into the surroundings. This is why we notice a temperature rise in the environment. A practical example is combustion, such as burning wood or fuel. During combustion, the chemical bonds in substances are broken and new ones are formed. This rearrangement releases energy that powers engines and heats our homes.
  • Characteristics of Exothermic Reactions:
    • Release heat
    • Temperature of surroundings increases
    • Energy of products is less than reactants
Endothermic Reactions
Endothermic reactions work in the opposite way to exothermic reactions. These reactions absorb energy from the surroundings.

In an endothermic reaction, the energy of the products is greater than that of the reactants, making the system absorb energy. Such reactions might feel cold to the touch as they draw heat into themselves. A common example is the process of photosynthesis in plants. During photosynthesis, plants take in sunlight and use its energy to transform carbon dioxide and water into glucose and oxygen.
  • Traits of Endothermic Reactions:
    • Absorb heat
    • Cooler surroundings
    • Require energy input
Combustion Reaction
Combustion reactions are a specific subset of exothermic reactions known for producing heat & light. When a substance combusts, it reacts rapidly with oxygen. This process releases energy.

Combustion is critical not only in everyday activities like cooking or heating but also in important industrial processes. Essential fuels like natural gas, gasoline, and charcoal undergo combustion. In a typical combustion reaction, such as burning methane gas:\( \text{CH}_4 + 2\text{O}_2 \rightarrow \text{CO}_2 + 2\text{H}_2\text{O} + \text{energy} \),methane reacts with oxygen to produce carbon dioxide and water, releasing energy. This energy release is why our cars can move and why energy sectors depend heavily on combustion processes.
  • Characteristics of Combustion:
    • Rapid reaction with oxygen
    • Substantial energy release
    • Formation of new products
Photosynthesis
The process of photosynthesis is a marvel of nature, where plants convert light energy into chemical energy. It is an essential endothermic reaction that sustains life on Earth by fueling the energy needs of plants and, indirectly, all other living things.

In photosynthesis, plants capture sunlight using chlorophyll, a green pigment found in plant cells. Using sunlight, carbon dioxide from the air, and water from the soil, plants produce glucose and oxygen. The reaction is represented by:\( 6\text{CO}_2 + 6\text{H}_2\text{O} + \text{energy} \rightarrow \text{C}_6\text{H}_{12}\text{O}_6 + 6\text{O}_2 \).This process plays a crucial role in regulating the atmosphere, providing oxygen, and serving as the foundation of most food chains. It is a clear demonstration of an endothermic reaction benefiting the entire ecosystem.
  • Key Points about Photosynthesis:
    • Converts solar energy to chemical energy
    • Produces oxygen as a by-product
    • Essential for plant growth and energy storage

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Most popular questions from this chapter

Hydrogen sulfide, \(\mathrm{H}_{2} \mathrm{~S}\), is a poisonous gas with the odor of rotten eggs. The reaction for the formation of \(\mathrm{H}_{2} \mathrm{~S}\) from the elements is $$ \mathrm{H}_{2}(g)+\frac{1}{8} \mathrm{~S}_{8}(\text { rhombic }) \longrightarrow \mathrm{H}_{2} \mathrm{~S}(g) $$ Use Hess's law to obtain the enthalpy change for this reaction from the following enthalpy changes: $$ \begin{array}{c} \mathrm{H}_{2} \mathrm{~S}(g)+\frac{3}{2} \mathrm{O}_{2}(g) \longrightarrow \mathrm{H}_{2} \mathrm{O}(g)+\mathrm{SO}_{2}(g) ; \Delta H=-518 \mathrm{~kJ} \\\ \mathrm{H}_{2}(g)+\frac{1}{2} \mathrm{O}_{2}(g) \longrightarrow \mathrm{H}_{2} \mathrm{O}(g) ; \Delta H=-242 \mathrm{~kJ} \\ \frac{1}{8} \mathrm{~S}_{8}(\text { rhombic })+\mathrm{O}_{2}(g) \longrightarrow \mathrm{SO}_{2}(g) ; \Delta H=-297 \mathrm{~kJ} \end{array} $$

A piece of iron was heated to \(95.4^{\circ} \mathrm{C}\) and dropped into a constant-pressure calorimeter containing \(284 \mathrm{~g}\) of water at \(32.2^{\circ} \mathrm{C}\). The final temperature of the water and iron was \(51.9^{\circ} \mathrm{C}\). Assuming that the calorimeter itself absorbs a negligible amount of heat, what was the mass (in grams) of the piece of iron? The specific heat of iron is \(0.449 \mathrm{~J} /\left(\mathrm{g} \cdot{ }^{\circ} \mathrm{C}\right)\), and the specific heat of water is \(4.18 \mathrm{~J} /\) \(\left(\mathrm{g} \cdot{ }^{\circ} \mathrm{C}\right)\)

Ammonia will burn in the presence of a platinum catalyst to produce nitric oxide, NO. $$ 4 \mathrm{NH}_{3}(g)+5 \mathrm{O}_{2}(g) \longrightarrow 4 \mathrm{NO}(g)+6 \mathrm{H}_{2} \mathrm{O}(g) $$ What is the heat of reaction at constant pressure? Use the following thermochemical equations: $$ \begin{aligned} \mathrm{N}_{2}(g)+\mathrm{O}_{2}(g) & \longrightarrow 2 \mathrm{NO}(g) ; \Delta H=180.6 \mathrm{~kJ} \\ \mathrm{~N}_{2}(g)+3 \mathrm{H}_{2}(g) \longrightarrow 2 \mathrm{NH}_{3}(g) ; \Delta H &=-91.8 \mathrm{~kJ} \\ 2 \mathrm{H}_{2}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}(g) ; \Delta H=-483.7 \mathrm{~kJ} \end{aligned} $$

A rebreathing gas mask contains potassium superoxide, \(\mathrm{KO}_{2}\), which reacts with moisture in the breath to give oxygen. $$ 4 \mathrm{KO}_{2}(s)+2 \mathrm{H}_{2} \mathrm{O}(l) \longrightarrow 4 \mathrm{KOH}(s)+3 \mathrm{O}_{2}(g) $$ Estimate the grams of potassium superoxide required to supply a person's oxygen needs for one hour. Assume a person requires \(1.00 \times 10^{2} \mathrm{kcal}\) of energy for this time period. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, \(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6},\) to \(\mathrm{CO}_{2}(g)\) and \(\mathrm{H}_{2} \mathrm{O}(l)\). From the amount of glucose required to give \(1.00 \times 10^{2} \mathrm{kcal}\) of heat, calculate the amount of oxygen consumed and hence the amount of \(\mathrm{KO}_{2}\) required. The \(\Delta H_{f}^{\circ}\) for glucose \((s)\) is \(-1273 \mathrm{~kJ} / \mathrm{mol}\).

Potassium superoxide, \(\mathrm{KO}_{2}\), is used in some rebreathing gas masks (in which the exhaled breath is recycled in a closed space). Water vapor in the exhaled air reacts with potassium superoxide to produce oxygen gas: $$ 4 \mathrm{KO}_{2}(s)+2 \mathrm{H}_{2} \mathrm{O}(l) \longrightarrow 4 \mathrm{KOH}(s)+3 \mathrm{O}_{2}(g) $$ In an experiment at \(25^{\circ} \mathrm{C}\) and \(1.00 \mathrm{~atm}\) in which water vapor reacts with a quantity of potassium superoxide, it was found that \(2.70 \mathrm{~kJ}\) of heat was absorbed. The oxygen gas produced was then collected at \(23.0^{\circ} \mathrm{C}\) and \(789 \mathrm{mmHg}\). What volume (in liters) of oxygen was collected?

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