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Complete and balance the following equations. $$ \begin{array}{l} \mathrm{CO}_{2}(g)+\mathrm{Ba}(\mathrm{OH})_{2}(a q) \longrightarrow \\ \mathrm{MgCO}_{3}(s)+\operatorname{HBr}(a q) \longrightarrow \end{array} $$

Short Answer

Expert verified
The balanced equations are: \( \mathrm{CO}_{2} + \mathrm{Ba(OH)}_{2} \rightarrow \mathrm{BaCO}_{3} + \mathrm{H}_{2}\mathrm{O} \) and \( \mathrm{MgCO}_{3} + 2\mathrm{HBr} \rightarrow \mathrm{MgBr}_{2} + \mathrm{CO}_{2} + \mathrm{H}_{2}\mathrm{O} \).

Step by step solution

01

Write the Unbalanced Equation for Reaction 1

The first reaction involves carbon dioxide and barium hydroxide. The equation given is: \( \mathrm{CO}_{2}(g) + \mathrm{Ba(OH)}_{2}(aq) \rightarrow \ldots \). This reaction will likely produce barium carbonate and water: \( \mathrm{BaCO}_{3}(s) + \mathrm{H}_{2}\mathrm{O}(l)\).
02

Balance the First Reaction

To balance this equation: \( \mathrm{CO}_{2}(g) + \mathrm{Ba(OH)}_{2}(aq) \rightarrow \mathrm{BaCO}_{3}(s) + \mathrm{H}_{2}\mathrm{O}(l) \), check each element:- Carbon: 1 on both sides- Oxygen: 2 (from CO2) + 2 (from Ba(OH)2) = 4 and 3 (in BaCO3) + 1 (in H2O) = 4- Barium: 1 on both sides- Hydrogen: 2 on both sidesThe reaction is balanced as written.
03

Write the Unbalanced Equation for Reaction 2

The second reaction involves magnesium carbonate and hydrobromic acid. The equation given is: \( \mathrm{MgCO}_{3}(s) + \mathrm{HBr}(aq) \rightarrow \ldots \). This reaction will likely produce magnesium bromide, carbon dioxide, and water: \( \mathrm{MgBr}_{2}(aq) + \mathrm{CO}_{2}(g) + \mathrm{H}_{2}\mathrm{O}(l) \).
04

Balance the Second Reaction

To balance this equation, start with \( \mathrm{MgCO}_{3}(s) + 2\mathrm{HBr}(aq) \rightarrow \mathrm{MgBr}_{2}(aq) + \mathrm{CO}_{2}(g) + \mathrm{H}_{2}\mathrm{O}(l) \), check each element:- Magnesium: 1 on both sides- Carbon: 1 on both sides- Oxygen: 3 on both sides- Hydrogen: 2 on both sides- Bromine: 2 on both sidesThe reaction is balanced as written.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical reactions
Chemical reactions are processes where reactants transform into products via chemical changes. This transformation involves breaking existing bonds and forming new ones. Every day, you see chemical reactions take place, from rusting iron to digesting food.
In any chemical reaction, it's crucial to consider the conservation of mass. This means that the number of atoms for each element must remain constant, both in the reactants and the products. Properly representing the reaction in a balanced equation enforces the conservation of mass. It's like ensuring ingredients match the portion needed in a recipe!
Writing and balancing these equations involves:
  • Identifying reactants and potential products
  • Adjusting coefficients to have equal numbers of atoms for each element on both sides
This forms the foundational step in stoichiometry and understanding chemical kinetics.
Barium carbonate formation
Barium carbonate (\(\mathrm{BaCO_3}\)) forms as a compound typically through reactions involving barium and carbonate ions. In this specific chemical reaction, carbon dioxide (\(\mathrm{CO_2}\)) reacts with barium hydroxide (\(\mathrm{Ba(OH)_2}\)) to produce barium carbonate and water.
This process can be generalized as a double displacement reaction where ions swap partners. Here, it can be depicted as: \[\mathrm{CO_2(g) + Ba(OH)_2(aq) \rightarrow BaCO_3(s) + H_2O(l)}\] Barium carbonate precipitates to form a solid, indicating the completion of this reaction. This balancing ensures:
  • 1 carbon atom on both sides
  • 4 oxygen atoms from reactants equal 4 in the products
  • 2 hydrogen atoms maintaining balance
Thus, this reaction is balanced, maintaining mass conservation.
Magnesium bromide formation
Magnesium bromide (\(\mathrm{MgBr_2}\)) is created by reacting magnesium carbonate (\(\mathrm{MgCO_3}\)) with hydrobromic acid (\(\mathrm{HBr}\)). This exchange involves a more complex transformation which includes multiple products.
In this reaction, exchanging ions results in magnesium bonding with bromine, leading to the formation of magnesium bromide, alongside the release of carbon dioxide and water:\[\mathrm{MgCO_3(s) + 2HBr(aq) \rightarrow MgBr_2(aq) + CO_2(g) + H_2O(l)}\] It's balanced ensuring:
  • 1 magnesium atom on both sides
  • Flexibility to balance bromine by using 2 \(\mathrm{HBr}\)
  • Products formed in stoichiometric relations
Correct balancing ensures that the conservation of mass and charge is maintained in this chemical process.
Stoichiometry
Stoichiometry is the heart of chemical calculations and is crucial for understanding chemical reactions. It involves the quantitative relationships and conversions based on balanced chemical equations to predict how much product forms or reactant is consumed in a reaction.
Using stoichiometry, one can deduce everything from reaction yields to limiting reactants. This concept uses the mole ratios derived from balanced equations to perform these calculations. For example, if given the balanced equation:\[\mathrm{MgCO_3(s) + 2HBr(aq) \rightarrow MgBr_2(aq) + CO_2(g) + H_2O(l)}\] once can calculate:
  • The amount of \(\mathrm{MgBr_2}\) produced from a given amount of \(\mathrm{MgCO_3}\)
  • The required \(\mathrm{HBr}\) to completely react with the available \(\mathrm{MgCO_3}\)
Thus, mastering stoichiometry is essential for all chemistry students aiming to excel in solving real-world problems.

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Most popular questions from this chapter

Complete and balance the following equations. \(\mathrm{KOH}(a q)+\mathrm{MgCl}_{2}(a q) \longrightarrow\) \(\mathrm{Mg}(s)+\mathrm{CuSO}_{4}(a q) \longrightarrow\) \(\mathrm{Sr}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow\) \(\mathrm{SrCO}_{3}(s)+\mathrm{HCl}(a q) \longrightarrow\) \(\mathrm{Ba}(\mathrm{OH})_{2}(a q)+\mathrm{CO}_{2}(g) \longrightarrow\)

A \(0.325-g\) sample of sulfur was burned in an excess of oxygen in the presence of a platinum catalyst. The final product of this combustion was then dissolved in water to give \(1.000 \mathrm{~L}\) of solution. To this solution was added \(75.6 \mathrm{~mL}\) of \(0.1028 \mathrm{M}\) aqueous \(\mathrm{BaCl}_{2}\), resulting in a white precipitate. This precipitate was filtered off, dried, and weighed. What was the product of the combustion of sulfur in excess oxygen? What was the solution obtained by dissolving this product in water? What was the white precipitate? What was the mass of this dried precipitate?

What happens to the metallic character of the maingroup elements as you move left to right across any row of the periodic table? What happens to the metallic character of the main-group elements as you move down a column (group)?

Write an equation for each of the following. burning of calcium metal in oxygen burning of phosphine, \(\mathrm{PH}_{3}\), in excess oxygen burning of ethanolamine, \(\mathrm{HOCH}_{2} \mathrm{CH}_{2} \mathrm{NH}_{2}\), in excess oxygen ( \(\mathrm{N}\) ends up as \(\mathrm{N}_{2}\) )

Francium- 223 is a radioactive alkali metal that decays by beta emission. Write the nuclear equation for this decay process.

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