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Keeping in mind that aqueous \(\mathrm{Cu}^{2+}\) is blue and aqueous \(\mathrm{Zn}^{2+}\) is colorless, predict what you would observe over a several-day period if you performed the following experiments. a. A strip of \(Z n\) is placed into a beaker containing aqueous \(\mathrm{Zn}^{2+}\). b. A strip of \(\mathrm{Cu}\) is placed into a beaker containing aqueous \(\mathrm{Cu}^{2+}\) c. A strip of \(Z n\) is placed into a beaker containing aqueous \(\mathrm{Cu}^{2+}\). d. A strip of \(\mathrm{Cu}\) is placed into a beaker containing aqueous \(\mathrm{Zn}^{2+}\).

Short Answer

Expert verified
C: Zn replaces Cu, solution fades; A, B, D: no change.

Step by step solution

01

Understanding the Reactivity Series

The reactivity series ranks metals by their ability to displace other metals from solutions of their ions. Zinc (Zn) is more reactive than Copper (Cu), meaning Zn can displace Cu from its solution, but not vice versa.
02

Predicting Observation for Experiment A

When a Zn strip is placed in a beaker with aqueous Zn虏鈦, there is no chemical change since both are the same element. Therefore, the strip remains unchanged, and the solution stays colorless.
03

Predicting Observation for Experiment B

When a Cu strip is placed in a beaker with aqueous Cu虏鈦, there will be no chemical reaction because they are the same element. The Cu strip remains unchanged, and the solution stays blue.
04

Predicting Observation for Experiment C

When Zn strip is placed in a beaker with aqueous Cu虏鈦, a displacement reaction occurs where Zn displaces Cu虏鈦 from the solution. You will observe the blue color fading as Cu虏鈦 ions get reduced to solid copper, forming on the Zn strip. The solution eventually becomes colorless.
05

Predicting Observation for Experiment D

When a Cu strip is placed in a beaker with aqueous Zn虏鈦, no reaction occurs because Cu is less reactive than Zn and cannot displace Zn虏鈦 ions. The copper strip remains unchanged, and the solution stays colorless.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Reactivity Series
The reactivity series is a ranking of metals from the most reactive to the least reactive. This sequence is crucial for predicting whether a displacement reaction will occur when a metal comes into contact with a solution of another metal's ions. Here's a simple way to visualize it:
  • Zinc (Zn) is higher in the reactivity series than Copper (Cu), indicating that Zn has a higher tendency to lose electrons and form positive ions.
  • Conversely, since Copper is lower in the series, it does not readily lose electrons compared to Zinc.

Understanding where metals, such as Zn and Cu, fall in the reactivity series helps determine their capability to participate in chemical reactions with metal ion solutions. The more reactive a metal, the better it can displace a less reactive metal from its compound.
Displacement Reactions
Displacement reactions occur when a more reactive metal displaces a less reactive metal from a solution of its ions. In essence, it "kicks out" the less reactive metal and takes its place. This can be observed in a very predictable pattern, based on the reactivity series, such as:
  • In Scenario A, where a Zn strip is placed in a solution of Zn虏鈦 ions, no displacement occurs as the metal and ion are the same.
  • Scenario B reveals that placing a Cu strip in Cu虏鈦 ions also results in no reaction since there is no "kicking out" action needed.

The true displacement is observed in Scenario C, where a Zn strip displaces Cu from a Cu虏鈦 solution. Here, Zn reduces Cu虏鈦 to solid Copper, with Zn dissolving to form Zn虏鈦 ions. This reaction showcases the ability of Zn to displace a less reactive Cu, demonstrating a key principle of displacement reactions.
In Scenario D, where a Cu strip is placed in Zn虏鈦 ions, there is no displacement. The reason is clear: Cu is less reactive than Zn and cannot displace Zn from the solution.
Metal Ion Solutions
Metal ion solutions are aqueous solutions that contain dispersed metal ions. These solutions are an important medium for observing chemical behaviors such as displacement reactions. The initial color of the solution can give us clues about the present metal ions:
  • With Cu虏鈦 ions in solution, the solution is characteristically blue.
  • Zn虏鈦 ions, on the other hand, form a colorless solution.
Analyzing these colors helps in recognizing the displacement activity in a reaction. For instance, when a Zn strip is placed into a Cu虏鈦 solution, the blue color gradually fades as the displacement proceeds, signifying the reduction of Cu虏鈦 ions to metallic Copper.
Understanding the behavior of metal ion solutions is crucial for predicting the outcomes of metal and ion interactions based on displacement reactions and reactivity series principles. By recognizing changes in solution color and the nature of metal ions involved, one can easily perceive the manifestations of chemical processes in action.

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Most popular questions from this chapter

Briefly explain why different products are obtained from the electrolysis of molten \(\mathrm{NaCl}\) and the electrolysis of a dilute aqueous solution of \(\mathrm{NaCl}\).

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