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Define an acid and a base according to the Br酶nstedLowry concept. Give an acid-base equation and identify each species as an acid or a base.

Short Answer

Expert verified
An acid donates a proton; a base accepts it. In \( \text{HCl} + \text{NH}_3 \rightarrow \text{NH}_4^+ + \text{Cl}^- \), HCl is the acid, and NH鈧 is the base.

Step by step solution

01

Define a Br酶nsted-Lowry Acid

According to the Br酶nsted-Lowry concept, an acid is a substance that donates a proton (H鈦 ion) to another substance during a chemical reaction.
02

Define a Br酶nsted-Lowry Base

According to the Br酶nsted-Lowry concept, a base is a substance that accepts a proton (H鈦 ion) from another substance during a chemical reaction.
03

Write an Acid-Base Equation

An example of an acid-base equation is the reaction between hydrochloric acid (HCl) and ammonia (NH鈧): \[ \text{HCl} + \text{NH}_3 \rightarrow \text{NH}_4^+ + \text{Cl}^- \]
04

Identify the Acid and Base in the Equation

-In the equation, HCl donates a proton to NH鈧, so HCl is the Br酶nsted-Lowry acid. -NH鈧 accepts a proton to form NH鈧勨伜, so NH鈧 is the Br酶nsted-Lowry base. -NH鈧勨伜 is the conjugate acid of the base NH鈧, and Cl鈦 is the conjugate base of the acid HCl.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Proton Donor
In the Br酶nsted-Lowry acid-base theory, an acid is defined as a proton donor. This definition expands upon the traditional visualization of acids, which often simply focused on molecules like HCl dissolving in water. When we say that an acid donates a proton, we specifically mean that the acid releases a hydrogen ion (\(H^+\)) in a reaction. This hydrogen ion is essentially a free proton due to the fact that hydrogen, in its ionic state, has no electrons to shield its positively charged nucleus.

For example, consider hydrochloric acid (HCl) in a reaction:
  • HCl interacts with a base, like ammonia (NH鈧), during which HCl donates a proton.
  • This donation transforms HCl into its conjugate base, Cl鈦.
The act of donating changes the initial acid into a new species. Understanding this concept of a 鈥榩roton donor鈥 is crucial for grasping why an acid can act in such a way and turn into a conjugate base as a result of the reaction.
Proton Acceptor
A fundamental aspect of Br酶nsted-Lowry theory is the characterization of a base as a proton acceptor. In a chemical reaction, a base accepts a hydrogen ion (\(H^+\)), allowing it to play a complementary role to the acid, which donates the proton. This transformation is visible in reactions where a substance like ammonia (NH鈧) is present.

During a reaction, a proton acceptor:
  • Gains a hydrogen ion, thereby transforming itself into its conjugate acid.
  • Undergoes a change in structure or charge, such as NH鈧 becoming NH鈧勨伜 upon accepting a proton from HCl.
Recognizing bases as proton acceptors provides a broader understanding of chemical reactivity and the interchange of particles during reactions. By accepting the proton, the base forms a different chemical species, encapsulating the dynamic nature of acid-base interactions.
Conjugate Acid-Base Pairs
Every time an acid donates a proton, it forms what is known as a conjugate base. Similarly, when a base accepts a proton, it converts into a conjugate acid. The pairing of these transformations forms what is called a conjugate acid-base pair. This concept is central to understanding the Br酶nsted-Lowry acid-base theory as it highlights the reversible nature of proton transfer reactions.

For instance, in the reaction between HCl and NH鈧:
  • HCl acts as an acid, donating a proton to become Cl鈦, its conjugate base.
  • NH鈧 acts as a base, accepting a proton to become NH鈧勨伜, its conjugate acid.
These paired transformations illustrate the balance and equilibrium that can exist in chemical reactions. By identifying these pairs, chemists can predict the direction of the chemical equilibrium and understand how different molecules interact in a given environment.

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Most popular questions from this chapter

A sample of grape juice has a pH of 4.15 . What is the hydroxide-ion concentration of this solution?

You can obtain the pH of a \(0.100 \mathrm{M} \mathrm{HCl}\) solution by assuming that all of the \(\mathrm{H}_{3} \mathrm{O}^{+}\) ion comes from the \(\mathrm{HCl}\), in which case the \(\mathrm{pH}\) equals \(-\log 0.100=1.00 .\) But if you want the \(\mathrm{pH}\) of a solution that is \(1.00 \times 10^{-7} \mathrm{M} \mathrm{HCl}\), you also need to account for \(\mathrm{H}_{3} \mathrm{O}^{+}\) ion coming from water. (Why?) Note that the auto-ionization of water is the only equilibrium you need to account for. What is the \(\mathrm{pH}\) of \(1.00 \times 10^{-7} \mathrm{M} \mathrm{HCl} ?\)

A sample of apple cider has a pH of 3.75 . What is the hydroxide-ion concentration of this solution?

Which of the following \(\mathrm{pH}\) values indicate an acidic solution at \(25^{\circ} \mathrm{C} ?\) Which are basic and which are neutral? a) 12.9 b 8.9 c) 5.1 d) 1.6

Strong Acids, Weak Acids, and pH Two 0.10 -mol samples of the hypothetical monoprotic acids \(\mathrm{HA}(a q)\) and \(\mathrm{HB}(a q)\) are used to prepare \(1.0 \mathrm{-} \mathrm{L}\) stock solutions of each acid. a)Write the chemical reactions for these acids in water. What are the concentrations of the two acid solutions? b)One of these acids is a strong acid, and one is weak. What could you measure that would tell you which acid was strong and which was weak? c)Say that the \(\mathrm{HA}(a q)\) solution has a \(\mathrm{pH}\) of 3.7 . Is this the stronger of the two acids? How did you arrive at your answer? d)What is the concentration of \(\mathrm{A}^{-}(a q)\) in the HA solution described in part \(\mathrm{c}\) ? e)If \(\mathrm{HB}(a q)\) is a strong acid, what is the hydronium-ion concentration? f) In the solution of \(\mathrm{HB}(a q),\) which of the followin would you expect to be in the greatest concentration \(\mathrm{H}_{3} \mathrm{O}^{+}(a q), \mathrm{B}^{-}(a q), \mathrm{HB}(a q),\) or \(\mathrm{OH}^{-}(a q) ?\) How did yo decide? g)In the solution of \(\mathrm{HA}(a q),\) which of the following would you expect to be in the greatest concentration: \(\mathrm{H}_{3} \mathrm{O}^{+}(a q), \mathrm{A}^{-}(a q), \mathrm{HA}(a q),\) or \(\mathrm{OH}^{-}(a q) ?\) How did you decide? h) Say you add \(1.0 \mathrm{~L}\) of pure water to a solution of \(\mathrm{HB}\). Would this water addition make the solution more acidic, make it less acidic, or not change the acidity of the original solution? Be sure to fully justify your answer. i) You prepare a \(1.0-\mathrm{L}\) solution of \(\mathrm{HA}\). You then take a \(200-\mathrm{mL}\) sample of this solution and place it into a separate container. Would this \(200 \mathrm{~mL}\) sample be more acidic, be less acidic, or have the same acidity as the original \(1.0-\mathrm{L}\) solution of HA \((a q) ?\) Be sure to support your answer.

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