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You make solutions of ammonia and sodium hydroxide by adding the same moles of each solute to equal volumes of water. Which solution would you expect to have the higher \(\mathrm{pH}\) ?

Short Answer

Expert verified
Sodium hydroxide ( ext{NaOH}) solution would have the higher pH.

Step by step solution

01

Understanding the Problem

We need to compare the pH levels of two solutions: ammonia (NH鈧) and sodium hydroxide (NaOH), when equal moles of each are dissolved in equal volumes of water.
02

Chemical Nature of the Solutes

Ammonia (NH鈧) is a weak base and partially dissociates in water, forming hydroxide ions (OH鈦) less effectively. Sodium hydroxide (NaOH) is a strong base and dissociates completely in water, producing a much higher concentration of hydroxide ions.
03

Determining the Basicity

Since NaOH is a strong base, it will produce more OH鈦 ions compared to the weak base NH鈧, leading to a higher pH level for the sodium hydroxide solution.
04

Comparison Conclusion

The higher concentration of hydroxide ions from NaOH indicates it will have a higher pH compared to the ammonia solution.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ammonia Solution
Ammonia solution, also known as ammonium hydroxide when dissolved in water, is a common chemical compound used in various applications. It is formed when ammonia gas ( H_3) is dissolved in water, producing a liquid that smells pungent and acts as a base. However, ammonia is termed a 'weak base.' This means it does not dissociate completely in water. Only a small fraction of the ammonia molecules release hydroxide ions ( OH^-), which are responsible for the basic nature of the solution.

Because of this incomplete dissociation, an ammonia solution possesses a moderate H value, typically lower than that of a strong base solution with the same molar concentration. Despite this moderate increase in H, ammonia solutions are still useful in household cleaners and industrial applications due to their effective, yet relatively mild, alkalinity. Understanding the concept of partial dissociation is crucial in recognizing the impact of weak bases on H.
Sodium Hydroxide Solution
Sodium hydroxide solution is a well-known example of a strong base, typically encountered in many industrial and scientific settings. This compound, often referred to as "caustic soda," is famous for its ability to effectively and fully dissociate in water. When sodium hydroxide (NaOH) dissolves, it releases sodium ions ( Na^+ ) and hydroxide ions ( OH^-), increasing the concentration of OH^- ions significantly.

This complete dissociation results in a much higher H compared to weak bases when equal concentrations are considered. The presence of a greater number of OH^- ions makes the solution strongly basic, leading to a higher H, which can often exceed 13, depending on concentration. Such solutions are utilized in various processes such as soap making, paper manufacturing, and even drain cleaning, which require strong alkaline conditions.
Weak Base
A weak base is characterized by its inability to fully dissociate into its constituent ions in a solution. Instead, it only partially separates, which substantially limits the production of hydroxide ions ( OH^-). This lower concentration of OH^- ions results in a less basic solution with a more moderate H around 7 to 10, depending on the specific weak base and its concentration.

The degree of ionization of a weak base is determined by its base dissociation constant ( K_b dvalue). For ammonia, the K_b is relatively low, which accounts for its only modest increase in H upon dissolution. Despite this, weak bases are important in numerous chemical reactions and buffering solutions where a controlled basic environment is needed.
Strong Base
A strong base is known for its complete ionization in water. This characteristic ensures that virtually all of the base molecules dissociate into their respective ions, significantly increasing the concentration of hydroxide ions ( OH^-). Consequently, this results in a much higher H value, typically ranging from 10 to 14, depending on the concentration of the solution.

Strong bases like sodium hydroxide ( NaOH) showcase such properties, making them valuable in diverse chemical applications where robust alkalinity is required. They are not only effective at raising the H but also in breaking down organic contaminants and altering pH dramatically. Understanding strong bases helps in predicting the behavior of solutions in which they are constituents and highlights their use in applications that require harsh chemical conditions.

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Most popular questions from this chapter

Self-contained environments, such as that of a space station, require that the carbon dioxide exhaled by people be continuously removed. This can be done by passing the air over solid alkali hydroxide, in which carbon dioxide reacts with hydroxide ion. What ion is produced by the addition of \(\mathrm{OH}^{-}\) ion to \(\mathrm{CO}_{2}\) ? Use the Lewis concept to explain this.

In the following reaction of tetrafluoroboric acid, \(\mathrm{HBF}_{4}\), with the acetate ion, \(\mathrm{C}_{2} \mathrm{H}_{3} \mathrm{O}_{2}^{-},\) the formation of tetrafluoroborate ion, \(\mathrm{BF}_{4}^{-}\), and acetic acid, \(\mathrm{HC}_{2} \mathrm{H}_{3} \mathrm{O}_{2}\) is favored. $$ \mathrm{HBF}_{4}+\mathrm{C}_{2} \mathrm{H}_{3} \mathrm{O}_{2}^{-} \longrightarrow \mathrm{BF}_{4}^{-}+\mathrm{HC}_{2} \mathrm{H}_{3} \mathrm{O}_{2} $$ Which is the weaker base, \(\mathrm{BF}_{4}^{-}\) or acetate ion?

A 1.00-L aqueous solution contained \(6.78 \mathrm{~g}\) of barium hydroxide, \(\mathrm{Ba}(\mathrm{OH})_{2}\). What was the \(\mathrm{pH}\) of the solution at \(25^{\circ} \mathrm{C} ?\)

a) Consider the hydrated aluminum ion \(\mathrm{Al}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}{ }_{6}^{3+}\) as a Br酶nsted-Lowry acid. Write the chemical equation in which this ion loses a proton in a reaction with ammonia, \(\mathrm{NH}_{3}\). Identify the conjugate acids and bases in this reaction. b) Ethanethiol, \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{SH},\) is a malodorous compound present in petroleum. It is removed from petroleum by reaction with sulfuric acid. Write a chemical equation for this reaction, identifying acid and base conjugates.

Strong Acids, Weak Acids, and pH Two 0.10 -mol samples of the hypothetical monoprotic acids \(\mathrm{HA}(a q)\) and \(\mathrm{HB}(a q)\) are used to prepare \(1.0 \mathrm{-} \mathrm{L}\) stock solutions of each acid. a)Write the chemical reactions for these acids in water. What are the concentrations of the two acid solutions? b)One of these acids is a strong acid, and one is weak. What could you measure that would tell you which acid was strong and which was weak? c)Say that the \(\mathrm{HA}(a q)\) solution has a \(\mathrm{pH}\) of 3.7 . Is this the stronger of the two acids? How did you arrive at your answer? d)What is the concentration of \(\mathrm{A}^{-}(a q)\) in the HA solution described in part \(\mathrm{c}\) ? e)If \(\mathrm{HB}(a q)\) is a strong acid, what is the hydronium-ion concentration? f) In the solution of \(\mathrm{HB}(a q),\) which of the followin would you expect to be in the greatest concentration \(\mathrm{H}_{3} \mathrm{O}^{+}(a q), \mathrm{B}^{-}(a q), \mathrm{HB}(a q),\) or \(\mathrm{OH}^{-}(a q) ?\) How did yo decide? g)In the solution of \(\mathrm{HA}(a q),\) which of the following would you expect to be in the greatest concentration: \(\mathrm{H}_{3} \mathrm{O}^{+}(a q), \mathrm{A}^{-}(a q), \mathrm{HA}(a q),\) or \(\mathrm{OH}^{-}(a q) ?\) How did you decide? h) Say you add \(1.0 \mathrm{~L}\) of pure water to a solution of \(\mathrm{HB}\). Would this water addition make the solution more acidic, make it less acidic, or not change the acidity of the original solution? Be sure to fully justify your answer. i) You prepare a \(1.0-\mathrm{L}\) solution of \(\mathrm{HA}\). You then take a \(200-\mathrm{mL}\) sample of this solution and place it into a separate container. Would this \(200 \mathrm{~mL}\) sample be more acidic, be less acidic, or have the same acidity as the original \(1.0-\mathrm{L}\) solution of HA \((a q) ?\) Be sure to support your answer.

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