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The bicarbonate ion has the ability to act as an acid in the presence of a base or as a base in the presence of an acid, so it is said to be amphiprotic. Illustrate this behavior with water by writing Br酶nsted-Lowry acid- base reactions. Also illustrate this property by selecting a common strong acid and base to react with the bicarbonate ion.

Short Answer

Expert verified
The bicarbonate ion can donate a proton, acting as an acid with NaOH, and accept a proton, acting as a base with HCl.

Step by step solution

01

Understanding Amphiprotic Substances

An amphiprotic substance is one that can donate or accept a proton (H鈦). Bicarbonate ion (HCO鈧冣伝) is amphiprotic, meaning it can act as both an acid and a base.
02

Reaction with Water as a Base

When bicarbonate ion acts as an acid, it donates a proton to water. This can be expressed as:\[\text{HCO}_3^- + \text{H}_2\text{O} \rightarrow \text{CO}_3^{2-} + \text{H}_3\text{O}^+\]Here, HCO鈧冣伝 donates a proton to water, forming carbonate ion and hydronium ion.
03

Reaction with Water as an Acid

Conversely, when bicarbonate ion acts as a base, it accepts a proton from water. The reaction is:\[\text{HCO}_3^- + \text{H}_2\text{O} \rightarrow \text{H}_2\text{CO}_3 + \text{OH}^-\]In this reaction, HCO鈧冣伝 accepts a proton from water, forming carbonic acid and hydroxide ion.
04

Reaction with a Strong Acid

Consider a reaction with a strong acid, like hydrochloric acid (HCl). The bicarbonate ion acts as a base:\[\text{HCO}_3^- + \text{HCl} \rightarrow \text{H}_2\text{CO}_3 + \text{Cl}^-\]Here, HCO鈧冣伝 accepts a proton from HCl, forming carbonic acid and chloride ion.
05

Reaction with a Strong Base

For a reaction with a strong base, such as sodium hydroxide (NaOH), bicarbonate acts as an acid:\[\text{HCO}_3^- + \text{NaOH} \rightarrow \text{Na}^+ + \text{CO}_3^{2-} + \text{H}_2\text{O}\]In this reaction, HCO鈧冣伝 donates a proton to NaOH, forming carbonate ion, sodium ion, and water.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Bicarbonate Ion
The bicarbonate ion, denoted as \(\text{HCO}_3^-\), is a fascinating chemical species due to its ability to act as both an acid and a base. This duality of function classifies it as amphiprotic, a term you'll often encounter in chemistry discussions.
  • When acting as an acid, \(\text{HCO}_3^-\) donates a proton (\(\text{H}^+\)).
  • When functioning as a base, it accepts a proton from another species.
This unique behavior makes bicarbonate ions highly versatile and essential in various biochemical and environmental processes. Understanding bicarbonate's amphiprotic nature is crucial for grasping how it behaves in different reactions, especially those involving water and strong acids or bases.
Br酶nsted-Lowry Acid-Base Reactions
According to the Br酶nsted-Lowry theory, acids are proton donors, and bases are proton acceptors. This definition broadens the understanding of acids and bases beyond the classical definitions from Arrhenius, where acids produce \(\text{H}^+\) in water while bases produce \(\text{OH}^-\).
  • In a Br酶nsted-Lowry reaction, transferring a proton from the acid to the base is the key event.
  • The bicarbonate ion exemplifies this by alternately donating and accepting protons. For instance, when it donates a proton to water, \(\text{HCO}_3^-\) acts as an acid.
  • Conversely, when it accepts a proton from water, it acts as a base, showing its flexibility in Br酶nsted-Lowry reactions.
This proton transfer is fundamental to acid-base chemistry, and bicarbonate ions serve as an excellent illustration of this concept.
Proton Transfer
Proton transfer is a core aspect of many chemical reactions, particularly those involving acids and bases. In a proton transfer reaction, a "proton" (\(\text{H}^+\)) moves from one molecule to another. This movement is the defining action in Br酶nsted-Lowry acid-base reactions.
The bicarbonate ion can donate a proton to form carbonate \(\text{CO}_3^{2-}\) or accept a proton to form carbonic acid \(\text{H}_2\text{CO}_3\). This duo of reactions can be seen when bicarbonate interacts with water, where it either loses or gains a \(\text{H}^+\) ion. Proton transfer reactions are crucial for biological systems and industrial processes, underpinning functions like energy transfer and chemical synthesis.
Strong Acids and Bases
Strong acids and bases are substances that completely dissociate in solution. This complete dissociation means that they release more protons (\(\text{H}^+\)) or hydroxide ions (\(\text{OH}^-\)) compared to their weak counterparts.
  • In the world of strong acids, hydrochloric acid (HCl) is a common example. It provides \(\text{H}^+\) ions readily to any base it encounters.
  • On the other hand, sodium hydroxide (NaOH) is a typical strong base, which fully dissociates to produce \(\text{OH}^-\) ions. This characteristic makes them potent reactants capable of altering the pH of solutions significantly.
When bicarbonate ion interacts with strong acids and bases, its role as either a proton donor or acceptor becomes evident. For instance, reacting with HCl, bicarbonate acts as a base, whereas with NaOH, it behaves as an acid. Understanding the distinctions between strong and weak acids and bases aids in predicting and explaining reaction outcomes involving bicarbonate ions.

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Most popular questions from this chapter

Complete each of the following equations. Then write the Lewis formulas of the reactants and products and identify each reactant as a Lewis acid or a Lewis base. a) \(\mathrm{InCl}_{3}+\mathrm{Cl}^{-} \longrightarrow\)___________ \(\mathrm{b)} \mathrm{BBr}_{3}+\mathrm{Br}^{-} \longrightarrow\)___________

Self-contained environments, such as that of a space station, require that the carbon dioxide exhaled by people be continuously removed. This can be done by passing the air over solid alkali hydroxide, in which carbon dioxide reacts with hydroxide ion. What ion is produced by the addition of \(\mathrm{OH}^{-}\) ion to \(\mathrm{CO}_{2}\) ? Use the Lewis concept to explain this.

a) Consider the hydrated aluminum ion \(\mathrm{Al}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}{ }_{6}^{3+}\) as a Br酶nsted-Lowry acid. Write the chemical equation in which this ion loses a proton in a reaction with ammonia, \(\mathrm{NH}_{3}\). Identify the conjugate acids and bases in this reaction. b) Ethanethiol, \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{SH},\) is a malodorous compound present in petroleum. It is removed from petroleum by reaction with sulfuric acid. Write a chemical equation for this reaction, identifying acid and base conjugates.

The conjugate base of hydrofluoric acid dissolved in water is: a) \(\mathrm{F}^{-}\) b) \(\mathrm{OH}^{-}\) c) \(\mathrm{H}_{3} \mathrm{O}^{+}\) d) \(\mathrm{HF} \) e) \(\mathrm{F}_{2}\)

For each of the following, write the complete chemical equation for the acid- base reaction that occurs. Describe each using Br酶nsted language (if appropriate) and then using Lewis language (show electron-dot formulas). a The \(\mathrm{ClO}^{-}\) ion reacts with water. b) The reaction of \(\mathrm{NH}_{4}^{+}\) and \(\mathrm{NH}_{2}^{-}\) in liquid ammonia to produce \(\mathrm{NH}_{3}\).

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