Chapter 3: Problem 26
\(100 \mathrm{~mL}\) of \(0.3 \mathrm{~N} \mathrm{HCl}\) is mixed with \(200 \mathrm{~mL}\) of \(0.6\) \(\mathrm{N} \mathrm{H}_{2} \mathrm{SO}_{4}\) The final normality of the resulting solution will be (a) \(0.1 \mathrm{~N}\) (b) \(0.2 \mathrm{~N}\) (c) \(0.3 \mathrm{~N}\) (d) \(0.5 \mathrm{~N}\)
Short Answer
Step by step solution
Calculate milliequivalents of HCl
Calculate milliequivalents of H2SO4
Find total milliequivalents of the resulting solution
Calculate total volume of the solution
Calculate normality of the resulting solution
Conclusion
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Molarity vs Normality
Normality, on the other hand, considers the number of equivalents of a solute in one liter of solution. Equivalent, in this context, refers to the reactivity or combining power of a chemical species. For example, sulfuric acid ( H_2SO_4 ) is a diprotic acid, meaning it can donate two protons per molecule in reactions. Therefore, its normality is twice its molarity. This makes normality particularly useful in titrations and reactions where the stoichiometry may not be straightforward. Understanding these differences allows chemists to accurately measure reactivity and perform precise calculations.
Acid-Base Titration
During a titration, the point at which all the acid is fully reacted with the base is called the equivalence point. This is typically signaled by a color change in an indicator added to the solution, or by measuring the pH change with a pH meter. For accurate results, knowledge of the normality is essential, as it helps in calculating the exact amount of substance that reacts. Normality reflects the number of reactive units, making it an ideal measure when dealing with titrations among compounds that have variable equivalences.
Solution Concentration Calculations
To calculate concentration, start by determining the amount of solute and solvent involved. For normality, this means calculating based on equivalents of the solute. In the given exercise, the normality was calculated using milliequivalents and total volume:
- Find milliequivalents of your substances (HCl and H_2SO_4 here) by multiplying volume and normality.
- Combine milliequivalents to obtain total reactive capacity.
- Divide total milliequivalents by volume in liters to get normality.