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The logarithm of the molar absorptivity for acetone in ethanol is \(2.75\) at \(366 \mathrm{~nm}\). Calculate the range of acetone concentrations that can be used if the absorbance is to be greater than \(0.100\) and less than \(2.000\) with a 1.50-cm cell.

Short Answer

Expert verified
The concentration of acetone should be between 0.000118 mol/L and 0.00237 mol/L.

Step by step solution

01

Understand Beer's Law

Beer's Law states that the absorbance (\(A\)) of a solution is directly proportional to the path length (\(b\)) and the concentration (\(c\)) of the solution, as well as the molar absorptivity (\(\varepsilon\)). It can be expressed as: \(A = \varepsilon b c\).
02

Convert Logarithmic Molar Absorptivity to Linear Form

The molar absorptivity is given in logarithmic form as \(\log_{10}(\varepsilon) = 2.75\). To convert it to linear form, use the formula: \(\varepsilon = 10^{2.75}\). Thus, \(\varepsilon \approx 562.34\, \text{L/mol*cm}\).
03

Set Up the Inequality for Absorbance

We want the absorbance to be greater than 0.100 and less than 2.000, so we set up the inequality: \(0.100 < \varepsilon b c < 2.000\).
04

Insert Known Values

Insert the known values into the inequality: \(0.100 < 562.34 \times 1.50 \times c < 2.000\).
05

Solve for Concentration Range

Solve the inequality for \(c\):1. Divide all parts of the inequality by \(562.34 \times 1.50\):\(\frac{0.100}{843.51} < c < \frac{2.000}{843.51}\)2. This simplifies to approximately: \(0.000118 < c < 0.00237\).Thus, the concentration range is \(0.000118 \text{ mol/L} < c < 0.00237 \text{ mol/L}\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Understanding Molar Absorptivity
Molar absorptivity, also known as the molar extinction coefficient, is a crucial concept in understanding how substances absorb light. It is represented by the Greek letter \( \varepsilon \ \) in Beer's Law and provides a measure of how well a chemical species absorbs light at a given wavelength. \( \varepsilon \) is expressed in units of \( \text{L/mol*cm} \). The higher the value of molar absorptivity, the better the substance absorbs light.
In the context of Beer's Law, \( \varepsilon \) is combined with path length (\( b \)) and concentration (\( c \)) to determine the absorbance (\( A \)) of a solution. When given in a logarithmic form, it may be expressed as \( \log_{10}(\varepsilon) \). Converting this to a linear form gives us a real numeric value to work with, making calculations possible.
Exploring Absorbance Calculation
Absorbance is a measure of how much light is absorbed when it passes through a solution. According to Beer's Law, the equation governing this is given as \( A = \varepsilon b c \), where \( A \) is the absorbance, \( \varepsilon \) is molar absorptivity, \( b \) is the path length of the cell (usually in cm), and \( c \) is the concentration of the solution in mol/L.
The absorbance is directly proportional to both the concentration of the absorbing species and the path length through which the light travels. This relationship is useful in analytical chemistry for determining concentrations by measuring absorbance at specific wavelengths using spectrophotometers. As in the original problem, if absorbance is bounded between two values, the concentration range can be determined by manipulating this relationship.
Determining Concentration Range
In scenarios like the original problem, determining the concentration range is essential for ensuring that measured absorbance values fall within a specified range. Beer's Law helps establish this range by manipulating its equation based on given parameters.
From the inequality \( 0.100 < \varepsilon b c < 2.000 \), we calculate the range of concentrations. We substitute known values for molar absorptivity and path length, then solve the inequality to find the minimum and maximum concentrations. This step is crucial in experiments where specific absorbance values are required, guiding adjustments in solution concentration.
The Role of Analytical Chemistry
Analytical chemistry is the branch dedicated to analyzing the composition of materials through qualitative and quantitative measurements. In the context of Beer's Law, it's particularly focused on detecting and quantifying chemical substances using light absorption.
Spectrophotometry, a common technique in this field, plays an integral role in using Beer's Law as it measures how much light a solution absorbs at various wavelengths. This is critical in fields like pharmaceuticals, environmental science, and biochemistry, where understanding precise concentrations of substances is necessary.
  • Quality Control: Analytical chemistry ensures consistency and safety in manufactured products through precise measurement.
  • Environmental Monitoring: It helps determine pollutant concentrations in samples from air, water, and soil.
  • Research: Enables the exploration of chemical reactions and properties in academic and industrial settings.
Understanding these concepts provides the foundation for studying chemical phenomena and conducting reliable experiments in scientific investigations.

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Most popular questions from this chapter

A photometer with a linear response to radiation gave a reading of \(690 \mathrm{mV}\) with a blank in the light path and \(169 \mathrm{mV}\) when the blank was replaced by an absorbing solution. Calculate *(a) the transmittance and absorbance of the absorbing solution. (b) the expected transmittance if the concentration of absorber is one half that of the original solution. "(c) the transmittance to be expected if the light path through the original solution is doubled.

The logarithm of the molar absorptivity of phenol in aqueous solution is \(3.812\) at \(211 \mathrm{~nm}\). Calculate the range of phenol concentrations that can be used if the absorbance is to be greater than \(0.150\) and less than 1.500 with a \(1.25-\mathrm{cm}\) cell.

Ethylenediaminetetraacetic acid displaces bismuth(III) from its thiourea complex: $$ \mathrm{Bi}(\mathrm{tu})_{6}{ }^{3+}+\mathrm{H}_{2} \mathrm{Y}^{2-} \rightarrow \mathrm{BiY}^{-}+6 \mathrm{tu}+2 \mathrm{H}^{+} $$ where tu is the thiourea molecule, \(\left(\mathrm{NH}_{2}\right)_{2} \mathrm{CS}\). Predict the shape of a photometric titration curve based on this process, given that the \(\mathrm{Bi}(\mathrm{III}) /\) thiourea complex is the only species in the system that absorbs at \(465 \mathrm{~nm}\), the wavelength selected for the titration.

The molar absorptivity for aqueous solutions of phenol at \(211 \mathrm{~nm}\) is \(6.17 \times 10^{5} \mathrm{~L} \mathrm{~cm}^{-1} \mathrm{~mol}^{-1}\). Calculate the permissible range of phenol concentrations if the transmittance is to be less than \(85 \%\) and greater than \(7 \%\) when the measurements are made in \(1.00-\mathrm{cm}\) cells.

A. J. Mukhedkar and N. V. Deshpande (Anal. Chem., \(1963,35,47\), DOI: 10.1021/ac60194?a014) report on a simultaneous determination for cobalt and nickel based on absorption by their 8 -quinolinol complexes. Molar absorptivities \(\left(\mathrm{L} \mathrm{mol}{ }^{-1} \mathrm{~cm}^{-1}\right)\) are \(\varepsilon_{\mathrm{Ca}}=3529\) and \(\varepsilon_{\mathrm{N} i}=3228\) at \(365 \mathrm{~nm}\) and \(\varepsilon_{\mathrm{Co}}=428.9\) and \(\varepsilon_{\mathrm{Ni}}=0\) at \(700 \mathrm{~nm}\). Calculate the concentration of nickel and cobalt in each of the following solutions (1.00-cm cells): \begin{tabular}{ccc} Solution & \(A_{\text {shs }}\) & \(A_{\text {Noe }}\) \\ \hline 1 & \(0.617\) & \(0.0235\) \\ 2 & \(0.755\) & \(0.0714\) \\ 3 & \(0.920\) & \(0.0945\) \\ 4 & \(0.592\) & \(0.0147\) \\ 5 & \(0.685\) & \(0.0540\) \\ \hline \end{tabular}

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