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Write chemical formulas for the following complex ions: (a) hexamminezinc(II) (b) dichloroargentate (c) disulfatocuprate(II) (d) trioxalotoferrate(III) (e) hexacyanoferrate(II)

Short Answer

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(a) [Zn(NH鈧)鈧哴虏鈦 (b) [AgCl鈧俔鈦 (c) [Cu(SO鈧)鈧俔虏鈦 (d) [Fe(C鈧侽鈧)鈧僝鲁鈦 (e) [Fe(CN)鈧哴鈦粹伝

Step by step solution

01

Understanding the Complex Ion Components

To write the chemical formula for each complex ion, we must understand the components of the name. This includes the central metal atom, the ligands attached to it, and the oxidation state of the metal if given or implied.
02

Decoding the Ligands and Metal

Identify the ligands and their corresponding number from the name. For example, 'hexammine' indicates six 'ammine' ligands (NH鈧). In a name like 'dichloro,' 'di' means two chloride (Cl鈦) ions. Understand the overall charge that these ligands impart to the coordination compound based on their charges.
03

Writing the Chemical Formula

For each ion, write the central metal atom, followed by the ligands in their corresponding amounts, enclosed in brackets. Indicate the overall charge of the complex ion outside the brackets, based on the charges assigned to ligands and the oxidation state of the metal. For example, if zinc is in a 2+ state and we have six neutral NH鈧 ligands, the formula will have zero charge outside.
04

Signifying the Overall Charge

Add the overall charge outside the brackets if the complex is an anion or cation. If the complex is neutral, indicate this appropriately.
05

Formulate Hexamminezinc(II)

Hexamminezinc(II): Zinc (Zn) with oxidation state of +2 with 6 ammine ligands (neutral), Formula: [Zn(NH鈧)鈧哴虏鈦
06

Formulate Dichloroargentate

Dichloroargentate: Silver (Ag) with two chloride ions (2Cl鈦) forming an anion, Formula: [AgCl鈧俔鈦
07

Formulate Disulfatocuprate(II)

Disulfatocuprate(II): Copper (Cu) in oxidation state +2 with two sulfate ions (SO鈧劼测伝), Formula: [Cu(SO鈧)鈧俔虏鈦
08

Formulate Trioxalotoferrate(III)

Trioxalotoferrate(III): Iron (Fe) in oxidation state +3 with three oxalate ions (C鈧侽鈧劼测伝), Formula: [Fe(C鈧侽鈧)鈧僝鲁鈦
09

Formulate Hexacyanoferrate(II)

Hexacyanoferrate(II): Iron (Fe) in oxidation state +2 with six cyanide ions (CN鈦), Formula: [Fe(CN)鈧哴鈦粹伝

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Formulas
Understanding chemical formulas is essential when dealing with complex ions. A chemical formula expresses the proportions of atoms that make up a molecule or compound. In the case of complex ions, this includes identifying the central metal atom and its associated ligands. The notation begins with the metal, followed by the ligands. These ligands are typically written in parentheses, showing the number attached, such as in the example
  • [Fe(CN)鈧哴鈦粹伝, where 'Fe' is iron and '(CN)鈧' represents six cyanide ligands.

Writing a chemical formula requires understanding each component's contribution to the ion's overall structure and charge. Each ligand carries a specific charge, which affects the coordination compound's total charge. It's important to not only recognize these parts but also accurately compute their resulting charge. This ensures the formula correctly represents the real-world chemical nature of the ion. The complex itself may be an anion (negatively charged), cation (positively charged), or neutral, which will be indicated by the charge outside the square brackets. This precise representation is crucial to predict the chemical behavior of any given compound.
Coordination Compounds
Coordination compounds are interesting and complex elements of the chemistry world. They feature a central metal atom bonded to surrounding molecules or ions known as ligands. These ligands are components that donate electrons to the metal, allowing for intricate bonding arrangements.
Coordination compounds are crafted through coordination bonds, which are a special type of chemical bond. These bonds occur when a ligand donates a pair of electrons to a metal atom, forming a stable structure.
  • This interaction is crucial to defining the chemical and physical properties of the compound.
  • An example includes [Cu(SO鈧)鈧俔虏鈦, where copper serves as the central atom surrounded by sulfate ligands.
Coordinating numbers, which represent the total number of attachments made to the central atom, help specify the structure and arrangement of a coordination compound. These numbers can range from 2 to 12, though six is most common.
The geometry of coordination compounds can also vary greatly. Depending on the coordinating number and types of ligands present, these compounds can form shapes such as octahedral, tetrahedral, or square planar. Coordination compounds play a significant role in various fields, like catalysis, material science, and bioinorganic chemistry, showcasing immense versatility.
Oxidation States
In chemistry, an oxidation state defines the degree of oxidation of an element within a compound. It indicates how many electrons an atom gains or loses during bonding with other atoms. This is crucial in naming complex ions and compounds. For instance, in the case of complex ions, the oxidation state is often included in the compound's name, such as "Zinc(II)" in hexamminezinc(II), signifying a +2 oxidation state for zinc.
Understanding oxidation states helps in determining the overall charge of the complex ion.
  • This is calculated by summing up the oxidation state of the central metal and the charges brought by its ligands.
  • For example, in [AgCl鈧俔鈦, silver typically has an oxidation state linked with the charge of chloride ligands.
This concept is fundamental for writing the correct chemical formula, as it ensures the accurately calculated net charge reflects the real conditions. Recognizing the role of oxidation states in complex compounds also aids in predicting reactivity trends and stability, making this a critical concept in both theoretical and practical chemical applications.

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Most popular questions from this chapter

The Tl in a 9.57-g sample of rodenticide was oxidized to the trivalent state and treated with an unmeasured excess of \(\mathrm{Mg} / \mathrm{EDTA}\) solution. The reaction is $$ \mathrm{Tl}^{3+}+\mathrm{MgY}^{2-} \rightarrow \mathrm{TlY}^{-}+\mathrm{Mg}^{2+} $$ Titration of the liberated \(\mathrm{Mg}^{2+}\) required \(12.77 \mathrm{~mL}\) of \(0.03610 \mathrm{M}\) EDTA. Calculate the percent \(\mathrm{Tl}_{2} \mathrm{SO}_{4}\) \((504.8 \mathrm{~g} / \mathrm{mol})\) in the sample.

A solution contains \(1.569 \mathrm{mg}\) of \(\mathrm{CoSO}_{4}(155.0 \mathrm{~g} /\) mol) per milliliter. Calculate (a) the volume of \(0.007840 \mathrm{M} \mathrm{EDTA}\) needed to titrate a \(25.00-\mathrm{mL}\) aliquot of this solution. (b) the volume of \(0.009275 \mathrm{M} \mathrm{Zn}^{2+}\) needed to titrate the excess reagent after addition of \(50.00\) \(\mathrm{mL}\) of \(0.007840 \mathrm{M}\) EDTA to a \(25.00-\mathrm{mL}\) aliquot of this solution. (c) the volume of \(0.007840 \mathrm{M} \mathrm{EDTA}\) needed to titrate the \(\mathrm{Zn}^{2+}\) displaced by \(\mathrm{Co}^{2+}\) following addition of an unmeasured excess of \(\mathrm{ZnY}^{2-}\) to a \(25.00-\mathrm{mL}\) aliquot of the \(\mathrm{CoSO}_{4}\) solution. The reaction is $$ \mathrm{Co}^{2+}+\mathrm{ZnY}^{2-} \rightarrow \mathrm{CoY}^{2-}+\mathrm{Zn}^{2+} $$

Construct a titration curve for \(50.00 \mathrm{~mL}\) of \(0.0150\) \(\mathrm{M} \mathrm{Fe}^{2+}\) with \(0.0300 \mathrm{M} \mathrm{EDTA}\) in a solution buffered to \(\mathrm{pH}\) 7.0. Calculate \(\mathrm{pFe}\) values after the addition of \(0.00,10.00,24.00,24.90,25.00,25.10,26.00\), and \(30.00 \mathrm{~mL}\) of titrant.

The \(\mathrm{Zn}\) in a \(0.7457-\mathrm{g}\) sample of foot powder was titrated with \(22.57 \mathrm{~mL}\) of \(0.01639 \mathrm{M}\) EDTA. Calculate the percent \(\mathrm{Zn}\) in this sample.

A 0.3304-g sample of brass (containing lead, zinc, copper, and tin) was dissolved in nitric acid. The sparingly soluble \(\mathrm{SnO}_{2} \cdot 4 \mathrm{H}_{2} \mathrm{O}\) was removed by filtration, and the combined filtrate and washings were then diluted to \(500.0 \mathrm{~mL}\). A \(10.00-\mathrm{mL}\) aliquot was suitably buffered; titration of the lead, zinc, and copper in this aliquot required \(34.78 \mathrm{~mL}\) of \(0.002700\) M EDTA. The copper in a \(25.00-\mathrm{mL}\) aliquot was masked with thiosulfate; the lead and zinc were then titrated with \(25.62 \mathrm{~mL}\) of the EDTA solution. Cyanide ion was used to mask the copper and zinc in a 100-mL aliquot; \(10.00 \mathrm{~mL}\) of the EDTA solution was needed to titrate the lead ion. Determine the composition of the brass sample; evaluate the percentage of tin by difference.

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