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What mass of \(\mathrm{AgI}\) can be produced from a \(0.512-\mathrm{g}\) sample that assays \(20.1 \% \mathrm{AlI}_{3}\) ?

Short Answer

Expert verified
0.178 g of AgI can be produced.

Step by step solution

01

Determine the amount of AlI3 in the sample

First, we need to find the mass of \(\mathrm{AlI}_3\) in the sample. Since the sample assays at \(20.1\%\) \(\mathrm{AlI}_3\), calculate the mass of \(\mathrm{AlI}_3\) by multiplying the total sample mass by the percentage.\[\text{Mass of } \mathrm{AlI}_3 = 0.512 \, \mathrm{g} \times \frac{20.1}{100} = 0.102912 \, \mathrm{g}\]
02

Calculate moles of AlI3

Next, convert the mass of \(\mathrm{AlI}_3\) to moles using its molar mass. The molar mass of \(\mathrm{AlI}_3\) is approximately \(407.695 \, \mathrm{g/mol}\).\[\text{Moles of } \mathrm{AlI}_3 = \frac{0.102912 \, \mathrm{g}}{407.695 \, \mathrm{g/mol}} \approx 0.0002524 \, \text{mol}\]
03

Use stoichiometry to find moles of AgI

The reaction for the formation of \(\mathrm{AgI}\) from \(\mathrm{AlI}_3\) is given by:\[\mathrm{AlI}_3 + 3\mathrm{AgNO}_3 \rightarrow 3\mathrm{AgI} + \mathrm{Al(NO}_3)_3\]From the balanced equation, 1 mole of \(\mathrm{AlI}_3\) produces 3 moles of \(\mathrm{AgI}\). Therefore:\[\text{Moles of } \mathrm{AgI} = 0.0002524 \, \text{mol} \times 3 \approx 0.0007572 \, \text{mol}\]
04

Calculate mass of AgI

Convert the moles of \(\mathrm{AgI}\) back to grams using the molar mass of \(\mathrm{AgI}\), which is approximately \(234.77 \, \mathrm{g/mol}\).\[\text{Mass of } \mathrm{AgI} = 0.0007572 \, \text{mol} \times 234.77 \, \mathrm{g/mol} \approx 0.1777 \, \mathrm{g}\]
05

Final result

The mass of \(\mathrm{AgI}\) that can be produced from the 0.512 g sample is approximately \(0.178 \, \mathrm{g}\) when rounded to three significant figures.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Reactions
Chemical reactions involve the transformation of substances through breaking and forming bonds, resulting in new products. In our exercise, we are dealing with the reaction where aluminum iodide (\(\mathrm{AlI}_3\)) reacts with silver nitrate (\(\mathrm{AgNO}_3\)) to form silver iodide (\(\mathrm{AgI}\)) and aluminum nitrate (\(\mathrm{Al(NO}_3)_3\)). This type of reaction is known as a double displacement reaction. Each reactant swaps components to form two new compounds.

This reaction can be better understood in terms of stoichiometry, which allows us to calculate how much product can form from given amounts of reactants. In this case, the balanced reaction equation is crucial. It tells us that 1 mole of \(\mathrm{AlI}_3\) reacts with 3 moles of \(\mathrm{AgNO}_3\) to produce 3 moles of \(\mathrm{AgI}\). This molar ratio is necessary for calculating how much \(\mathrm{AgI}\) will be formed from a known amount of \(\mathrm{AlI}_3\). By understanding chemical reactions and stoichiometry, we can ensure precise calculations of material usage and product yield in chemical processes.
Mole Calculations
Mole calculations are essential for translating between mass and the number of particles in chemistry. The mole concept connects the mass of a substance to the number of atoms or molecules it contains. How? By using its molar mass!

For \(\mathrm{AlI}_3\), the molar mass is approximately \(407.695 \, \mathrm{g/mol}\). To find out how many moles we have, we divide the sample mass by this value. In our exercise, we calculated the moles of \(\mathrm{AlI}_3\) as follows:
  • Given mass of \(\mathrm{AlI}_3\): \(0.102912 \, \mathrm{g}\)
  • Molar mass of \(\mathrm{AlI}_3\): \(407.695 \, \mathrm{g/mol}\)
  • Conversion to moles: \(\frac{0.102912}{407.695} \approx 0.0002524 \, \text{mol}\)
Understanding mole calculations helps chemists determine how far a reaction will proceed and how much of each element in a compound reacts or is produced.
Mass Percent Composition
The concept of mass percent composition helps describe the proportions of each component within a substance. It expresses the mass of each element or compound as a percentage of the total mass. This percentage is crucial for quantitative analysis and quality control in chemical manufacturing.

In the given exercise, we started by using the mass percent composition of \(\mathrm{AlI}_3\) to find out how much of it is present in the \(0.512-\mathrm{g}\) sample. The sample assays \(20.1\% \mathrm{AlI}_3\), meaning simply:
  • Multiply the total sample mass by the mass percent to find the mass of \(\mathrm{AlI}_3\): \(0.512 \, \mathrm{g} \times \frac{20.1}{100} \approx 0.102912 \, \mathrm{g}\).
This technique is often used in analytical chemistry to calculate how much of a particular substance is in a mixture. It gives critical insights into the composition of materials, ensuring the desired properties or purity in applications.

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Most popular questions from this chapter

A 6.881-g sample containing magnesium chloride and sodium chloride was dissolved in sufficient water to give \(500 \mathrm{~mL}\) of solution. Analysis for the chloride content of a \(50.0\) - \(\mathrm{mL}\) aliquot resulted in the formation of \(0.5923 \mathrm{~g}\) of \(\mathrm{AgCl}\). The magnesium in a second \(50.0-\mathrm{mL}\) aliquot was precipitated as \(\mathrm{MgNH}_{4} \mathrm{PO}_{4}\); on ignition, \(0.1796 \mathrm{~g}\) of \(\mathrm{Mg}_{2} \mathrm{P}_{2} \mathrm{O}_{7}\) was found. Calculate the percentage of \(\mathrm{MgCl}_{2} \cdot 6 \mathrm{H}_{2} \mathrm{O}\) and of \(\mathrm{NaCl}\) in the sample.

Precipitates used in the gravimetric determination of uranium include \(\mathrm{Na}_{2} \mathrm{U}_{2} \mathrm{O}_{7}(634.0 \mathrm{~g} / \mathrm{mol})\), \(\left(\mathrm{UO}_{2}\right)_{2} \mathrm{P}_{2} \mathrm{O}_{7}(714.0 \mathrm{~g} / \mathrm{mol})\), and \(\mathrm{V}_{2} \mathrm{O}_{5} \cdot 2 \mathrm{UO}_{3}(753.9 \mathrm{~g} /\) \(\mathrm{mol})\). Which of these weighing forms provides the greatest mass of precipitate from a given quantity of uranium?

A 7.000-g sample of a pesticide was decomposed with metallic sodium in alcohol, and the liberated chloride ion was precipitated as \(\mathrm{AgCl}\). Express the results of this analysis in terms of percent DDT \(\left(\mathrm{C}_{14} \mathrm{H}_{9} \mathrm{Cl}_{5}\right)\) based on the recovery of \(0.2513 \mathrm{~g}\) of \(\mathrm{AgCl}\).

Ammoniacal nitrogen can be determined by treatment of the sample with chloroplatinic acid; the product is slightly soluble ammonium chloroplatinate: $$ \mathrm{H}_{2} \mathrm{PtCl}_{6}+2 \mathrm{NH}_{4}^{+} \rightarrow\left(\mathrm{NH}_{4}\right)_{2} \mathrm{PtCl}_{6}+2 \mathrm{H}^{+} $$ The precipitate decomposes on ignition, yielding metallic platinum and gaseous products: $$ \left(\mathrm{NH}_{4}\right)_{2} \mathrm{PtCl}_{6} \rightarrow \mathrm{Pt}(s)+2 \mathrm{Cl}_{2}(g)+2 \mathrm{NH}_{3}(g)+2 \mathrm{HCl}(g) $$ Calculate the percentage of ammonia in a sample if \(0.2115 \mathrm{~g}\) gave rise to \(0.4693 \mathrm{~g}\) of platinum.

When a 100.0-mL portion of a solution containing \(0.500 \mathrm{~g}\) of \(\mathrm{AgNO}_{3}\) is mixed with \(100.0 \mathrm{~mL}\) of a solution containing \(0.300 \mathrm{~g}\) of \(\mathrm{K}_{2} \mathrm{CrO}_{4}\), a bright red precipitate of \(\mathrm{Ag}_{2} \mathrm{CrO}_{4}\) forms. (a) Assuming that the solubility of \(\mathrm{Ag}_{2} \mathrm{CrO}_{4}\) is negligible, calculate the mass of the precipitate. (b) Calculate the mass of the unreacted component that remains in solution.

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