/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 66 A gaseous fuel containing methan... [FREE SOLUTION] | 91Ó°ÊÓ

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A gaseous fuel containing methane and ethane is burned with excess air. The fuel enters the furnace at \(25^{\circ} \mathrm{C}\) and 1 atm, and the air enters at \(200^{\circ} \mathrm{C}\) and 1 atm. The stack gas leaves the furnace at \(800^{\circ} \mathrm{C}\) and 1 atm and contains 5.32 mole\% \(\mathrm{CO}_{2}, 1.60 \%\) CO, \(7.32 \%\) O \(_{2}, 12.24 \% \mathrm{H}_{2} \mathrm{O}\), and the balance \(\mathrm{N}_{2}\). (a) Calculate the molar percentages of methane and ethane in the fuel gas and the percentage excess air fed to the reactor. (b) Calculate the heat (kJ) transferred from the reactor per cubic meter of fuel gas fed. (c) A proposal has been made to lower the feed rate of air to the furnace. State advantages and a drawback of doing so.

Short Answer

Expert verified
For task (a), the molar percentages of methane and ethane in the fuel gas and the percentage excess air fed to the reactor are computed based on stoichiometric relations and given stack gas composition. Task (b)'s answer is expressed in kJ, reflecting the heat balance for the reaction process. For task (c), describing the potential benefits and drawbacks of reducing the air feed requires understanding of the principles of combustion and furnace operation possibilities.

Step by step solution

01

Balance the combustion reaction

Write the chemical equations for combustion of methane (CH4) and ethane (C2H6), separately. Each fuel reacts with oxygen (O2) to form carbon dioxide (CO2) and water (H2O). Input these balanced equations here.
02

Back-calculate the molar percentages of methane and ethane in the fuel gas

Use the given stack gas composition and the balanced equations from Step 1 to back-calculate the amounts of reactants (CH4 and C2H6). Mathematics based on mole percentages will be required here.
03

Calculate the percentage excess air fed to the reactor

After finding the composition of the fuel gas in Step 2, calculate the stoichiometric amount of air needed for complete combustion. Compare this with the amount of air actually fed (we know it's excess because it's stated in the problem) to get the percentage excess air.
04

Calculate the heat transferred from the reactor per cubic meter of fuel gas fed

Use the known compositions, temperatures and heat capacities of the reactants and products to find the heat transferred per cubic meter of fuel gas. This step requires application of thermodynamics principles including the specific heat formula Q = mcΔT (where Q is heat, m is mass, c is specific heat and ΔT is the temperature difference).
05

Discuss the advantages and a drawback of lowering the air feed rate

Analyze the advantages and disadvantages of reducing the air feed rate under typical furnace operation. Based on principles of combustion and furnace operation, lower air feed rate may lead to improvement in overall combustion efficiency but could also cause incomplete combustion resulting in formation of harmful emissions and lowered heat output.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Engineering Education
Chemical engineering education lays the foundation for understanding complex processes like combustion reactions. It's crucial for students to grasp fundamental concepts such as balancing chemical equations, which is the first step in solving combustion problems. A strong grasp of thermodynamics is required as well, especially when calculating the heat transfer in reactors.

Students learn to apply these principles in real-world scenarios, such as analyzing furnace operations and reactor efficiency. In this context, knowing how to determine the composition of a fuel and calculate excess air are essential skills. The exercise in question challenges learners to use these concepts to analyze a gaseous fuel mixture burned with excess air, encouraging an application of theoretical knowledge to practical situations.
Stoichiometric Combustion Analysis
Stoichiometric combustion analysis is the process of quantifying the reactants and products in a combustion reaction to ensure the precise amount of oxygen is available for the complete burning of the fuel. This is vital for maintaining efficiency and minimizing harmful emissions in industrial processes.

An understanding of stoichiometry allows engineers to calculate the ideal ratios of fuel to oxygen. They use balanced chemical equations, as in the provided exercise where the combustion of methane and ethane is analyzed. By back-calculating the molar percentages of the fuel components, one can determine the precise fuel composition. This information is pivotal for optimizing reactions and ensuring complete combustion, which in turn maximizes energy output and minimizes pollutants such as carbon monoxide.
Heat Transfer in Reactors
Heat transfer in reactors is a fundamental aspect of chemical reactor design and operation. Reactors must be able to effectively manage the energy produced or consumed during reactions. In combustion reactions, such as the burning of methane and ethane in the given exercise, the heat transfer analysis determines how much heat is transferred from the reactor per unit of fuel gas fed.

Engineers use the specific heat formula \( Q = mc\Delta T \) to calculate the heat transfer, where \( Q \) is the heat transferred, \( m \) is the mass, \( c \) is the specific heat capacity of the substances involved, and \( \Delta T \) is the temperature change. This is critical for designing reactors that operate safely and efficiently. Additionally, the temperatures of the inlet and outlet streams are considered to accurately calculate the overall energy balance of the system.
Excess Air Calculation
Excess air calculation is used to determine the amount of air supplied to a reaction beyond the stoichiometric requirement. Providing excess air is common practice to ensure complete combustion, but it must be optimized to prevent energy loss and increase the efficiency of the combustion process.

In the exercise, the percentage of excess air fed to the reactor is calculated by comparing the stoichiometrically-required air to the actual air used. Ensuring the right amount of excess air is critical; too little can lead to incomplete combustion and higher emissions of pollutants, while too much can lower the combustion temperature and increase heat loss with the stack gases, thus reducing the reactor's thermal efficiency. Mastery of this calculation impacts the operational decisions in furnace management and is an excellent example of the application of chemical engineering principles.

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Most popular questions from this chapter

Methane and \(30 \%\) excess air are to be fed to a combustion reactor. An inexperienced technician mistakes his instructions and charges the gases together in the required proportion into an evacuated closed tank. (The gases were supposed to be fed directly into the reactor.) The contents of the charged tank are at \(25^{\circ} \mathrm{C}\) and 4.00 atm absolute. (a) Calculate the standard internal energy of combustion of the methane combustion reaction. \(\Delta \hat{U}_{c}^{\circ}(\mathrm{kJ} / \mathrm{mol}),\) taking \(\mathrm{CO}_{2}(\mathrm{g})\) and \(\mathrm{H}_{2} \mathrm{O}(\mathrm{v})\) as the presumed products. Then prove that if the constant-pressure heat capacity of an ideal-gas species is independent of temperature, the specific internal energy of that species at temperature \(T\left(^{\circ} \mathrm{C}\right)\) relative to the same species at \(25^{\circ} \mathrm{C}\) is given by the expression $$\hat{U}=\left(C_{p}-R\right)\left(T-25^{\circ} \mathrm{C}\right)$$ where \(R\) is the gas constant. Use this formula in the next part of the problem. (b) You wish to calculate the maximum temperature, \(T_{\max }\left(^{\circ} \mathrm{C}\right),\) and corresponding pressure, \(P_{\max }(\text { atm }),\) that the tank would have to withstand if the mixture it contains were to be accidentally ignited. Taking molecular species at \(25^{\circ} \mathrm{C}\) as references and treating all species as ideal gases, prepare an inlet-outlet internal energy table for the closed system combustion process. In deriving expressions for each \(\dot{U}_{i}\) at the final reactor condition \(\left(T_{\max }, P_{\max }\right),\) use the following approximate values for \(C_{p_{i}}\left[\mathrm{k} J /\left(\mathrm{mol} \cdot^{\circ} \mathrm{C}\right)\right]: 0.033 \mathrm{for} \mathrm{O}_{2}, 0.032\) for \(\mathrm{N}_{2}, 0.052 \mathrm{for} \mathrm{CO}_{2},\) and \(0.040 \mathrm{for} \mathrm{H}_{2} \mathrm{O}(\mathrm{v}) .\) Then use an energy balance and the ideal-gas equation of state to perform the required calculations. (c) Why would the actual temperature and pressure attained in a real tank be less than the values calculated in Part (a)? (State several reasons.) (d) Think of ways that the tank contents might be accidentally ignited. The list should suggest why accepted plant safety regulations prohibit the storage of combustible vapor mixtures.

Ethyl alcohol (ethanol) can be produced by the fermentation of sugars derived from agricultural products such as sugarcane and com. Some countries without large petroleum and natural gas reserves - such as Brazil - have found it profitable to convert a portion of their agricultural output to cthanol for fuel or for use as a feedstock in the synthesis of other chemicals. In one such process, a portion of the starch in corn is converted to ethanol in two consecutive reactions. In a saccharification reaction, starch decomposes in the presence of certain enzymes (biological catalysts) to form an aqueous mash containing maltose \(\left(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\right.\), a sugar) and several other decomposition products. The mash is cooled and combined with additional water and a yeast culture in a batch fermentation tank (fermentor). In the fermentation reaction (actually a complex series of reactions), the yeast culture grows and in the process converts maltose to ethanol and carbon dioxide: $$\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}+\mathrm{H}_{2} \mathrm{O} \rightarrow 4 \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}+4 \mathrm{CO}_{2}$$ The fermentor is a 550,000 gallon tank filled to \(90 \%\) of its capacity with a suspension of mash and yeast in water. The mass of the yeast is negligible compared to the total mass of the tank contents. Thermal energy is released by the exothermic conversion of maltose to ethanol. In an adiabatic operating stage, the temperature of the tank contents increases from an initial value of \(85^{\circ} \mathrm{F}\) to \(95^{\circ} \mathrm{F}\), and in a second stage the temperature is kept at \(95^{\circ} \mathrm{F}\) by a reactor cooling system. The final reaction mixture contains carbon dioxide dissolved in a slurry containing 7.1 wt\% ethanol, 6.9 wt\% soluble and suspended solids, and the balance water. The mixture is pumped to a flash evaporator in which \(\mathrm{CO}_{2}\) is vaporized, and the ethanol product is then separated from the remaining mixture components in a series of distillation and stripping operations. Data One bushel ( 56 Ib \(_{m}\) ) of corn yiclds 25 gallons of mash fed to the fermentor, which in turn yields 2.6 gallons of ethanol. Roughly 101 bushels of corn is harvested from an acre of land. A batch fermentation cycle (charging the fermentation tank, running the reaction, discharging the tank, and preparing the tank to receive the next load) takes eight hours. The process operates 24 hours per day, 330 days per year. The specific gravity of the fermentation reaction mixture is approximately constant at \(1.05 .\) The average heat capacity of the mixture is \(0.95 \mathrm{Btu} /\left(\mathrm{lb}_{\mathrm{m}} \cdot^{\circ} \mathrm{F}\right)\) The standard heat of combustion of maltose to form \(\mathrm{CO}_{2}(\mathrm{g})\) and \(\mathrm{H}_{2} \mathrm{O}(\mathrm{l})\) is \(\Delta H_{\mathrm{c}}^{\mathrm{o}}=-5649 \mathrm{kJ} / \mathrm{mol}\) (a) Calculate (i) the quantity of ethanol ( \(\left(\mathrm{b}_{\mathrm{m}}\right)\) produced per batch, (ii) the quantity of water (gal) that must be added to the mash and yeast in the fermentation tank, and (iii) the acres of land that must be harvested per year to keep the process running. (b) Calculate the standard heat of the maltose conversion reaction, \(\Delta H_{\mathrm{r}}^{\circ}\) (Btu). (c) Estimate the total amount of heat (Btu) that must be transferred from the fermentor during the reaction period. Take only the maltose conversion into account in this calculation (i.c., neglect the yeast growth reaction and any other reactions that may occur in the fermentor), assume that the heat of reaction is independent of temperature in the range from \(77^{\circ} \mathrm{F}\left(=25^{\circ} \mathrm{C}\right)\) to \(95^{\circ} \mathrm{F}\), and neglect the heat of solution of carbon dioxide in water. (d) Although Brazil and Venezuela are neighboring countries, producing ethanol from grain for use as a fuel is an important process in Brazil and an almost nonexistent one in Venezuela. What difference between the two countries probably accounts for this observation?

Formaldehyde may be produced in the reaction between methanol and oxygen: $$2 \mathrm{CH}_{3} \mathrm{OH}(\mathrm{l})+\mathrm{O}_{2}(\mathrm{g}) \rightarrow 2 \mathrm{HCHO}(\mathrm{g})+2 \mathrm{H}_{2} \mathrm{O}(\mathrm{l}): \quad \Delta H_{\mathrm{r}}^{\circ}=-326.2 \mathrm{kJ}$$ The standard heat of combustion of hydrogen is $$\mathrm{H}_{2}(\mathrm{g})+\frac{1}{2} \mathrm{O}_{2}(\mathrm{g}) \rightarrow \mathrm{H}_{2} \mathrm{O}(\mathrm{l}): \quad \Delta \hat{H}_{\mathrm{c}}^{\circ}=-285.8 \mathrm{kJ} / \mathrm{mol}$$ (a) Use these heats of reaction and Hess's law to determine the standard heat of the direct decomposition of mcthanol to form formaldchyde: $$\mathrm{CH}_{3} \mathrm{OH}(\mathrm{l}) \rightarrow \mathrm{HCHO}(\mathrm{g})+\mathrm{H}_{2}(\mathrm{g})$$ (b) Explain why you would probably use the method of Part (a) to determine the heat of the methanol decomposition reaction experimentally rather than carrying out the decomposition reaction and measuring \(\Delta H_{f}^{\circ}\) directly.

Methanol vapor is burned with excess air in a catalytic combustion chamber. Liquid methanol initially at \(25^{\circ} \mathrm{C}\) is vaporized at 1.1 atm and heated to \(100^{\circ} \mathrm{C}\); the vapor is mixed with air that has been preheated to \(100^{\circ} \mathrm{C},\) and the combined stream is fed to the reactor at \(100^{\circ} \mathrm{C}\) and 1 atm. The reactor effluent emerges at \(300^{\circ} \mathrm{C}\) and 1 atm. Analysis of the product gas yields a dry-basis composition of \(4.8 \% \mathrm{CO}_{2}\) \(14.3 \% \mathrm{O}_{2},\) and \(80.9 \% \mathrm{N}_{2}\) (a) Calculate the percentage excess air supplied and the dew point of the product gas. (b) Taking a basis of 1 g-mole of methanol burned, calculate the heat ( \(k\) J) needed to vaporize and heat the methanol feed, and the heat (kJ) that must be transferred from the reactor. (c) Suggest how the energy economy of this process could be improved. Then suggest why the company might choose not to implement your redesign.

The synthesis of cthyl chloride is accomplished by reacting ethylene with hydrogen chloride in the presence of an aluminum chloride catalyst: $$\mathrm{C}_{2} \mathrm{H}_{4}(\mathrm{g})+\mathrm{HCl}(\mathrm{g}) \stackrel{\text { catallyst }}{\longrightarrow} \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{Cl}(\mathrm{g}) ; \quad \Delta H_{\mathrm{r}}\left(0^{\circ} \mathrm{C}\right)=-64.5 \mathrm{kJ}$$ Process data and a simplified schematic flowchart are given here. Data Reactor: adiabatic, outlet temperature \(=50^{\circ} \mathrm{C}\) Feed A: \(100 \% \mathrm{HCl}(\mathrm{g}), 0^{\circ} \mathrm{C}\) Feed \(\mathrm{B}: 93\) mole \(\% \mathrm{C}_{2} \mathrm{H}_{4}, 7 \% \mathrm{C}_{2} \mathrm{H}_{6}, 0^{\circ} \mathrm{C}\) Reactor: adiabatic, outlet temperature \(=50^{\circ} \mathrm{C}\) Feed A: 100\% HCl(g), 0"C Feed B: 93 mole\% C_H_4, 7\% C_H_0, 0"C Product C: Consists of 1.5\% of the HCl, 1.5\% of the C_2 \(\mathrm{H}_{4}\), and all of the \(\mathrm{C}_{2} \mathrm{H}_{6}\) that enter the reactor Product D: \(1600 \mathrm{kg} \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{Cl}(\mathrm{l}) / \mathrm{h}, 0^{\circ} \mathrm{C}\) Recycle to reactor: \(\mathbf{C}_{2} \mathrm{H}_{5} \mathrm{Cl}(\mathrm{l}), 0^{\circ} \mathrm{C}\) \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{Cl}: \Delta \hat{H}_{\mathrm{y}}=24.7 \mathrm{kJ} / \mathrm{mol}\) (assume independent of \(T\) ) \(\left(C_{p}\right)_{C_{2} H_{3} C(v)}\left[\mathrm{kJ} /\left(\mathrm{mol} \cdot^{\circ} \mathrm{C}\right)\right]=0.052+8.7 \times 10^{-5} T\left(^{\circ} \mathrm{C}\right)\) The reaction is exothermic, and if the heat of reaction is not removed in some way, the reactor temperature could increase to an undesirably high level. To avoid this occurrence, the reaction is carried out with the catalyst suspended in liquid cthyl chloride. As the reaction proceeds, most of the heat liberated goes to vaporize the liquid, making it possible to keep the reaction temperature at or below 50^'C. The stream leaving the reactor contains cthyl chloride formed by reaction and that vaporized in the reactor. This stream passes through a heat exchanger where it is cooled to \(0^{\circ} \mathrm{C},\) condensing essentially all of the cthyl chloride and leaving only unreacted \(\mathrm{C}_{2} \mathrm{H}_{4}, \mathrm{HCl}\), and \(\mathrm{C}_{2} \mathrm{H}_{6}\) in the gas phase. A portion of the liquid condensate is recycled to the reactor at a rate equal to the rate at which ethyl chloride is vaporized, and the rest is taken off as product. At the process conditions, heats of mixing and the influence of pressure on enthalpy may be neglected. (a) At what rates (kmol/h) do the two feed streams enter the process? (b) Calculate the composition (component mole fractions) and molar flow rate of product stream \(\mathrm{C}\). (c) Write an energy balance around the reactor and use it to determine the rate at which ethyl chloride must be recycled. (d) A number of simplifying assumptions were made in the process description and the analysis of this process system, so the results obtained using a more realistic simulation would differ considerably from those you should have obtained in Parts (a)-(c). List as many of these assumptions as you can think of.

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