/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 50 Eight fluid ounces \((1 \mathrm{... [FREE SOLUTION] | 91Ó°ÊÓ

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Eight fluid ounces \((1 \mathrm{qt}=32 \mathrm{oz})\) of a beverage in a glass at \(18.0^{\circ} \mathrm{C}\) is to be cooled by adding ice and stirring. The properties of the beverage may be taken to be those of liquid water. The enthalpy of the ice relative to liquid water at the triple point is \(-348 \mathrm{kJ} / \mathrm{kg} .\) Estimate the mass of ice (g) that must melt bring the liquid temperature to \(4^{\circ} \mathrm{C},\) neglecting energy losses to the surroundings.

Short Answer

Expert verified
Approximately 40 g of ice must be added to the beverage to cool it from 18.0°C to 4.0°C.

Step by step solution

01

Convert quantities

First, convert the initial quantity of the liquid from ounces to kg: \(8 oz = 0.237 kg\) (since 1 oz = 0.0283495 kg). This gives us the mass of the beverage (m1) as 0.237 kg. The temperature change (dt) of the beverage is \(18.0° C - 4° C = 14° C\).
02

Calculate the energy lost by the beverage

Next, calculate the energy (Q1) that the beverage will lose using the specific heat equation: \( Q = mcΔT \) where m is mass, c is the specific heat capacity of water (\(4.18 kJ/(kg°C)\)), and ΔT is the temperature change. Thus, \(Q1 = 0.237 kg * 4.18 kJ/(kg°C) * 14°C = 13.94 kJ\). This is the amount of heat that needs to be taken by the ice to achieve the desired temperature.
03

By using the enthalpy of fusion, calculate the mass of ice required

Finally, calculate the mass of ice (m2) required to absorb this heat. This can be done using the equation for latent heat and the value of the enthalpy given (Hf = -348 kJ/kg). Rearranging for m gives \( m = Q/Hf = 13.94 kJ/-(-348 kJ/kg) = 0.04 kg\). Convert this value from kg to g: \(m2 = 0.04 kg * 1000 g/kg = 40 g\).
04

Conclusion

Therefore, to cool the beverage from 18°C to 4°C, approximately 40 g of ice must be added.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Specific Heat Capacity
Specific heat capacity is an important concept in thermodynamics, especially when dealing with the heat transfer in liquids like water. It defines how much energy is needed to raise the temperature of a certain mass of a substance by 1°C. For water, this value is high at 4.18 kJ/kg°C. This means water can absorb a lot of heat before it increases its temperature significantly.
When solving problems related to specific heat capacity, the formula used is \( Q = mc\Delta T \) where:
  • \( m \) is the mass of the substance (in kilograms)
  • \( c \) is the specific heat capacity (in kJ/kg°C)
  • \( \Delta T \) is the change in temperature (in °C)
  • \( Q \) is the heat transferred (in kJ)
In the context of the exercise, we calculate how much heat the beverage loses as it cools. This is crucial for finding out how much heat the ice needs to absorb to balance this loss and lower the drink's temperature as desired. By knowing the specific heat capacity, we can determine the total heat energy involved based on the temperature change.
Enthalpy of Fusion
The enthalpy of fusion refers to the amount of energy required to convert a solid into a liquid at its melting point without changing temperature. For water, this involves transforming ice into liquid water. The enthalpy of fusion for ice is given as \(-348 \text{kJ/kg}\), which indicates the energy absorbed from the surroundings for the phase change.Understanding this concept helps address questions about how much ice is needed in thermal problems. Calculating the mass of ice needed to absorb heat during a process, like cooling a beverage, requires applying the concept of enthalpy of fusion. In mathematical terms, the formula is:\[ m = \frac{Q}{H_f} \]where:
  • \( m \) is the mass of the ice required (in kilograms)
  • \( Q \) is the heat to be absorbed (in kJ)
  • \( H_f \) is the enthalpy of fusion (in kJ/kg)
In the exercise, ice is added to absorb the heat lost from the cooling beverage. Calculating this correctly ensures that there's enough ice melting to bring the drink down to its desired temperature.
Heat Transfer
Heat transfer is a fundamental concept that describes the movement of heat from one substance to another. It can take place through conduction, convection, or radiation, but in scenarios like cooling a beverage with ice, conduction is the primary method. When two substances at different temperatures come in contact, heat flows from the warmer to the cooler substance until equilibrium is reached.Several real-life scenarios demonstrate this concept, such as adding ice to a drink to cool it. In the exercise, heat is transferred from the warmer beverage to the colder ice. This causes the ice to absorb heat and melt, while simultaneously lowering the temperature of the beverage. The efficiency of heat transfer is critical in determining how much of the colder substance is required to reach a desired temperature change. The formula \( Q = mc\Delta T \) can precisely calculate the amount of transferred heat. Understanding this process allows us to accurately gauge how substances undergo changes in temperature through their interactions with other materials.

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Most popular questions from this chapter

Liquid water at 60 bar and \(250^{\circ} \mathrm{C}\) passes through an adiabatic expansion valve, emerging at a pressure \(P_{\mathrm{f}}\) and temperature \(T_{\mathrm{f}} .\) If \(P_{\mathrm{f}}\) is low enough, some of the liquid evaporates. (a) If \(P_{\mathrm{f}}=1.0\) bar, determine the temperature of the final mixture \(\left(T_{\mathrm{f}}\right)\) and the fraction of the liquid feed that evaporates \(\left(y_{\mathrm{v}}\right)\) by writing an energy balance about the valve and neglecting \(\Delta \dot{E}_{\mathrm{k}}\) (b) If you took \(\Delta \dot{E}_{\mathrm{k}}\) into account in Part (a), how would the calculated outlet temperature compare with the value you determined? What about the calculated value of \(y_{\mathrm{v}} ?\) Explain. (c) What is the value of \(P_{\mathrm{f}}\) above which no evaporation would occur? (d) Sketch the shapes of plots of \(T_{\mathrm{f}}\) versus \(P_{\mathrm{f}}\) and \(y_{\mathrm{v}}\) versus \(P_{\mathrm{f}}\) for 1 bar \(\leq P_{\mathrm{f}} \leq 60\) bar. Briefly explain your reasoning.

Arsenic contamination of aquifers is a major health problem in much of the world and is particularly severe in Bangladesh. One method of removing the arsenic is to pump water from an aquifer to the surface and through a bed packed with granular material containing iron oxide, which binds the arsenic. The purified water is then either used or allowed to seep back through the ground into the aquifer. In an installation of the type just described, a pump draws 69.1 gallons per minute of contaminated water from an aquifer through a 3 -inch ID pipe and then discharges the water through a 2-inch ID pipe to an open overhead tank filled with granular material. The water leaves the end of the discharge line 80 feet above the water in the aquifer. The friction losses in the piping system are \(10 \mathrm{ft} \cdot \mathrm{lb}_{\mathrm{f}} / \mathrm{lb}_{\mathrm{m}}\) (a) If the pump is \(70 \%\) efficient (i.e., \(30 \%\) of the electrical energy delivered to the pump is not used in pumping the water), what is the required pump horsepower? (b) Even if we assume that the iron oxide binds \(100 \%\) of the arsenic, what other factors limit the effectiveness of this operation?

Oxygen at \(150 \mathrm{K}\) and 41.64 atm has a tabulated specific volume of \(4.684 \mathrm{cm}^{3} / \mathrm{g}\) and a specific internal energy of 1706 J/mol. (a) The figure \(1706 \mathrm{J} / \mathrm{mol}\) is not the true internal energy of one g-mole of oxygen gas at \(150 \mathrm{K}\) and 41.64 atm. Why not? In a sentence, state the correct physical significance of that figure. (The term "reference state" should appear in your statement.) (b) Calculate the specific enthalpy of \(\mathrm{O}_{2}(\mathrm{J} / \mathrm{mol})\) at \(150 \mathrm{K}\) and \(41.64 \mathrm{atm},\) and state the physical significance of this figure. What can you say about the reference state used to calculate it?

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