Chapter 8: Problem 67
Explain the concept of resonance.
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Chapter 8: Problem 67
Explain the concept of resonance.
These are the key concepts you need to understand to accurately answer the question.
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Chlorine Bleach Chlorine combines with oxygen in several proportions. Dichlorine monoxide (Cl \(_{2} \mathrm{O}\) ) is used in the manufacture of bleaching agents. Potassium chlorate \(\left(\mathrm{KClO}_{3}\right)\) is used in oxygen generators aboard aircraft. Draw the Lewis structures for \(\mathrm{Cl}_{2} \mathrm{O}\) and \(\mathrm{ClO}_{3}^{-}\).
Origins of Life The discovery of polyatomic organic molecules such as cyanamide (H \(_{2} \mathrm{NCN}\) ) in interstellar space has led some scientists to believe that the molecules from which life began on Earth may have come from space. Draw Lewis structures for cyanamide, and select the preferred structure on the basis of formal charges.
In which of the following molecules does the phosphorus atom have an expanded valence shell? (a) \(\mathrm{POCl}_{3} ;\) (b) \(\mathrm{PF}_{5}\) (c) \(\left.\mathrm{PF}_{3} ; \text { (d) } \mathrm{P}_{2} \mathrm{F}_{4} \text { (which has a } \mathrm{P}-\mathrm{P} \text { bond }\right)\).
Which of the following chlorine oxides are odd-electron molecules? (a) \(\mathrm{Cl}_{2} \mathrm{O}_{7} ;\) (b) \(\mathrm{Cl}_{2} \mathrm{O}_{6} ;\) (c) \(\mathrm{ClO}_{4} ;\) (d) \(\mathrm{ClO}_{3}\) (e) \(\mathrm{ClO}_{2}\).
The cation \(\mathrm{N}_{2} \mathrm{F}^{+}\) is isoelectronic with \(\mathrm{N}_{2} \mathrm{O}\). a. What does it mean to be isoelectronic? b. Draw the Lewis structure for \(\mathrm{N}_{2} \mathrm{F}^{+}\). (Hint: The molecule contains a nitrogen-nitrogen bond.) c. Which atom has the +1 formal charge in the structure you drew in part (b)? d. Does \(\mathrm{N}_{2} \mathrm{F}^{+}\) have resonance forms? e. Could the middle atom in the \(\mathrm{N}_{2} \mathrm{F}^{+}\) ion be a fluorine atom? Explain your answer.
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