Chapter 5: Problem 73
How is Hess's law consistent with the law of conservation of energy?
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Chapter 5: Problem 73
How is Hess's law consistent with the law of conservation of energy?
These are the key concepts you need to understand to accurately answer the question.
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At an elevation where the boiling point of water is \(93^{\circ} \mathrm{C}, 100.0 \mathrm{g}\) of water at \(30^{\circ} \mathrm{C}\) absorbs \(290.0 \mathrm{kJ}\) of energy from a mountain climber's stove. Is this amount of energy sufficient to heat the water to its boiling point?
What is \(\Delta H_{\text {rxn }}\) for the reaction between \(\mathrm{H}_{2} \mathrm{S}\) and \(\mathrm{O}_{2}\) that yields \(\mathrm{SO}_{2}\) and water, \(2 \mathrm{H}_{2} \mathrm{S}(g)+3 \mathrm{O}_{2}(g) \rightarrow 2 \mathrm{SO}_{2}(g)+2 \mathrm{H}_{2} \mathrm{O}(g) \quad \Delta H_{\mathrm{rxn}}=?\) given \(\Delta H_{\mathrm{rxn}}\) for the following reactions? $$\begin{aligned} \mathrm{H}_{2}(g)+\frac{1}{2} \mathrm{O}_{2}(g) \rightarrow \mathrm{H}_{2} \mathrm{O}(g) & & \Delta H_{\mathrm{rxn}}=-241.8 \mathrm{kJ} \\ \mathrm{SO}_{2}(g)+3 \mathrm{H}_{2}(g) \rightarrow \mathrm{H}_{2} \mathrm{S}(g)+2 \mathrm{H}_{2} \mathrm{O}(g) & & \Delta H_{\mathrm{rxn}}=34.8 \mathrm{kJ} \end{aligned}$$
Which of the following would reach the higher temperature after \(10.00 \mathrm{g}\) of iron \(\left[c_{\mathrm{P}}=25.1 \mathrm{J} /\left(\mathrm{mol} \cdot^{\circ} \mathrm{C}\right)\right]\) at \(150^{\circ} \mathrm{C}\) is added: 100 mL of water \(\left[d=1.00 \mathrm{g} / \mathrm{mL}, c_{\mathrm{P}}=75.3 \mathrm{J} /\right.\) \(\left.\left(\mathrm{mol} \cdot^{\circ} \mathrm{C}\right)\right]\) or \(200 \mathrm{mL}\) of ethanol \(\left[\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\right.\) \(\left.d=0.789 \mathrm{g} / \mathrm{mL}, c_{\mathrm{P}}=113.1 \mathrm{J} /\left(\mathrm{mol} \cdot^{\circ} \mathrm{C}\right)\right] ?\)
Cleansing the Atmosphere The atmosphere contains the highly reactive molecule OH, which acts to remove selected pollutants. Use the values for \(\Delta H_{\mathrm{rxn}}\) given below to find the \(\Delta H_{\mathrm{rxn}}\) for the formation of \(\mathrm{OH}\) and \(\mathrm{H}\) from water. $$\begin{array}{rll} \frac{1}{2} \mathrm{H}_{2}(g)+\frac{1}{2} \mathrm{O}_{2}(g) \rightarrow \mathrm{OH}(g) & \Delta H_{\mathrm{rm}}=42.1 \mathrm{kJ} \\ \mathrm{H}_{2}(g) \rightarrow 2 \mathrm{H}(g) & \Delta H_{\mathrm{rm}}=435.9 \mathrm{kJ} \\ \mathrm{H}_{2}(g)+\frac{1}{2} \mathrm{O}_{2}(g) \rightarrow \mathrm{H}_{2} \mathrm{O}(g) & \Delta H_{\mathrm{rrm}}=-241.8 \mathrm{kJ} \\ \mathrm{H}_{2} \mathrm{O}(g) \rightarrow \mathrm{H}(g)+\mathrm{OH}(g) & \Delta H_{\mathrm{rm}}=? \end{array}$$
Are the enthalpies of fusion and vaporization of a given substance usually the same?
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