Chapter 5: Problem 15
What is meant by the terms system and surroundings?
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Chapter 5: Problem 15
What is meant by the terms system and surroundings?
These are the key concepts you need to understand to accurately answer the question.
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You are given the following data $$\begin{aligned} \frac{1}{2} \mathrm{N}_{2}(g)+\frac{1}{2} \mathrm{O}_{2}(g) \rightarrow \mathrm{NO}(g) & & \Delta H_{\mathrm{rxn}}^{\circ}=+90.3 \mathrm{kJ} \\ \mathrm{NO}(g)+\frac{1}{2} \mathrm{Cl}_{2}(g) \rightarrow \mathrm{NOCl}(g) & & \Delta H_{\mathrm{rxn}}^{\circ}=-38.6 \mathrm{kJ} \\ 2 \mathrm{NOCl}(g) \rightarrow \mathrm{N}_{2}(g)+\mathrm{O}_{2}(g)+\mathrm{Cl}_{2}(g) & \Delta H_{\mathrm{rxn}}^{\circ} &=? \end{aligned}$$ a. Which of the \(\Delta H_{\text {rxn }}^{\circ}\) values represent enthalpies of formation? b. Determine \(\Delta H_{\mathrm{rxn}}^{\circ}\) for the decomposition of \(\mathrm{NOCl}\)
Calculate the standard enthalpy of formation of \(\mathrm{SO}_{2}(g)\) from the standard enthalpy changes of the following reactions: $$\begin{aligned} 2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \rightarrow 2 \mathrm{SO}_{3}(g) & & \Delta H_{\mathrm{rxn}}^{\circ}=-196 \mathrm{kJ} \\ \frac{1}{4} \mathrm{S}_{8}(s)+3 \mathrm{O}_{2}(g) \rightarrow 2 \mathrm{SO}_{3}(g) & & \Delta H_{\operatorname{man}}^{\circ}=-790 \mathrm{kJ} \\\ \frac{1}{8} \mathrm{S}_{8}(s)+\mathrm{O}_{2}(g) \rightarrow \mathrm{SO}_{2}(g) & \Delta H_{5}^{\circ} &=? \end{aligned}$$
How can the first two of the following reactions be combined to obtain the third reaction? a. \(\mathrm{CO}(g)+\mathrm{NH}_{3}(g) \rightarrow \mathrm{HCN}(g)+\mathrm{H}_{2} \mathrm{O}(g)\) b. \(\mathrm{CO}(g)+3 \mathrm{H}_{2}(g) \rightarrow \mathrm{CH}_{4}(g)+\mathrm{H}_{2} \mathrm{O}(g)\) c. \(\mathrm{CH}_{4}(g)+\mathrm{NH}_{3}(g) \rightarrow \mathrm{HCN}(g)+3 \mathrm{H}_{2}(g)\)
Brazilians are quite familiar with fueling their automobiles with ethanol, a fermentation product from sugarcane. Calculate the standard molar enthalpy for the complete combustion of liquid ethanol by using the standard enthalpies of formation of the reactants and products as given in Appendix 4.
Calculate \(\Delta E\) for the following situations: a. \(q=120.0 \mathrm{J} ; w=-40.0 \mathrm{J}\) b. \(q=9.2 \mathrm{kJ} ; w=0.70 \mathrm{J}\) c. \(q=-625 \mathrm{J} ; w=-315 \mathrm{J}\)
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