Chapter 4: Problem 96
What is meant by a half-reaction?
Short Answer
Step by step solution
Key Concepts
These are the key concepts you need to understand to accurately answer the question.
/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none}
Learning Materials
Features
Discover
Chapter 4: Problem 96
What is meant by a half-reaction?
These are the key concepts you need to understand to accurately answer the question.
All the tools & learning materials you need for study success - in one app.
Get started for free
Bactericide and Virucide The water-soluble gas \(\mathrm{ClO}_{2}\) is known as an oxidative biocide. It destroys bacteria by oxidizing their cell walls and destroys viruses by attacking their viral envelopes. \(\mathrm{ClO}_{2}\) may be prepared for use as a decontaminating agent from several different starting materials in slightly acidic solutions. Complete and balance the following chemical equations for the synthesis of \(\mathrm{ClO}_{2}\) a. \(\mathrm{ClO}_{3}^{-}(a q)+\mathrm{SO}_{2}(g) \rightarrow \mathrm{ClO}_{2}(g)+\mathrm{SO}_{4}^{2-}(a q)\) b. \(\mathrm{ClO}_{3}^{-}(a q)+\mathrm{Cl}^{-}(a q) \rightarrow \mathrm{ClO}_{2}(g)+\mathrm{Cl}_{2}(g)\) c. \(\mathrm{ClO}_{3}^{-}(a q)+\mathrm{Cl}_{2}(g) \rightarrow \mathrm{ClO}_{2}(g)+\mathrm{O}_{2}(g)\)
Calculate the mass of \(\mathrm{MgCO}_{3}\) precipitated by mixing \(10.0 \mathrm{mL}\) of a \(0.200 M \mathrm{Na}_{2} \mathrm{CO}_{3}\) solution with \(5.00 \mathrm{mL}\) of \(0.0500 M \mathrm{Mg}\left(\mathrm{NO}_{3}\right)_{2}\) solution.
Antifreeze Ethylene glycol is the common name for the liquid used to keep the coolant in automobile cooling systems from freezing. It is \(38.7 \%\) carbon, \(9.7 \%\) hydrogen, and \(51.6 \%\) oxygen by mass. Its molar mass is \(62.07 \mathrm{g} / \mathrm{mol}\) and its density is \(1.106 \mathrm{g} / \mathrm{mL}\) at \(20^{\circ} \mathrm{C}\) a. What is the empirical formula of ethylene glycol? b. What is the molecular formula of ethylene glycol? c. In a solution prepared by mixing equal volumes of water and ethylene glycol, which ingredient is the solute and which is the solvent?
Rocks in Caves The stalactites and stalagmites in most caves are made of limestone (calcium carbonate; see Figure 4.14 ). However, in the Lower Kane Cave in Wyoming they are made of gypsum (calcium sulfate). The presence of \(\mathrm{CaSO}_{4}\) is explained by the following sequence of reactions: $$ \mathrm{H}_{2} \mathrm{S}(a q)+2 \mathrm{O}_{2}(g) \rightarrow \mathrm{H}_{2} \mathrm{SO}_{4}(a q) $$ \(\mathrm{H}_{2} \mathrm{SO}_{4}(a q)+\mathrm{CaCO}_{3}(s) \rightarrow \mathrm{CaSO}_{4}(s)+\mathrm{H}_{2} \mathrm{O}(\ell)+\mathrm{CO}_{2}(g)\) a. Which (if either) of these reactions is a redox reaction? How many electrons are transferred? b. Write a net ionic equation for the reaction of \(\mathrm{H}_{2} \mathrm{SO}_{4}\) with \(\mathrm{CaCO}_{3}\) c. How would the net ionic equation be different if the reaction were written as follows? \(\mathrm{H}_{2} \mathrm{SO}_{4}(a q)+\mathrm{CaCO}_{3}(s) \rightarrow \mathrm{CaSO}_{4}(s)+\mathrm{H}_{2} \mathrm{CO}_{3}(a q)\)
Preparation of Fluorine Gas HF is prepared by reacting \(\mathrm{CaF}_{2}\) with \(\mathrm{H}_{2} \mathrm{SO}_{4}:\) $$ \mathrm{CaF}_{2}(s)+\mathrm{H}_{2} \mathrm{SO}_{4}(\ell) \rightarrow 2 \mathrm{HF}(g)+\mathrm{CaSO}_{4}(s) $$ HF can in turn be electrolyzed when dissolved in molten KF to produce fluorine gas: $$ 2 \mathrm{HF}(\ell) \rightarrow \mathrm{F}_{2}(g)+\mathrm{H}_{2}(g) $$ Fluorine is extremely reactive, so it is typically sold as a \(5 \%\) mixture by volume in an inert gas such as helium. How much \(\mathrm{CaF}_{2}\) is required to produce \(500.0 \mathrm{L}\) of \(5 \% \mathrm{F}_{2}\) in helium? Assume the density of \(\mathrm{F}_{2}\) gas is \(1.70 \mathrm{g} / \mathrm{L}\)
What do you think about this solution?
We value your feedback to improve our textbook solutions.