Chapter 18: Problem 86
Describe three factors limiting widespread use of cars powered by fuel cells.
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Chapter 18: Problem 86
Describe three factors limiting widespread use of cars powered by fuel cells.
These are the key concepts you need to understand to accurately answer the question.
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The anode in an electrochemical cell is defined as the electrode where oxidation takes place. Why is the anode in an electrolytic cell connected to the positive \((+)\) terminal of an external supply, whereas the anode in a voltaic cell battery is connected to the negative \((-)\) terminal?
The half-reactions and standard potentials for a nickelmetal hydride battery with a titanium-zirconium anode are as follows: Cathode: \(\quad \mathrm{NiO}(\mathrm{OH})(s)+\mathrm{H}_{2} \mathrm{O}(\ell)+\mathrm{e}^{-} \rightarrow \mathrm{Ni}(\mathrm{OH})_{2}(s)+\mathrm{OH}^{-}(a q)\) \(E^{*}=0.52 \mathrm{V}\) Anode: \(\quad \mathrm{TiZr}_{2} \mathrm{H}(s)+\mathrm{OH}^{-}(a q) \rightarrow \mathrm{TiZr}_{2}(s)+\mathrm{H}_{2} \mathrm{O}(\ell)+\mathrm{e}^{-}\) \(E^{\circ}=0.00 \mathrm{V}\) a. Write the overall cell reaction for this battery. b. Calculate the standard cell potential.
Regarding the porous separator between the two halves of an electrochemical cell: a. Describe how it allows electrical charge to flow between the two half- cells. b. Explain why a piece of wire could not perform the same function.
Super Iron Batteries In \(1999,\) scientists in Israel developed a battery based on the following cell reaction with iron(VI), nicknamed "super iron": \(\beth \mathrm{K}_{2} \mathrm{FeO}_{4}(a q)+3 \mathrm{Zn}(s) \rightarrow \mathrm{Fe}_{2} \mathrm{O}_{3}(s)+\mathrm{ZnO}(s)+2 \mathrm{K}_{2} \mathrm{ZnO}_{2}(a q)\) a. Determine the number of electrons transferred in the cell reaction. b. What are the oxidation states of the transition metals in the reaction? c. Draw the cell diagram.
The positive terminal of a voltaic cell is the cathode. However, the cathode of an electrolytic cell is connected to the negative terminal of a power supply. Explain this difference in polarity.
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