Chapter 18: Problem 86
Describe three factors limiting widespread use of cars powered by fuel cells.
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Chapter 18: Problem 86
Describe three factors limiting widespread use of cars powered by fuel cells.
These are the key concepts you need to understand to accurately answer the question.
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In the redox reaction below, how many electrons are transferred for each molecule of \(\mathrm{H}_{2} \mathrm{O}_{2}\) consumed? \(2 \mathrm{MnO}_{4}^{-}(a q)+3 \mathrm{H}_{2} \mathrm{O}_{2}(a q) \rightarrow\) $$2 \mathrm{MnO}_{2}(s)+3 \mathrm{O}_{2}(g)+2 \mathrm{OH}^{-}(a q)+2 \mathrm{H}_{2} \mathrm{O}(\ell)$$
An electrochemical cell with an aqueous electrolyte is based on the reaction between \(\mathrm{Ni}^{2+}(a q)\) and \(\mathrm{Cd}(s)\) producing \(\mathrm{Ni}(s)\) and \(\mathrm{Cd}^{2+}(a q)\) a. Write half-reactions for the anode and cathode. b. Write a balanced net ionic equation describing the cell reaction. c. Draw the cell diagram.
Voltaic cells based on the following pairs of half-reactions are constructed. For each pair, write a balanced equation for the cell reaction, and identify which half-reaction takes place at each anode and cathode. a. \(\mathrm{Cd}^{2+}(a q)+2 \mathrm{e}^{-} \rightarrow \mathrm{Cd}(s)\) \(\mathrm{Ag}^{+}(a q)+\mathrm{e}^{-} \rightarrow \mathrm{Ag}(s)\) b. \(\mathrm{AgBr}(s)+\mathrm{e}^{-} \rightarrow \mathrm{Ag}(s)+\mathrm{Br}^{-}(a q)\) \(\mathrm{MnO}_{2}(s)+4 \mathrm{H}^{+}(a q)+2 \mathrm{e}^{-} \rightarrow \mathrm{Mn}^{2+}(a q)+2 \mathrm{H}_{2} \mathrm{O}(\ell)\) c. \(\mathrm{PtCl}_{4}^{2-}(a q)+2 \mathrm{e}^{-} \rightarrow \mathrm{Pt}(s)+4 \mathrm{Cl}^{-}(a q)\) \(\mathrm{AgCl}(s)+\mathrm{e}^{-} \rightarrow \mathrm{Ag}(s)+\mathrm{Cl}^{-}(a q)\)
The standard potential of the Cu-Zn cell reaction, $$\mathrm{Zn}(s)+\mathrm{Cu}^{2+}(a q) \rightarrow \mathrm{Zn}^{2+}(a q)+\mathrm{Cu}(s)$$ is \(1.10 \mathrm{V} .\) Would the potential of the Cu-Zn cell differ from \(1.10 \mathrm{V}\) if the concentrations of both \(\mathrm{Cu}^{2+}\) and \(\mathrm{Zn}^{2+}\) were \(0.25 M ?\)
If a piece of silver is placed in a solution in which \(\left[\mathrm{Ag}^{+}\right]=\left[\mathrm{Cu}^{2+}\right]=1.00 \mathrm{M},\) will the following reaction proceed spontaneously? $$2 \mathrm{Ag}(s)+\mathrm{Cu}^{2+}(a q) \rightarrow 2 \mathrm{Ag}^{+}(a q)+\mathrm{Cu}(s)$$
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