Chapter 11: Problem 55
What is a semipermeable membrane?
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Chapter 11: Problem 55
What is a semipermeable membrane?
These are the key concepts you need to understand to accurately answer the question.
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Calculate the osmotic pressure of each of the following aqueous solutions at \(20^{\circ} \mathrm{C}:\) a. \(2.39 M\) methanol \(\left(\mathrm{CH}_{3} \mathrm{OH}\right)\) b. \(9.45 \mathrm{mM} \mathrm{MgCl}_{2}\) c. \(40.0 \mathrm{mL}\) of glycerol \(\left(\mathrm{C}_{3} \mathrm{H}_{8} \mathrm{O}_{3}\right)\) in \(250.0 \mathrm{mL}\) of aqueous solution (density of glycerol \(=1.265 \mathrm{g} / \mathrm{mL}\) ) d. \(25 \mathrm{g}\) of \(\mathrm{CaCl}_{2}\) in \(350 \mathrm{mL}\) of solution
Rank the following ionic compounds in order of (a) increasing melting point and (b) increasing water solubility: \(\mathrm{BaF}_{2}, \mathrm{CaCl}_{2}, \mathrm{MgBr}_{2},\) and \(\mathrm{SrI}_{2}\)
Which has the higher melting point, LiF or MgO?
Determine the molarity of each of the following solutions from its osmotic pressure at \(25^{\circ} \mathrm{C} .\) Include the van 't Hoff factor for the solution when the factor is given. a. \(\Pi=0.0259\) atm for a solution of urea \(\left[\mathrm{CO}\left(\mathrm{NH}_{2}\right)_{2}\right]\) b. \(\Pi=1.56\) atm for a solution of sucrose \(\left(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\right)\) c. \(\Pi=0.697\) atm for a solution of \(\mathrm{KI}, i=1.90\)
How can measurements of osmotic pressure, freezing point depression, and boiling point elevation be used to find the molar mass of a solute? Why are such determinations usually carried out on molecular substances as opposed to ionic ones?
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