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91Ó°ÊÓ

Define the term "superconductor." Give the chemical formulas of two kinds of superconductors and their associated transition temperatures.

Short Answer

Expert verified
Superconductors conduct electricity without resistance below specific temperatures. Examples: YBCO at 93K and HgBaCaCuO at about 133K.

Step by step solution

01

Understanding Superconductors

A superconductor is a material that can conduct electricity with zero resistance when it is cooled below a certain critical temperature, known as the transition temperature. This allows for the creation of powerful magnetic fields and the possibility of lossless power transmission.
02

Chemical Formulas of Superconductors

Common examples of superconductors include Yttrium Barium Copper Oxide (YBCO) and Mercury Barium Calcium Copper Oxide (HgBaCaCuO). These materials are well-known for their high-temperature superconducting properties.
03

Identifying Transition Temperatures

Yttrium Barium Copper Oxide (YBCO) has a transition temperature around 93 Kelvin, while Mercury Barium Calcium Copper Oxide can have a transition temperature of around 133 Kelvin. These temperatures vary slightly based on specific formulations and preparations.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Zero resistance
Superconductors are unique materials that exhibit an amazing property: zero electrical resistance. This means that when electricity flows through a superconductor, it encounters no opposition. Unlike regular materials, where resistance causes the loss of energy as heat, superconductors preserve the energy completely. Because of zero resistance, superconductors can transport electric current indefinitely without a power source to sustain them. This property opens up exciting possibilities for creating efficient power lines and speeding up electronic processes.

Furthermore, zero resistance allows superconductors to generate exceptionally strong magnetic fields, useful in technologies like Magnetic Resonance Imaging (MRI) machines. The no-resistance flow ensures stability and efficiency that are unachievable in non-superconducting materials.
Transition temperature
To become superconducting, a material must be cooled to a specific temperature, known as the transition temperature or critical temperature ( T_c ). Below this temperature, the material's resistance drops to zero and it exhibits superconductivity. Transition temperatures vary greatly among materials, and finding substances that remain superconductive at manageable temperatures is a big goal in research.

For example, Mercury Barium Calcium Copper Oxide (HgBaCaCuO) has one of the highest known transition temperatures at approximately 133 Kelvin. Understanding and increasing the transition temperature of materials is vital because it determines the feasibility and cost-effectiveness of using superconductors in everyday applications. When the transition temperature is close to the temperature of liquid nitrogen (77 Kelvin), using superconductors becomes much more practical for widespread use.
High-temperature superconductors
High-temperature superconductors (HTS) are superconductors that function at relatively higher temperatures than traditional ones. Most HTS materials discovered, including Yttrium Barium Copper Oxide (YBCO), work well above 77 Kelvin. This makes them appealing because they can potentially reduce cooling costs significantly, as cooling to liquid nitrogen temperatures is more affordable than cooling to absolute zero.

HTS materials are often composed of complex oxides and exhibit superconductivity due to their intricate electronic structures. These materials hold promise for various technological advancements because they offer the benefits of superconductivity without the extreme cooling requirements of traditional superconductors. As a result, they are heavily studied for applications ranging from medical devices to power grids and magnetic levitation trains.

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Most popular questions from this chapter

How does conductivity vary with temperature for (a) a metallic conductor, (b) a nonconductor, (c) a semiconductor, and (d) a superconductor? In your answer, begin at high temperatures and come down to low temperatures.

Explain how the changes of the density of water with temperature causes "turnover" in a lake in the spring and fall. Explain why the turnover is important.

Potassium chloride and rubidium chloride both have the sodium chloride structure (Figure 9.24 ). X-ray diffraction experiments indicate that their cubic unit cell dimensions are \(629 \mathrm{pm}\) and \(658 \mathrm{pm}\), respectively. (i) One \(m o l \mathrm{KCl}\) and \(1 \mathrm{~mol} \mathrm{RbCl}\) are ground together to a very fine powder in a mortar and pestle, and the X-ray diffraction pattern of the pulverized solid is measured. Two patterns are observed, each corresponding to a cubic unit cell-one with an edge length of \(629 \mathrm{pm}\) and one with an edge length of \(658 \mathrm{pm}\). Call this Sample 1 . (ii) One \(\mathrm{mol} \mathrm{KCl}\) and \(1 \mathrm{~mol} \mathrm{RbCl}\) are heated until the entire mixture is molten and then cooled to room temperature. A single X-ray diffraction pattern indicates a cubic unit cell with an edge length of roughly \(640 \mathrm{pm}\). Call this Sample 2 . (a) Suppose that Samples 1 and 2 were analyzed for their chloride content. What fraction of each sample is chloride? Could the samples be distinguished by means of chemical analysis? (b) Interpret the two X-ray diffraction results in terms of the structures of the crystal lattices of Samples 1 and 2 . (c) What chemical formula should you write for Sample \(1 ?\) For Sample \(2 ?\) (d) Suppose that you dissolved \(1.00 \mathrm{~g}\) Sample 1 in \(100 \mathrm{~mL}\) water in a beaker and did the same with \(1.00 \mathrm{~g}\) Sample 2\. Which sample would conduct electricity better, or would both be the same? What ions would be present in each solution at what concentrations?

The chlorofluorocarbon \(\mathrm{CCl}_{2} \mathrm{~F}_{2}\) was once used as a refrigerant. Calculate what mass of this substance must evaporate to freeze \(2 \mathrm{~mol}\) water initially at \(20^{\circ} \mathrm{C}\). The vaporization enthalpy for \(\mathrm{CCl}_{2} \mathrm{~F}_{2}\) is \(289 \mathrm{~J} / \mathrm{g}\). The fusion enthalpy for solid ice is \(6.02 \mathrm{~kJ} / \mathrm{mol}\) and specific heat capacity for liquid water is \(4.184 \mathrm{~J} \mathrm{~g}^{-1}{ }^{\circ} \mathrm{C}^{-1}\).

After exercising on a hot summer day and working up a sweat, you often become cool when you stop. What is the molecular-level explanation of this phenomenon?

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