Chapter 9: Problem 6
Define sublimation.
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These are the key concepts you need to understand to accurately answer the question.
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Chapter 9: Problem 6
Define sublimation.
These are the key concepts you need to understand to accurately answer the question.
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Define the unit cell of a crystal.
Give two examples of (a) silicate ceramics, (b) oxide ceramics, and (c) nonoxide ceramics.
Potassium chloride and rubidium chloride both have the sodium chloride structure (Figure 9.24 ). X-ray diffraction experiments indicate that their cubic unit cell dimensions are \(629 \mathrm{pm}\) and \(658 \mathrm{pm}\), respectively. (i) One \(m o l \mathrm{KCl}\) and \(1 \mathrm{~mol} \mathrm{RbCl}\) are ground together to a very fine powder in a mortar and pestle, and the X-ray diffraction pattern of the pulverized solid is measured. Two patterns are observed, each corresponding to a cubic unit cell-one with an edge length of \(629 \mathrm{pm}\) and one with an edge length of \(658 \mathrm{pm}\). Call this Sample 1 . (ii) One \(\mathrm{mol} \mathrm{KCl}\) and \(1 \mathrm{~mol} \mathrm{RbCl}\) are heated until the entire mixture is molten and then cooled to room temperature. A single X-ray diffraction pattern indicates a cubic unit cell with an edge length of roughly \(640 \mathrm{pm}\). Call this Sample 2 . (a) Suppose that Samples 1 and 2 were analyzed for their chloride content. What fraction of each sample is chloride? Could the samples be distinguished by means of chemical analysis? (b) Interpret the two X-ray diffraction results in terms of the structures of the crystal lattices of Samples 1 and 2 . (c) What chemical formula should you write for Sample \(1 ?\) For Sample \(2 ?\) (d) Suppose that you dissolved \(1.00 \mathrm{~g}\) Sample 1 in \(100 \mathrm{~mL}\) water in a beaker and did the same with \(1.00 \mathrm{~g}\) Sample 2\. Which sample would conduct electricity better, or would both be the same? What ions would be present in each solution at what concentrations?
Could \(\mathrm{CaCl}_{2}\) possibly have the \(\mathrm{NaCl}\) structure? Explain your answer briefly.
What causes surface tension in liquids? Name a substance that has a very high surface tension. What kinds of intermolecular forces account for the high value?
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