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In this chapter Boyle's, Charles's, and Avogadro's laws were presented as word statements and mathematical relationships. Express each of these laws graphically.

Short Answer

Expert verified
Boyle's Law: Inverse curve; Charles's Law: Straight line; Avogadro's Law: Straight line.

Step by step solution

01

Boyle's Law

**Boyle's Law** states that at constant temperature, the pressure of a gas is inversely proportional to its volume. Mathematically, it's expressed as: \( PV = k \), where \( P \) is the pressure, \( V \) is the volume, and \( k \) is a constant. Graphically, this is represented as a hyperbola on a graph with Pressure \( P \) on the y-axis and Volume \( V \) on the x-axis.
02

Charles's Law

**Charles's Law** states that at constant pressure, the volume of a gas is directly proportional to its temperature in Kelvin. It is mathematically given by \( \frac{V}{T} = k \), where \( V \) is the volume, \( T \) is the temperature, and \( k \) is a constant. Graphically, this is represented as a straight line on a graph with Volume \( V \) on the y-axis and Temperature \( T \) on the x-axis, indicating a linear relationship.
03

Avogadro's Law

**Avogadro's Law** states that at constant temperature and pressure, the volume of a gas is directly proportional to the number of moles of gas. It's expressed as \( V = kn \), where \( V \) is the volume, \( n \) is the number of moles, and \( k \) is a constant. Graphically, it's represented as a straight line on a graph with Volume \( V \) on the y-axis and Moles \( n \) on the x-axis.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Boyle's Law
Boyle's Law forms a fundamental part of understanding gas behavior under varying pressure and volume. Imagine you have a balloon. When you squeeze the balloon, you decrease its volume, and you’ll notice that the pressure inside the balloon increases. This is a perfect demonstration of Boyle's Law at work. Simply put, if you keep the temperature the same, increasing the pressure will decrease the volume of the gas, and vice versa.
This idea can be represented mathematically by the equation \( PV = k \), where \( P \) represents pressure, \( V \) is volume, and \( k \) is a constant. In terms of graphing, this equation creates a hyperbolic curve when you plot pressure against volume. As pressure goes up, the volume reduces, showing the inverse relationship between them. This law is particularly useful in understanding the behavior of gases in closed systems, such as in the workings of a piston in an engine.
Charles's Law
Charles's Law is all about the comforting and ever-predictable relationship between volume and temperature in gases. If you've ever watched a hot air balloon rise into the sky, you've seen Charles's Law in action. When the air inside the balloon is heated, it expands, making the balloon grow larger and lighter than the cooler air outside.
The mathematical expression for Charles's Law is \( \frac{V}{T} = k \), where \( V \) is the volume, \( T \) is the temperature in Kelvins, and \( k \) is a constant. This means that as the temperature of a gas increases, so does its volume, as long as the pressure remains constant. When graphing this law, you'll see a straight line, reflecting the direct proportionality between temperature and volume. Understanding Charles's Law helps explain everyday phenomena like why car tires may seem deflated in cold weather compared to their condition on a hot day.
Avogadro's Law
Avogadro's Law highlights the simple yet fascinating relationship between the quantity of gas and its volume. Picture a bicycle pump. The more strokes you add, infusing the pump with more air molecules, the greater the pressure and therefore the volume you can pump into the bicycle tire.
According to Avogadro's Law, at a constant temperature and pressure, the volume of a gas is directly proportional to the number of gas molecules (or moles). The mathematical form of the law is \( V = kn \), where \( V \) is volume, \( n \) is the number of moles, and \( k \) is a constant. On a graph, plotting volume against the number of moles will yield a straight line, demonstrating their direct relationship. Avogadro's Law is essential for understanding chemical reactions involving gases, such as the way gases are measured and used in car airbags.

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Most popular questions from this chapter

Formaldehyde, \(\mathrm{CH}_{2} \mathrm{O},\) is a volatile organic compound that is sometimes released from insulation used in home construction, and it can be trapped and build up inside the home. When this happens, people exposed to the formaldehyde can suffer adverse health effects. The U. S. National Institute of Occupational Health and Safety (NIOSH) guideline for the maximum allowable concentration of formaldehyde in air in the workplace is \(16 \mathrm{ppb}\) (parts per billion) for an eight-hour average exposure. (a) Determine the partial pressure of formaldehyde at the maximum allowable level of \(16 \mathrm{ppb}\). (b) Calculate how many molecules of formaldehyde are present in each cubic centimeter of air when formaldehyde is present at \(16 \mathrm{ppb}\). (c) Calculate how many total molecules of formaldehyde are present in a room: \(15.0 \mathrm{ft}\) long \(\times 10.0 \mathrm{ft}\) wide \(X\) \(8.00 \mathrm{ft}\) high (at \(16 \mathrm{ppb}\) ).

When a commercial drain cleaner containing sodium hydroxide and small pieces of aluminum is poured, along with water, into a clogged drain, this reaction occurs: $$ \begin{aligned} 2 \mathrm{Al}(\mathrm{s})+2 \mathrm{NaOH}(\mathrm{aq})+6 \mathrm{H}_{2} \mathrm{O}(\ell) \longrightarrow \\ 2 \mathrm{NaAl}(\mathrm{OH})_{4}(\mathrm{aq})+3 \mathrm{H}_{2}(\mathrm{~g}) \end{aligned} $$ If \(6.5 \mathrm{~g} \mathrm{Al}\) and excess \(\mathrm{NaOH}\) are reacted, calculate the volume of \(\mathrm{H}_{2}\) gas produced at \(742 \mathrm{mmHg}\) and \(22.0^{\circ} \mathrm{C}\).

From the density of liquid water and its molar mass, calculate the volume that 1 mol liquid water occupies. If water were an ideal gas at STP, what volume would a mole of water vapor occupy? Can we achieve the STP conditions for water vapor? Why or why not?

A compound consists of \(37.5 \% \mathrm{C}, 3.15 \% \mathrm{H},\) and \(59.3 \%\) \(\mathrm{F}\) by mass. When \(0.298 \mathrm{~g}\) of the compound is heated to 50\. \({ }^{\circ} \mathrm{C}\) in an evacuated \(125-\mathrm{mL}\) flask, the pressure is observed to be \(750 . \mathrm{mmHg}\). The compound has three isomers. (a) Calculate the molar mass of the compound. (b) Determine the empirical and molecular formulas of the compound. (c) Draw the Lewis structure for each isomer of the compound.

Calculate the pressure exerted by \(1.55 \mathrm{~g}\) Xe gas at \(20 .{ }^{\circ} \mathrm{C}\) in a sealed \(560-\mathrm{mL}\) flask.

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