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Early coordination chemists relied on close experimental observation to determine the formulas of coordination compounds. They found, for example, that aqueous \(\mathrm{BaCl}_{2}\) did not cause precipitation when added to a solution of a \(\mathrm{Co}^{3+}\) -containing coordination compound, but precipitation occurred when aqueous silver nitrate was added to a solution of the coordination compound. The coordination compound was known to contain one \(\mathrm{Co}^{3+}\) ion, one sulfate ion, one chloride ion, and four ammonia molecules. Write the structural formula of the coordination compound that is consistent with the experimental results.

Short Answer

Expert verified
The structural formula is \[ [\text{Co}(\text{NH}_3)_4\text{Cl}]^{2+}\text{SO}_4^{2-}\] indicating coordination of Cl鈦 in the complex with SO鈧劼测伝 as outside ion.

Step by step solution

01

Understanding the Precipitation Observation

The key observation is that adding BaCl鈧 to the solution doesn't cause precipitation, but AgNO鈧 does. This suggests that the chloride ion is not free in solution and is actually part of the coordination sphere, while the anion causing precipitation with AgNO鈧 (likely chloride) is outside the coordination sphere.
02

Analyzing the Components

The coordination compound contains one Co鲁鈦, one sulfate ion, one chloride ion, and four ammonia molecules. Given the coordination number is typically 6 for Co鲁鈦, all available ligands (NH鈧 and possibly Cl鈦) should coordinate directly with the cobalt center.
03

Determining Ligand Coordination

The ammonia molecules are neutral ligands and are likely part of the coordination sphere with Co鲁鈦 due to their good ligand properties. The chloride ion, as suggested by step 1, must also be a part of the coordination complex. If only Cl鈦 was inside, it would not cause any precipitation reactions with AgNO鈧 as chloride is usually outside.
04

Assigning Coordination Roles

All four NH鈧 molecules coordinate to the Co鲁鈦 ion. The remaining site should be occupied by Cl鈦 or SO鈧劼测伝; however, if Cl鈦 is inside and SO鈧劼测伝 triggers the Ag鈦 precipitation this indicates SO鈧劼测伝 being outside the coordination sphere.
05

Constructing the Structural Formula

With NH鈧 and Cl鈦 as ligands, the coordination sphere involves Co鲁鈦, 4 NH鈧, and 1 Cl鈦, giving \[[\text{Co(NH}_4)_3\text{Cl}]^{2+}\text{SO}_4^{2-}\]Where [Co(NH鈧)鈧凜l]虏鈦 represents the coordination complex and SO鈧劼测伝 is the counter ion.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Coordination Sphere
In the study of coordination compounds, the concept of the coordination sphere is critical. It refers to the central atom, typically a metal, and the ligands directly attached to it. In essence, it is the 'core' of the coordination compound. Here, the ext{Co鲁鈦簘 ion serves as the central metal atom. Ligands, like ext{NH}_3 (ammonia) and ext{Cl}^-, bind directly to this central metal ion to form the coordination sphere.

In our example, since the coordination number for ext{Co鲁鈦簘 is usually six, four ext{NH}_3 molecules and one ext{Cl}^- ion are included within this sphere. This completes the coordination number of the cobalt ion, ensuring that it meets the typical geometric and electronic configuration needs. The coordination sphere is a distinct grouping within a coordination compound that can greatly influence the compound's chemical properties and reactivity.
  • The coordination sphere may affect solubility and stability of compounds.
  • Coordination number and types of ligands define the geometry of the complex.
  • Ions and molecules outside of this sphere, like ext{SO}_4^{2-} in this case, do not directly coordinate with the central metal ion.
Precipitation Reactions
Precipitation reactions play a pivotal role in identifying the structure of coordination compounds, as seen with the given exercise. They occur when two soluble solutions react to form an insoluble solid, called a precipitate. These reactions help in determining which parts of a complex ion are inside or outside the coordination sphere.

In our specific compound, the reaction did not produce a precipitate when ext{BaCl}_2 was added. This implies the ext{Cl}^- ion is not freely available in the solution, indicating its presence within the coordination sphere. Conversely, when ext{AgNO}_3 is introduced, it results in a precipitate. This suggests that the ext{SO}_4^{2-} ion is in the solution, external to the coordination sphere, allowing it to react and form a solid.
  • Precipitation reactions can help identify unbound ions in complexes.
  • This method is particularly useful for verifying the positions of ions, whether within or outside the coordination sphere.
  • Observations of these reactions can inform the structural formulation of coordination compounds.
Structural Formula
A structural formula provides a visual representation of the composition and connectivity of atoms within a compound. For coordination compounds, the structural formula delineates the coordination sphere and how ligands bind to the central metal.

In this specific scenario of the coordination compound, the structural formula displays the configuration as e [[ ext{Co(NH}_3)_4 ext{Cl}]^{2+} ext{SO}_4^{2-}], which tells us:
  • The central ext{Co鲁鈦簘 ion is directly coordinated to four ext{NH}_3 molecules and one ext{Cl}^- ligand inside the brackets, indicating their inclusion within the coordination sphere.
  • The ext{SO}_4^{2-} ion is outside the brackets, serving as a counter ion to balance the charge.
  • This configuration ensures the entire compound is electrically neutral.
This formula helps chemists understand not only the makeup of the compound but also potential reaction pathways and stability concerns.

Thus, structural formulas are fundamental in providing clear and informative insights into the nuanced nature of coordination chemistry.

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