Chapter 14: Problem 1
Define a Br酶nsted-Lowry acid and a Br酶nsted-Lowry base.
Short Answer
Expert verified
A Br酶nsted-Lowry acid donates a proton, and a Br酶nsted-Lowry base accepts a proton.
Step by step solution
01
Understanding Br酶nsted-Lowry Theory
The Br酶nsted-Lowry theory defines acids and bases based on their ability to donate or accept protons (H鈦 ions). It expands upon the earlier Arrhenius theory by focusing on the transfer of protons and not just hydrogen ions produced in water.
02
Defining a Br酶nsted-Lowry Acid
A Br酶nsted-Lowry acid is a substance that donates a proton to another substance. In any chemical reaction involving acids and bases, the Br酶nsted-Lowry acid is the species that loses an H鈦 ion. For example, in the reaction: \[ \text{HCl} + \text{H}_2\text{O} \rightarrow \text{Cl}^- + \text{H}_3\text{O}^+ \] \(\text{HCl}\) acts as the Br酶nsted-Lowry acid because it donates a proton to \(\text{H}_2\text{O}\).
03
Defining a Br酶nsted-Lowry Base
A Br酶nsted-Lowry base is a substance that accepts a proton from another substance. In a reaction, the Br酶nsted-Lowry base gains an H鈦 ion. Using the previous reaction: \[ \text{HCl} + \text{H}_2\text{O} \rightarrow \text{Cl}^- + \text{H}_3\text{O}^+ \] \(\text{H}_2\text{O}\) acts as the Br酶nsted-Lowry base because it accepts a proton from \(\text{HCl}\), resulting in the formation of \(\text{H}_3\text{O}^+\).
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Proton Donor
In the realm of chemistry, specifically when discussing acids and bases, the term "proton donor" is of great significance. The Br酶nsted-Lowry theory sheds light on this concept by defining a proton donor as a substance that is capable of losing a proton, specifically a hydrogen ion (
H鈦
). When undergoing a chemical reaction, a proton donor readily parts with its proton and thus, acts as an acid in accordance with the Br酶nsted-Lowry theory.
One classic example of a proton donor is hydrochloric acid ( HCl ). When HCl is mixed with water, it donates its proton to the water molecules. This process generates hydronium ions ( H鈧僌鈦 ) and chloride ions ( Cl鈦 ). This movement of protons from HCl to H鈧侽 exemplifies the action of a Br酶nsted-Lowry acid:
One classic example of a proton donor is hydrochloric acid ( HCl ). When HCl is mixed with water, it donates its proton to the water molecules. This process generates hydronium ions ( H鈧僌鈦 ) and chloride ions ( Cl鈦 ). This movement of protons from HCl to H鈧侽 exemplifies the action of a Br酶nsted-Lowry acid:
- Reaction: HCl + H鈧侽 鈫 Cl鈦 + H鈧僌鈦
- HCl donates the H鈦 ion (proton donor)
Proton Acceptor
Just as Br酶nsted-Lowry acids are defined as proton donors, Br酶nsted-Lowry bases gain their identity through their ability to act as "proton acceptors." A proton acceptor is a substance that can gain or accept a proton (
H鈦
) during a chemical reaction.
In the same example reaction where HCl donates a proton to water, water acts as the proton acceptor. As H鈧侽 accepts the H鈦 ion from HCl , it transforms into a hydronium ion ( H鈧僌鈦 ). This interaction shows the characteristic behavior of a Br酶nsted-Lowry base accepting a proton:
In the same example reaction where HCl donates a proton to water, water acts as the proton acceptor. As H鈧侽 accepts the H鈦 ion from HCl , it transforms into a hydronium ion ( H鈧僌鈦 ). This interaction shows the characteristic behavior of a Br酶nsted-Lowry base accepting a proton:
- Reaction: HCl + H鈧侽 鈫 Cl鈦 + H鈧僌鈦
- Water ( H鈧侽 ) accepts H鈦 ions (proton acceptor)
Acid-Base Reactions
Acid-base reactions are pivotal in both chemical processes and everyday experiences. The Br酶nsted-Lowry theory plays a key role in explaining how these reactions work. Acid-base reactions fundamentally revolve around the transfer of protons from an acid (proton donor) to a base (proton acceptor).
In our example reaction where HCl is mixed with water, an acid-base reaction occurs. Here, HCl , the acid, donates a proton to H鈧侽 , the base. This proton transfer results in the formation of chloride ions ( Cl鈦 ) and hydronium ions ( H鈧僌鈦 ):
In our example reaction where HCl is mixed with water, an acid-base reaction occurs. Here, HCl , the acid, donates a proton to H鈧侽 , the base. This proton transfer results in the formation of chloride ions ( Cl鈦 ) and hydronium ions ( H鈧僌鈦 ):
- Acid: HCl , donates H鈦
- Base: H鈧侽 , accepts H鈦
- Product: Formation of Cl鈦 and H鈧僌鈦