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Chapter 10: Problem 12

Describe the structural feature a molecule must have to undergo addition polymerization.

Short Answer

Expert verified
Molecules must have a carbon-carbon double bond for addition polymerization.

Step by step solution

01

Define Addition Polymerization

Addition polymerization is a process where unsaturated monomer molecules, typically containing double or triple bonds, link together to form a polymer. This process involves the opening of these multiple bonds and the creation of new single bonds between the monomers.
02

Identify Structural Requirements for Monomers

For a molecule to undergo addition polymerization, it must possess a carbon-carbon double bond ( =C=C ) or a capable double-triple bond ( =C'=C'' or -C鈮- ). These unsaturated bonds are necessary as their electrons can be redistributed to form new single bonds, allowing the monomers to join together in a repeating sequence.
03

Discuss the Role of the Double Bond

The carbon-carbon double bond in the monomer is crucial because it provides the reactive site for the polymerization process. When the double bond is opened during the reaction, it enables the free radicals, ions, or catalysts to add to the molecule, thereby elongating the polymer chain.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Unsaturated Monomers
Unsaturated monomers are key building blocks in the process of addition polymerization. These are molecules that contain either double or triple bonds between carbon atoms. Unsaturation means that not all the potential bonding sites of the carbon atoms are being utilized by single bonds.
This unsaturation provides...
  • Chemical reactivity: The presence of double or triple bonds makes these monomers more reactive compared to saturated molecules.
  • The potential for polymerization: The unsaturated bonds can open up to form longer chains.
This chemical behavior is extremely beneficial for creating polymers. It allows individual monomers to combine into long and strong polymer chains. This concept is crucial in understanding how materials like plastics are synthesized from simple molecules.
Carbon-Carbon Double Bond
The carbon-carbon double bond is a pivotal feature in the chemistry of addition polymerization. A carbon-carbon double bond, represented as \(C=C\), consists of one sigma bond and one pi bond. These bonds create a planar arrangement within the molecule, providing essential features for polymerization.
The double bond is reactive because...
  • The pi bond is weaker compared to other types of bonds, making it prime for breaking and bond reformation.
  • It serves as a site where polymerization initiators, like free radicals, can attack.
Here's where the magic happens: the opening of the pi bond produces free electrons. This allows the creation of new sigma bonds with adjacent monomer molecules, thus extending the polymer chain by joining more units together.
Polymer Formation
Polymer formation through addition polymerization involves a fascinating and structured series of reactions. It begins with the activation of the double bonds in unsaturated monomers. An initiator, such as a free radical or an ion, attacks this bond to form a reactive site.
Steps involved include...
  • Initiation: The reactive initiator breaks the double bonds creating reactive sites.
  • Propagation: Once started, the newly formed active sites begin to grab onto other monomers, forming new bonds.
  • Termination: Eventually, the chain stops growing when all active sites are satisfied, creating a stable polymer chain.
The entire process is seamless, converting simple monomers into complex and versatile polymers. This versatile process underlies the creation of numerous synthetic materials from rubber to plastic and beyond.

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