/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 120 When volumes of liquids are mixe... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

When volumes of liquids are mixed, the resulting volume is not always equal to the sum of the volume of each liquid. For example, when \(50.0 \mathrm{~mL}\) of ethanol \((\mathrm{d}=\) \(0.789 \mathrm{~g} / \mathrm{mL}\) ) is mixed with \(50.0 \mathrm{~mL}\) of water \((0.998 \mathrm{~g} / \mathrm{mL})\) at \(25^{\circ} \mathrm{C}\), the resulting volume is only \(95.6 \mathrm{~mL}\). Calculate the density of the solution.

Short Answer

Expert verified
The density of the solution is approximately 0.935 g/mL.

Step by step solution

01

Calculate Mass of Ethanol

Use the density formula to calculate the mass of ethanol: \[ \text{Mass} = \text{Volume} \times \text{Density} = 50.0 \ \text{mL} \times 0.789 \ \text{g/mL} = 39.45 \ \text{g} \]
02

Calculate Mass of Water

Calculate the mass of water using the density formula: \[ \text{Mass} = \text{Volume} \times \text{Density} = 50.0 \ \text{mL} \times 0.998 \ \text{g/mL} = 49.90 \ \text{g} \]
03

Calculate Total Mass of Solution

Add the mass of ethanol and the mass of water to find the total mass:\[ \text{Total Mass} = 39.45 \ \text{g} + 49.90 \ \text{g} = 89.35 \ \text{g} \]
04

Use the Resulting Volume to Find Density of Solution

Density is mass divided by volume. Calculate the density of the solution:\[ \text{Density} = \frac{\text{Total Mass}}{\text{Resulting Volume}} = \frac{89.35 \ \text{g}}{95.6 \ \text{mL}} \approx 0.935 \ \text{g/mL} \]

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Volume
Volume is the amount of space that a substance or object occupies. In everyday situations, we often measure the volume of a liquid in milliliters (mL) or liters (L). It's important to note that when mixing liquids, the total volume may not simply be the sum of the individual volumes. This phenomenon occurs due to the interactions between the molecules of the substances being mixed.

For example, when mixing ethanol and water, the volume comes out to be less than the sum of their initial volumes. In the provided exercise, the volume of the solution is only 95.6 mL, despite mixing 50.0 mL of ethanol with 50.0 mL of water. Understanding this concept is crucial, particularly when you're calculating the density of mixtures.
Mixture
A mixture is a combination of two or more substances where each retains its properties and can usually be separated by physical means. Mixtures can be categorized into homogeneous and heterogeneous mixtures. A homogeneous mixture, like the solution of ethanol in water, has a uniform composition throughout.

When preparing mixtures, each component may influence the final properties of the mixture in different ways, such as altering its density, viscosity, or boiling point. With ethanol and water, their distinct molecular structures lead to interactions that affect the final volume and density. By understanding mixtures, we can predict and calculate important characteristics like density, which is crucial for many scientific and industrial applications.
Ethanol and Water
Ethanol and water are both common liquids with distinct properties, and when mixed, they form a widely studied solution due to its interesting characteristics. Ethanol is an alcohol, known chemically as C\(\_2\)H\(\_5\)OH, and is less dense than water. Water, with its unique molecular structure, is known for its high density and ability to dissolve many substances.

When ethanol is added to water, the polar nature of both molecules leads to strong hydrogen bonding, which causes the mixture to occupy a smaller volume than expected. This interaction results in the phenomenon where the sum of their individual volumes is not equal to the final volume. In the given example, this results in a smaller than expected total volume and, consequently, affects the density calculation of the resultant solution.

Thus, understanding the interactions between ethanol and water is essential in calculating properties like density, which depend heavily on the final volume of the mixture.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

The compound sodium chloride has a solid-state structure in which there is a repeating cubic arrangement of sodium ions and chloride ions. The volume of the cube is \(1.81 \times 10^{-22} \mathrm{~cm}^{3} .\) Calculate the length of an edge of the cube in \(\mathrm{pm}\left(1 \mathrm{pm}=1 \times 10^{-12} \mathrm{~m}\right)\).

A crystal of fluorite (a mineral that contains calcium and fluorine) has a mass of \(2.83 \mathrm{~g}\). What is this mass in kilograms? Give the symbols for the elements in this crystal.

Air mostly consists of diatomic molecules of nitrogen (about \(80 \%\) ) and oxygen (about \(20 \%\) ). Draw a nanoscale picture of a sample of air that contains a total of 10 molecules.

Use the periodic table to identify these elements: (a) Name an element in Group \(2 \mathrm{~A}\). (b) Name an element in the third period. (c) What element is in the second period in Group \(4 \mathrm{~A}\) ? (d) What element is in the third period in Group \(6 \mathrm{~A}\) ? (e) What halogen is in the fifth period? (f) What alkaline-earth element is in the third period? (g) What noble gas element is in the fourth period? (h) What nonmetal is in Group \(6 \mathrm{~A}\) and the second period? (i) Name a metalloid in the fourth period.

A chemist analyzed several portions taken from different parts of a sample that contained only iron, \(\mathrm{Fe},\) and sulfur, S. She reported the results in the table. Could this sample be a compound of iron and sulfur? Explain why or why not. $$ \begin{array}{ccc} \hline \text { Portion } & \text { Total Mass }(g) & \text { Mass of Fe }(g) \\\ \hline 1 & 1.518 & 0.964 \\ 2 & 2.056 & 1.203 \\ 3 & 1.873 & 1.290 \\ \hline \end{array} $$

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.