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91Ó°ÊÓ

Identify the precipitate (if any) that forms when the following solutions are mixed, and write a balanced equation for each reaction. (a) \(\mathrm{NH}_{4} \mathrm{I}\) and \(\mathrm{CuCl}_{2},\) (b) LiOH and \(\mathrm{MnCl}_{2}\), (c) \(\mathrm{K}_{3} \mathrm{PO}_{4}\) and \(\mathrm{CoSO}_{4}\)

Short Answer

Expert verified
(a) Precipitate: CuI; Balanced equation: \[ 2 NH_4I + CuCl_2 \rightarrow 2 NH_4Cl + CuI \] (b) Precipitate: Mn(OH)2; Balanced equation: \[ 2 LiOH + MnCl_2 \rightarrow 2 LiCl + Mn(OH)_2 \] (c) Precipitate: Co3(PO4)2; Balanced equation: \[ 2 K_3PO_4 + 3 CoSO_4 \rightarrow 6 K_2SO_4 + Co_3(PO_4)_2 \]

Step by step solution

01

(a) Identify the ions in the first pair of solutions

The ions in the first solutions are NH4+ (ammonium) and I- (iodide) from NH4I, and Cu2+ (copper) and Cl- (chloride) from CuCl2.
02

(a) Predict the products of possible precipitation reactions

The possible products of the reaction are: 1. NH4Cl (formed from NH4+ and Cl- ions) 2. CuI (formed from Cu2+ and I- ions)
03

(a) Determine the solubility of the predicted products

Using solubility rules: 1. NH4Cl is soluble because it contains ammonium (NH4+). 2. CuI is moderately soluble, meaning it could still form a precipitate in some conditions. After considering solubility, CuI is the potential precipitate.
04

(a) Write a balanced chemical equation for the reaction

The balanced chemical equation for the reaction is: \[2 NH_4I + CuCl_2 \rightarrow 2 NH_4Cl + CuI\]
05

(b) Identify the ions in the second pair of solutions

The ions in the second solutions are Li+ (lithium) and OH- (hydroxide) from LiOH, and Mn2+ (manganese) and Cl- (chloride) from MnCl2.
06

(b) Predict the products of possible precipitation reactions

The possible products of the reaction are: 1. LiCl (formed from Li+ and Cl- ions) 2. Mn(OH)2 (formed from Mn2+ and OH- ions)
07

(b) Determine the solubility of the predicted products

Using solubility rules: 1. LiCl is soluble because it contains a Group 1 element (Li). 2. Mn(OH)2 is insoluble because it is a hydroxide salt. After considering solubility, Mn(OH)2 is the precipitate.
08

(b) Write a balanced chemical equation for the reaction

The balanced chemical equation for the reaction is: \[2 LiOH + MnCl_2 \rightarrow 2 LiCl + Mn(OH)_2\]
09

(c) Identify the ions in the third pair of solutions

The ions in the third solutions are K+ (potassium) and PO4^3- (phosphate) from K3PO4, and Co2+ (cobalt) and SO4^2- (sulfate) from CoSO4.
10

(c) Predict the products of possible precipitation reactions

The possible products of the reaction are: 1. K2SO4 (formed from K+ and SO4^2- ions) 2. Co3(PO4)2 (formed from Co2+ and PO4^3- ions)
11

(c) Determine the solubility of the predicted products

Using solubility rules: 1. K2SO4 is soluble because it contains a Group 1 element (K). 2. Co3(PO4)2 is insoluble because it is a phosphate salt. After considering solubility, Co3(PO4)2 is the precipitate.
12

(c) Write a balanced chemical equation for the reaction

The balanced chemical equation for the reaction is: \[2 K_3PO_4 + 3 CoSO_4 \rightarrow 6 K_2SO_4 + Co_3(PO_4)_2\]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Solubility Rules
Solubility rules are essential guidelines that help predict whether a salt will dissolve in water. They simplify the process of determining the outcome of mixing different ionic compounds.
These rules state that:
  • Compounds containing alkali metals (Group 1 elements) like lithium, sodium, or potassium, are generally soluble.
  • Ammonium compounds, such as those containing NH4+, are soluble.
  • Nitrates (NO3-) and acetates (CH3COO-) also tend to dissolve in water.
  • Most chlorides, bromides, and iodides are soluble, except when paired with silver, lead, or mercury.
  • Hydroxides are generally insoluble, except for those involving Group 1 elements and some Group 2 elements like barium or strontium.
  • Phosphates, carbonates, and sulfides usually form precipitates, except when they are paired with Group 1 elements or ammonium.
Applying these rules helps identify potential precipitates, such as the CuI precipitate from NH4I and CuCl2, Mn(OH)2 from LiOH and MnCl2, and Co3(PO4)2 from K3PO4 and CoSO4.
Balanced Chemical Equations
Balanced chemical equations are indispensable for representing chemical reactions accurately. They ensure that the number of atoms of each element is consistent on both the reactant and product sides. This is due to the law of conservation of mass, which states that matter cannot be created or destroyed in a chemical reaction.
Creating a balanced equation involves:
  • Identifying the reactants and products involved in the reaction.
  • Counting the number of each type of atom in the reactants and products.
  • Using coefficients to balance the number of atoms on both sides of the equation.
For example, when mixing NH4I and CuCl2, the balanced equation is \(2 \text{NH}_4\text{I} + \text{CuCl}_2 \rightarrow 2 \text{NH}_4\text{Cl} + \text{CuI}\). Similarly, mixing LiOH and MnCl2 results in \(2 \text{LiOH} + \text{MnCl}_2 \rightarrow 2 \text{LiCl} + \text{Mn(OH)}_2\). This process maintains balance and clarity in representing chemical transformations.
Ionic Compounds
Ionic compounds are a class of chemicals formed by the electrostatic attraction between oppositely charged ions. Typically, they are composed of metal cations and non-metal anions. The nature of this bond provides ionic compounds with unique properties.
The key characteristics of ionic compounds include:
  • Formation of crystal lattice structures due to the regular repeating pattern of ions.
  • High melting and boiling points due to strong ionic bonds.
  • Solubility in polar solvents like water, where they often dissociate into their respective ions.
  • Electrical conductivity in the melted state or when dissolved in a solvent, as free ions are present to carry electric current.
When NH4I mixes with CuCl2, each breaks into ionic components: NH4+, I-, Cu2+, and Cl-. These ions can recombine to form different ionic compounds, which may precipitate if insoluble. Thus, ionic compounds are fundamental to understanding how precipitation reactions work and the resulting substances they can form.

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Most popular questions from this chapter

The following reactions (note that the arrows are pointing only one direction) can be used to prepare an activity series for the halogens: $$ \begin{array}{c} \mathrm{Br}_{2}(a q)+2 \mathrm{NaI}(a q) \longrightarrow 2 \mathrm{NaBr}(a q)+\mathrm{I}_{2}(a q) \\ \mathrm{Cl}_{2}(a q)+2 \mathrm{NaBr}(a q) \longrightarrow 2 \mathrm{NaCl}(a q)+\mathrm{Br}_{2}(a q) \end{array} $$ (a) Which elemental halogen would you predict is the most stable, upon mixing with other halides? (b) Predict whether a reaction will occur when elemental chlorine and potassium iodide are mixed. (c) Predict whether a reaction will occur when elemental bromine and lithium chloride are mixed.

Complete and balance the following molecular equations, and then write the net ionic equation for each: (a) \(\mathrm{HBr}(a q)+\mathrm{Ca}(\mathrm{OH})_{2}(a q) \longrightarrow\) (b) \(\mathrm{Cu}(\mathrm{OH})_{2}(s)+\mathrm{HClO}_{4}(a q) \longrightarrow\) (c) \(\mathrm{Al}(\mathrm{OH})_{3}(s)+\mathrm{HNO}_{3}(a q) \longrightarrow\)

Using the activity series (Table 4.5 ), write balanced chemical equations for the following reactions. If no reaction occurs, write NR. (a) Iron metal is added to a solution of copper(II) nitrate, (b) zinc metal is added to a solution of magnesium sulfate, (c) hydrobromic acid is added to tin metal, (d) hydrogen gas is bubbled through an aqueous solution of nickel(II) chloride, (e) aluminum metal is added to a solution of cobalt(II) sulfate.

(a) Is the number of moles of ions present in a solution an intensive or an extensive property? (b) Can you identify which one between \(0.10 \mathrm{~mol} \mathrm{ZnCl}_{2}\) and \(0.1 \mathrm{M} \mathrm{ZnCl}_{2}\) contains more \(\mathrm{Zn}^{2+}\) ion? Why?

You are presented with a white solid and told that due to careless labeling it is not clear if the substance is barium chloride, lead chloride, or zinc chloride. When you transfer the solid to a beaker and add water, the solid dissolves to give a clear solution. Next an \(\mathrm{Na}_{2} \mathrm{SO}_{4}(a q)\) solution is added and a white precipitate forms. What is the identity of the unknown white solid? [Section 4.2\(]\)

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