Chapter 18: Problem 53
(a) What are trihalomethanes (THMs)? (b) Draw the Lewis structures of two example THMs.
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Chapter 18: Problem 53
(a) What are trihalomethanes (THMs)? (b) Draw the Lewis structures of two example THMs.
These are the key concepts you need to understand to accurately answer the question.
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In the lime soda process once used in large scale municipal water softening, calcium hydroxide prepared from lime and sodium carbonate are added to precipitate \(\mathrm{Ca}^{2+}\) as \(\mathrm{CaCO}_{3}(s)\) and \(\mathrm{Mg}^{2+}\) as \(\mathrm{Mg}(\mathrm{OH})_{2}(s);\) $$ \begin{aligned} \mathrm{Ca}^{2+}(a q)+\mathrm{CO}_{3}^{2-}(a q) & \longrightarrow \mathrm{CaCO}_{3}(s) \\ \mathrm{Mg}^{2+}(a q)+2 \mathrm{OH}^{-}(a q) & \longrightarrow \mathrm{Mg}(\mathrm{OH})_{2}(s) \end{aligned} $$ How many moles of \(\mathrm{Ca}(\mathrm{OH})_{2}\) and \(\mathrm{Na}_{2} \mathrm{CO}_{3}\) should be added to soften (remove the \(\mathrm{Ca}^{2+}\) and \(\mathrm{Mg}^{2+}\) ) 1000 L of water in which $$ \begin{array}{l} {\left[\mathrm{Ca}^{2+}\right]=3.5 \times 10^{-4} \mathrm{M}} \\ {\left[\mathrm{Mg}^{2+}\right]=7.5 \times 10^{-4} \mathrm{M}} \end{array} $$
The standard enthalpies of formation of \(\mathrm{ClO}\) and \(\mathrm{ClO}_{2}\) are 101 and \(102 \mathrm{~kJ} / \mathrm{mol}\), respectively. Using these data and the thermodynamic data in Appendix C, calculate the overall enthalpy change for each step in the following catalytic cycle: $$ \begin{array}{l} \mathrm{ClO}(g)+\mathrm{O}_{3}(g) \longrightarrow \mathrm{ClO}_{2}(g)+\mathrm{O}_{2}(g) \\ \mathrm{ClO}_{2}(g)+\mathrm{O}(g) \longrightarrow \mathrm{ClO}(g)+\mathrm{O}_{2}(g) \end{array} $$ What is the enthalpy change for the overall reaction that results from these two steps?
The ultraviolet spectrum can be divided into three regions based on wavelength: UV-A (315-400 nm), UV-B (280-315 \(\mathrm{nm})\), and UV-C \((100-280 \mathrm{nm})\). (a) Photons from which region have the highest energy and therefore are the most harmful to living tissue? (b) In the absence of ozone, which of these three regions, if any, are absorbed by the atmosphere? (c) When appropriate concentrations of ozone are present in the stratosphere, is all of the UV light absorbed before reaching the Earth's surface? If not, which region or regions are not filtered out?
The main reason that distillation is a costly method for purifying water is the high energy required to heat and vaporize water. (a) Using the density, specific heat, and heat of vaporization of water from Appendix B, calculate the amount of energy required to vaporize \(1.00 \mathrm{~L}\) of water beginning with water at \(25^{\circ} \mathrm{C}\). (b) If the energy is provided by electricity costing \(\$ 0.085 / \mathrm{kWh},\) calculate its cost. \((\mathbf{c})\) If distilled water sells in a grocery store for \(\$ 0.49\) per \(L,\) what percentage of the sales price is represented by the cost of the energy?
Discuss how catalysts can make processes more energy efficient.
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