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Predict the chemical formula of the ionic compound formed between the following pairs of elements: (a) Al and Cl, (d) Li and \(O\). (b) \(\mathrm{Mg}\) and \(\mathrm{O},(\mathbf{c}) \mathrm{Zn}\) and \(\mathrm{Cl},\)

Short Answer

Expert verified
(a) AlCl鈧, (b) MgO, (c) ZnCl鈧, (d) Li鈧侽.

Step by step solution

01

Understand Ionic Compounds

Ionic compounds are formed between metals and nonmetals. The metal donates electrons to become a positively charged cation, while the non-metal accepts electrons to become a negatively charged anion.
02

Determine Charges

Identify the valency of the elements: - Al forms a 3+ cation, Cl forms a 1- anion. - Mg forms a 2+ cation, O forms a 2- anion. - Zn forms a 2+ cation, Cl forms a 1- anion. - Li forms a 1+ cation, O forms a 2- anion.
03

Write Formulas Using Charge Balance

Create a neutral compound by balancing the total positive and negative charges: - For Al and Cl: Al forms AlCl鈧 (3 chloride ions are needed to balance 1 aluminum ion). - For Mg and O: Mg forms MgO (one magnesium ion balances with one oxide ion). - For Zn and Cl: Zn forms ZnCl鈧 (two chloride ions are needed to balance one zinc ion). - For Li and O: Li forms Li鈧侽 (two lithium ions are needed to balance one oxide ion).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Predicting Chemical Formulas
Predicting the chemical formula of an ionic compound is an essential skill in chemistry. It involves understanding the interaction between metal and nonmetal elements, where the metal loses electrons, forming a cation, while the nonmetal gains electrons, forming an anion.
To predict a chemical formula, it's crucial to know the charges of these ions, which allows us to balance them in a compound. For example, aluminum (Al), a metal, forms a cation with a charge of +3, and chlorine (Cl), a nonmetal, forms an anion with a charge of -1. To balance these, the formula becomes AlCl鈧, meaning one aluminum ion combines with three chloride ions.
  • Always identify the charge of each ion first.
  • Use the charges to determine the ratio needed to achieve charge neutrality.
Hence, predicting chemical formulas includes examining these charges carefully.
Cation and Anion Charges
In ionic compounds, understanding the charges of cations and anions is fundamental. A cation is a positively charged ion, and an anion is a negatively charged ion. Metals typically form cations, and nonmetals form anions.
For example:
  • Aluminum (Al) forms a cation with a charge of +3.
  • Chlorine (Cl), a nonmetal, forms an anion with a charge of -1.
  • Magnesium (Mg) has a valency of +2, while oxygen (O) forms a -2 anion.
Recognizing these charges helps in forming correct ionic compounds, like balancing Al with Cl to form AlCl鈧. The charges dictate how many of each ion are needed to achieve a neutral compound. Remember, the total charge from cations must equal the total charge from anions for the compound to be stable.
Metal and Nonmetal Reactions
The reaction between metals and nonmetals is the basis for forming ionic compounds. Metals, which are on the left side of the periodic table, tend to lose electrons and form cations.
Nonmetals, found on the right side of the table, gain these electrons to become anions. For instance, lithium (Li) loses an electron to form Li鈦, while oxygen (O) gains two electrons to form O虏鈦. This electron exchange is what creates the ionic bond, resulting in compounds like Li鈧侽.
Some key points include:
  • Metals are electron donors (e.g., Li = Li鈦).
  • Nonmetals are electron acceptors (e.g., O = O虏鈦).
  • The exchange of electrons forms a stable ionic bonding.
This predictable exchange pattern makes it easier to determine the products of metal and nonmetal reactions.
Charge Balancing in Compounds
In ionic compounds, charge balancing is vital to ensure neutrality. The positive and negative charges must cancel each other out.
For example, in aluminum chloride (AlCl鈧), one Al鲁鈦 cation balances with three Cl鈦 anions. The overall charge of the compound must equal zero.
Consider these steps when balancing charges:
  • Calculate total positive charge (e.g., from metal cations).
  • Calculate total negative charge (e.g., from nonmetal anions).
  • Adjust the ratio of ions to equalize positive and negative charges.
In zinc chloride (ZnCl鈧), Zn虏鈦 pairs with two Cl鈦 ions to form a neutral compound. This precise balancing ensures electrical neutrality, which is crucial for the formation of stable compounds.

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Most popular questions from this chapter

Which of the following trends in lattice energy is due to differences in ionic radii? (a) \(\mathrm{LiF}>\mathrm{NaF}>\mathrm{CsF},(\mathbf{b}) \mathrm{CaO}>\mathrm{KCl}\), (c) \(\mathrm{PbS}>\mathrm{Li}_{2} \mathrm{O}\).

Using Lewis symbols and Lewis structures, diagram the formation of \(\mathrm{BF}_{3}\) from \(\mathrm{B}\) and \(\mathrm{F}\) atoms, showing valence- shell electrons. (a) How many valence electrons does B have initially? (b) How many bonds F has to make in order to achieve an octet? (c) How many valence electrons surround the B in the \(\mathrm{BF}_{3}\) molecule? (d) How many valence electrons surround each F in the \(\mathrm{BF}_{3}\) molecule? (e) Does \(\mathrm{BF}_{3}\) obey the octet rule?

The substance chlorine monoxide, \(\mathrm{ClO}(g)\), is important in atmospheric processes that lead to depletion of the ozone layer. The ClO molecule has an experimental dipole moment of \(1.24 \mathrm{D},\) and the \(\mathrm{Cl}-\mathrm{O}\) bond length is \(160 \mathrm{pm} .(\mathbf{a})\) Determine the magnitude of the charges on the \(\mathrm{Cl}\) and \(\mathrm{O}\) atoms in units of the electronic charge, \(e .(\mathbf{b})\) Based on the electronegativities of the elements, which atom would you expect to have a partial negative charge in the ClO molecule? (c) Using formal charges as a guide, propose the dominant Lewis structure for the molecule. (d) The anion \(\mathrm{ClO}^{-}\) exists. What is the formal charge on the Cl for the best Lewis structure for \(\mathrm{ClO}^{-}\) ?

Under special conditions, sulfur reacts with anhydrous liquid ammonia to form a binary compound of sulfur and nitrogen. The compound is found to consist of \(69.6 \% \mathrm{~S}\) and \(30.4 \% \mathrm{~N}\). Measurements of its molecular mass yield a value of \(184.3 \mathrm{~g} / \mathrm{mol}\). The compound occasionally detonates on being struck or when heated rapidly. The sulfur and nitrogen atoms of the molecule are joined in a ring. All the bonds in the ring are of the same length. (a) Calculate the empirical and molecular formulas for the substance. (b) Write Lewis structures for the molecule, based on the information you are given. (Hint: You should find a relatively small number of dominant Lewis structures.) (c) Predict the bond distances between the atoms in the ring. (Note: The \(S-S\) distance in the \(S_{8}\) ring is 205 pm.) \((\mathbf{d})\) The enthalpy of formation of the compound is estimated to be \(480 \mathrm{~kJ} / \mathrm{mol}^{-1} . \Delta H_{f}^{\circ}\) of \(\mathrm{S}(g)\) is \(222.8 \mathrm{~kJ} / \mathrm{mol}\). Estimate the average bond enthalpy in the compound.

Incomplete Lewis structures for the nitrous acid molecule, \(\mathrm{HNO}_{2}\), and the nitrite ion, \(\mathrm{NO}_{2}^{-}\), are shown here. (a) Complete each Lewis structure by adding electron pairs as needed. (b) Is the formal charge on \(\mathrm{N}\) the same or different in these two species? (c) Would either \(\mathrm{HNO}_{2}\) or \(\mathrm{NO}_{2}^{-}\) be expected to exhibit resonance? (d) Would you expect the \(\mathrm{N}=\mathrm{O}\) bond in \(\mathrm{HNO}_{2}\) to be longer, shorter, or the same length as the \(\mathrm{N}-\mathrm{O}\) bonds in \(\mathrm{NO}_{2}^{-}\) ? [Sections 8.5 and 8.6 ] $$ \mathrm{H}-\mathrm{O}-\mathrm{N}=\mathrm{O} \quad \mathrm{O}-\mathrm{N}=\mathrm{O} $$

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