Chapter 3: Problem 62
The reaction between potassium superoxide, \(\mathrm{KO}_{2}\), and \(\mathrm{CO}_{2}\), $$ 4 \mathrm{KO}_{2}+2 \mathrm{CO}_{2} \longrightarrow 2 \mathrm{~K}_{2} \mathrm{CO}_{3}+3 \mathrm{O}_{2} $$ is used as a source of \(\mathrm{O}_{2}\) and absorber of \(\mathrm{CO}_{2}\) in selfcontained breathing equipment used by rescue workers. (a) How many moles of \(\mathrm{O}_{2}\) are produced when \(0.400 \mathrm{~mol}\) of \(\mathrm{KO}_{2}\) reacts in this fashion? (b) How many grams of \(\mathrm{KO}_{2}\) are needed to form \(7.50 \mathrm{~g}\) of \(\mathrm{O}_{2}\) ?
Short Answer
Step by step solution
Understand the Reaction
Calculate Moles of \(\mathrm{O}_{2}\) from \(0.400 \mathrm{~mol}\) \(\mathrm{KO}_{2}\)
Calculate Molar Mass of \(\mathrm{O}_{2}\)
Calculate Moles of \(\mathrm{O}_{2}\) for 7.50 g
Calculate \(\mathrm{KO}_{2}\) Required for 7.50 g of \(\mathrm{O}_{2}\)
Calculate Molar Mass of \(\mathrm{KO}_{2}\)
Calculate Grams of \(\mathrm{KO}_{2}\) Needed
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chemical Reactions
For instance, in the reaction involving potassium superoxide (\(\mathrm{KO}_{2}\)) and carbon dioxide (\(\mathrm{CO}_{2}\)), the balanced equation is:\[4 \mathrm{KO}_{2} + 2 \mathrm{CO}_{2} \rightarrow 2 \mathrm{K}_{2} \mathrm{CO}_{3} + 3 \mathrm{O}_{2}\]This equation communicates several crucial pieces of information:
- It tells us the specific number of molecules or moles of each reactant and product involved in the reaction.
- It is also balanced, meaning atoms on both sides of the equation are equal, adhering to the law of conservation of mass.
- For every 4 moles of \(\mathrm{KO}_{2}\), 2 moles of \(\mathrm{CO}_{2}\) react to produce 2 moles of \(\mathrm{K}_{2}\mathrm{CO}_{3}\) and 3 moles of \(\mathrm{O}_{2}\).
Mole Calculations
Applying this concept to our exercise, we focus on using moles to quantify the amount of substance produced or reacted. Let's say you have \(0.400\) moles of \(\mathrm{KO}_{2}\):
- From the balanced equation, we know 4 moles of \(\mathrm{KO}_{2}\) can produce 3 moles of \(\mathrm{O}_{2}\).
- To find out how many moles of \(\mathrm{O}_{2}\) are produced, we use the ratio \(\frac{3 \text{ moles } \mathrm{O}_{2}}{4 \text{ moles } \mathrm{KO}_{2}} \).
- By multiplying this ratio by \(0.400 \) moles \(\mathrm{KO}_{2}\), we compute that \(0.300\) moles of \(\mathrm{O}_{2}\) are produced.
Oxygen Production
The chemical reaction between \(\mathrm{KO}_{2}\) and \(\mathrm{CO}_{2}\) not only cleanses the air of carbon dioxide but also ensures a supply of oxygen. To understand how much \(\mathrm{KO}_{2}\) is needed to produce a certain mass of \(\mathrm{O}_{2}\), let's consider a situation where you need \(7.50 \text{ g}\) of \(\mathrm{O}_{2}\):
- First, calculate how many moles are in \(7.50 \text{ g}\) of \(\mathrm{O}_{2}\): Using its molar mass \(32.00\, \text{g/mol}\), \(\frac{7.50 \text{ g}}{32.00 \text{ g/mol}} = 0.234375 \text{ moles of } \mathrm{O}_{2}\).
- Using the stoichiometric ratio, determine the moles of \(\mathrm{KO}_{2}\) needed: \(\frac{4 \text { moles } \mathrm{KO}_{2}}{3 \text{ moles } \mathrm{O}_{2}} \times 0.234375 \text{ moles } \mathrm{O}_{2} = 0.3125 \text{ moles of } \mathrm{KO}_{2}\).
- Finally, from the molar mass of \(\mathrm{KO}_{2}\) \((71.10 \text{ g/mol})\), calculate the needed mass: \(0.3125 \text{ moles} \times 71.10 \text{ g/mol} = 22.21 \text{ g of } \mathrm{KO}_{2}\).