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The compound \(\mathrm{XCl}_{4}\) contains \(75.0 \% \mathrm{Cl}\) by mass. What is the element X?

Short Answer

Expert verified
The element X is titanium (Ti).

Step by step solution

01

Define Variables

Let the atomic mass of chlorine (Cl) be denoted as \(M_{Cl} = 35.5\, \text{g/mol}\). Suppose the atomic mass of element X is \(M_X\, \text{g/mol}\). The molar mass of the compound \(\text{XCl}_4\) is \(M_X + 4 \times M_{Cl}\).
02

Express Mass Percentage of Chlorine

Use the given mass percentage of chlorine in the compound, which is 75%. Therefore, the mass of chlorine in \(\text{XCl}_4\) is \((4 \times M_{Cl})\) grams and the expression for the mass percentage is: \[ \frac{4 \times M_{Cl}}{M_X + 4 \times M_{Cl}} = 0.75 \]
03

Substitute Known Values

Substitute \(M_{Cl} = 35.5\) into the mass percentage equation: \[ \frac{4 \times 35.5}{M_X + 4 \times 35.5} = 0.75 \]
04

Solve for X's Atomic Mass

Simplify the equation to solve for \(M_X\): \[ 4 \times 35.5 = 0.75(M_X + 4 \times 35.5) \]\[ 142 = 0.75(M_X + 142) \]Eliminate decimals by isolating \(M_X\):\[ 142 = 0.75M_X + 106.5 \]Subtract 106.5 from both sides:\[ 35.5 = 0.75M_X \]Divide by 0.75 to find \(M_X\):\[ M_X = \frac{35.5}{0.75} = 47.33 \]
05

Determine Element X

Round 47.33 to the nearest whole number, which gives 47. Refer to the periodic table to identify the element with an atomic mass of approximately 47. This element is titanium (Ti).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Atomic Mass
Atomic mass is a fundamental concept in chemistry that refers to the mass of an individual atom of an element. It's often expressed in atomic mass units (amu) or grams per mole (g/mol). The atomic mass is essentially the sum of the masses of the protons and neutrons in the nucleus.
Each element on the periodic table has a characteristic atomic mass. For example:
  • Hydrogen's atomic mass is approximately 1 amu.
  • Chlorine's atomic mass is approximately 35.5 amu.
The atomic mass helps chemists determine the mass of a certain number of atoms, or the molar mass of compounds. It's crucial for calculating and comparing the proportions of elements within compounds, as we explored in the problem above.
Mass Percentage
Mass percentage is a way to express the concentration of a component in a mixture or a compound. It tells us what fraction of the total mass is attributable to a specific element. Here is how mass percentage is calculated:
  • Mass percentage is defined as: \( \text{Mass Percentage} = \frac{\text{Mass of Element in Compound}}{\text{Total Mass of Compound}} \times 100 \% \)
Mass percentage is an important metric when analyzing chemical compositions. In our example, chlorine constitutes 75% of the mass in \( \text{XCl}_4 \). This helps us determine the mass of other elements in the compound, like element X.
Once you determine the mass percentages, you can also backtrack to find out the empirical formula of the compound. This is essential in chemistry to reveal the makeup of unknown substances.
Molar Mass
Molar mass is the weight of one mole (approximately 6.022 x \(10^{23}\) particles) of a given substance. It's expressed in grams per mole (g/mol). Molar mass is incredibly useful for converting between the mass of a substance and the number of moles, which is crucial for stoichiometric calculations in chemical reactions.
For elements, the molar mass is numerically equal to the atomic mass shown on the periodic table. For compounds, it's the sum of the atomic masses of all the atoms in the molecule.
Using our compound \( \text{XCl}_4 \) as an example:
  • The molar mass can be calculated by adding together the molar mass of 'X' and four times the molar mass of Cl.
  • This aids in determining composition and reacting masses.
Understanding molar mass allows you to predict how substances will react and how much of each reactant will be required or produced in reactions.
Periodic Table
The periodic table is a comprehensive chart that organizes all known chemical elements. It's laid out in order of increasing atomic number, which represents the number of protons in the nucleus of each element's atom. This logical framework is vital in predicting elemental properties.
The periodic table's structure allows chemists to infer relationships between elements:
  • Elements in the same column (group) generally exhibit similar chemical behaviors.
  • Atomic mass increases across periods from left to right.
  • The later sections of each row contain metals, while non-metals populate the table's central areas.
For tasks like the one in our example, the periodic table was used to identify the unknown element X based on its atomic mass. Finding the atomic mass closest to an element on the table helped us identify it as titanium (Ti). The periodic table remains an indispensable tool in solving chemistry problems, understanding elemental properties, and organizing chemical information efficiently.

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Most popular questions from this chapter

\(\mathrm{NO}_{x}\) is a generic term for the nitrogen oxides, \(\mathrm{NO}\) and \(\mathrm{NO}_{2}\). \(\mathrm{NO}_{x}\) gases are air pollutants that react to form smog and acid rain. In order to reduce \(\mathrm{NO}_{x}\) emission from vehicle, catalytic converters are installed in car exhausts to decompose NO and \(\mathrm{NO}_{2}\) respectively into \(\mathrm{N}_{2}\) and \(\mathrm{O}_{2}(\mathbf{a})\) Write the balanced chemical equations for the decomposition of \(\mathrm{NO}\) and \(\mathrm{NO}_{2}\) respectively. (b) If the car produces \(100 \mathrm{~g} \mathrm{NO}_{x}\) a day, with equal mole ratio of \(\mathrm{NO}\) and \(\mathrm{NO}_{2}\), how many grams of NO and \(\mathrm{NO}_{2}\) are produced respectively?

The thermite reaction, $$ \mathrm{Fe}_{2} \mathrm{O}_{3}+\mathrm{Al} \rightarrow \mathrm{Al}_{2} \mathrm{O}_{3}+\mathrm{Fe} $$ produces so much heat that the Fe product melts. This reaction is used industrially to weld metal parts under water, where a torch cannot be employed. It is also a favorite chemical demonstration in the lecture hall (on a small scale). (a) Balance the chemical equation for the thermite reaction, and include the proper states of matter. (b) Calculate how many grams of aluminum are needed to completely react with \(500.0 \mathrm{~g}\) of \(\mathrm{Fe}_{2} \mathrm{O}_{3}\) in this reaction. (c) This reaction produces \(852 \mathrm{~kJ}\) of heat per mole of \(\mathrm{Fe}_{2} \mathrm{O}_{3}\) reacted. How many grams of \(\mathrm{Fe}_{2} \mathrm{O}_{3}\) are needed to produce \(1.00 \times 10^{4} \mathrm{~kJ}\) of heat? (d) If you performed the reverse reaction- aluminum oxide plus iron makes iron oxide plus aluminum-would that reaction have heat as a reactant or a product?

When benzene \(\left(\mathrm{C}_{6} \mathrm{H}_{6}\right)\) reacts with bromine \(\left(\mathrm{Br}_{2}\right)\), bromobenzene \(\left(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{Br}\right)\) is obtained: $$ \mathrm{C}_{6} \mathrm{H}_{6}+\mathrm{Br}_{2} \longrightarrow \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{Br}+\mathrm{HBr} $$ (a) When \(30.0 \mathrm{~g}\) of benzene reacts with \(65.0 \mathrm{~g}\) of bromine, what is the theoretical yield of bromobenzene? (b) If the actual yield of bromobenzene is \(42.3 \mathrm{~g},\) what is the percentage yield?

The molecular formula of saccharin, an artificial sweetener, is \(\mathrm{C}_{7} \mathrm{H}_{5} \mathrm{NO}_{3} \mathrm{~S} .(\mathbf{a})\) What is the molar mass of saccharin? (b) How many moles of sachharin are in \(2.00 \mathrm{mg}\) of this substance?(c) How many molecules are in \(2.00 \mathrm{mg}\) of this substance? (d) How many C atoms are present in \(2.00 \mathrm{mg}\) of saccharin?

What is the molecular formula of each of the following compounds? (a) empirical formula \(\mathrm{CH}_{3} \mathrm{O},\) molar mass \(=62.0 \mathrm{~g} / \mathrm{mol}\) (b) empirical formula \(\mathrm{NH}_{2}\), molar mass \(=32.0 \mathrm{~g} / \mathrm{mol}\)

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