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Consider a sample of calcium carbonate in the form of a cube measuring 2.005 in. on each edge. If the sample has a density of \(2.71 \mathrm{~g} / \mathrm{cm}^{3},\) how many oxygen atoms does it contain?

Short Answer

Expert verified
The cube contains approximately \(6.458 \times 10^{24}\) oxygen atoms.

Step by step solution

01

Calculate the Volume of the Cube

To find the volume of the cube, use the formula for the volume of a cube, which is given by side\(^3\). The side length is given as 2.005 inches. First, convert inches to centimeters, knowing that 1 inch = 2.54 cm: \[\text{Side length in cm} = 2.005 \, \text{in} \times 2.54 \, \frac{\text{cm}}{\text{in}} = 5.0937 \, \text{cm}.\]Now calculate the volume: \[V = (5.0937 \, \text{cm})^3 = 132.056 \, \text{cm}^3.\]
02

Calculate the Mass of the Cube

The volume of the cube is 132.056 cm\(^3\). Using the given density \( \rho = 2.71 \, \text{g/cm}^3 \), apply the density formula \( \text{Density} = \frac{\text{Mass}}{\text{Volume}} \) to find the mass:\[\text{Mass} = \text{Density} \times \text{Volume} = 2.71 \, \text{g/cm}^3 \times 132.056 \, \text{cm}^3 = 357.874 \, \text{g}.\]
03

Calculate Moles of Calcium Carbonate

Calcium carbonate (CaCO\(_3\)) has a molar mass of roughly 100.09 g/mol. Use this to find the number of moles of CaCO\(_3\):\[\text{Moles of CaCO}_3 = \frac{357.874 \, \text{g}}{100.09 \, \text{g/mol}} = 3.577 \, \text{mol}.\]
04

Find Moles of Oxygen Atoms

Each CaCO\(_3\) molecule contains 3 oxygen atoms. Therefore, the number of moles of oxygen atoms is 3 times the moles of calcium carbonate:\[\text{Moles of O atoms} = 3 \times 3.577 \, \text{mol} = 10.731 \, \text{mol}.\]
05

Calculate the Number of Oxygen Atoms

Use Avogadro's number, \(6.022 \times 10^{23}\), to find the number of oxygen atoms:\[\text{Number of O atoms} = 10.731 \, \text{mol} \times 6.022 \times 10^{23} \text{ atoms/mol} = 6.458 \times 10^{24} \text{ atoms}.\]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molar Mass
Molar mass is a crucial concept in chemistry. It refers to the mass of one mole of a substance, measured in grams per mole (g/mol). For any chemical compound, like calcium carbonate (CaCO\(_3\)), calculating its molar mass involves adding up the molar masses of its constituent elements.
  • Calcium (Ca) has a molar mass of roughly 40.08 g/mol.
  • Carbon (C) has a molar mass of approximately 12.01 g/mol.
  • Oxygen (O) has a molar mass of about 16.00 g/mol.
To find the total molar mass of calcium carbonate, you add together the molar masses of all the atoms in its formula:
\[ ext{Molar mass of CaCO}_3 = 40.08 ext{ g/mol (Ca)} + 12.01 ext{ g/mol (C)} + 3 \times 16.00 ext{ g/mol (O)} = 100.09 ext{ g/mol}.\]Understanding molar mass helps in converting between grams of a substance and moles, which is essential when working with chemical reactions and formulations.
Density Calculation
Density is a measure that relates the mass of an object to its volume. It is calculated by the formula:
\[ ext{Density} = \frac{\text{Mass}}{\text{Volume}}\]The unit for density is often grams per cubic centimeter (g/cm³) in chemistry. In the exercise, the density of calcium carbonate is given as 2.71 g/cm³. To use this information, you must know the volume of the object, which is calculated based on its physical dimensions. For a cube, the volume is determined by the formula:
\[ ext{Volume} = ext{Side length}^3\]Once the volume of the cube is known, multiplying the volume by the density will give you the mass:
  • Volume: Convert side length from inches to centimeters (using 1 inch = 2.54 cm), then cube it.
  • Mass: Multiply the volume in cm³ by the density (2.71 g/cm³).
This process allows you to find how much the substance weighs, which is essential for many calculations in chemistry.
Avogadro's Number
Avogadro's number is one of the fundamental concepts in chemistry. It is the number of atoms, ions, or molecules in one mole of a substance, approximately equal to \(6.022 \times 10^{23}\). This immense number helps scientists and students count particles in measurable quantities.
When dealing with molecules like calcium carbonate (CaCO\(_3\)), knowing the number of molecules or atoms involved is crucial for stoichiometry and reaction yield calculations.
  • The exercise involved determining the number of oxygen atoms, which required knowing the moles of CaCO\(_3\).
  • By multiplying the moles of oxygen atoms by Avogadro's number, you can find how many oxygen atoms are present.
This concept allows chemists to scale atomic reactions from the microscopic level to quantities we can manage in a lab setting, ensuring that we can predict and measure the results of chemical reactions accurately.

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Most popular questions from this chapter

Viridicatumtoxin B, \(\mathrm{C}_{30} \mathrm{H}_{31} \mathrm{NO}_{10}\), is a natural antibiotic compound. It requires a synthesis of 12 steps in the laboratory. Assuming all steps have equivalent yields of \(85 \%,\) which is the final percent yield of the total synthesis?

Balance the following equations: (a) \(\mathrm{SiCl}_{4}(l)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{Si}(\mathrm{OH})_{4}(s)+\mathrm{HCl}(a q)\) (b) \(\mathrm{CO}_{2}(g)+\mathrm{H}_{2} \mathrm{O} \longrightarrow \mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}(s)+\mathrm{O}_{2}(g)\) (c) \(\mathrm{Al}(\mathrm{OH})_{3}(s)+\mathrm{H}_{2} \mathrm{SO}_{4}(l) \longrightarrow \mathrm{Al}_{2}\left(\mathrm{SO}_{4}\right)_{3}(s)+\mathrm{H}_{2} \mathrm{O}(l)\) (d) \(\mathrm{H}_{3} \mathrm{PO}_{4}(a q) \longrightarrow \mathrm{H}_{4} \mathrm{P}_{2} \mathrm{O}_{7}(a q)+\mathrm{H}_{2} \mathrm{O}(l)\)

The source of oxygen that drives the internal combustion engine in an automobile is air. Air is a mixture of gases, principally \(\mathrm{N}_{2}(\sim 79 \%)\) and \(\mathrm{O}_{2}(\sim 20 \%) .\) In the cylinder of an automobile engine, nitrogen can react with oxygen to produce nitric oxide gas, NO. As NO is emitted from the tailpipe of the car, it can react with more oxygen to produce nitrogen dioxide gas. (a) Write balanced chemical equations for both reactions. (b) Both nitric oxide and nitrogen dioxide are pollutants that can lead to acid rain and global warming; collectively, they are called \({ }^{\prime \prime} \mathrm{NO}_{x}{ }^{\prime \prime}\) gases. In \(2009,\) the United States emitted an estimated 19 million tons of nitrogen dioxide into the atmosphere. How many grams of nitrogen dioxide is this? (c) The production of \(\mathrm{NO}_{x}\) gases is an unwanted side reaction of the main engine combustion process that turns octane, \(\mathrm{C}_{8} \mathrm{H}_{18},\) into \(\mathrm{CO}_{2}\) and water. If \(85 \%\) of the oxygen in an engine is used to combust octane and the remainder used to produce nitrogen dioxide, calculate how many grams of nitrogen dioxide would be produced during the combustion of \(500 \mathrm{~g}\) of octane.

Calcium hydride reacts with water to form calcium hydroxide and hydrogen gas. (a) Write a balanced chemical equation for the reaction. (b) How many grams of calcium hydride are needed to form \(4.500 \mathrm{~g}\) of hydrogen?

Determine the empirical formulas of the compounds with the following compositions by mass: (a) \(42.1 \% \mathrm{Na}, 18.9 \% \mathrm{P}\), and \(39.0 \% \mathrm{O}\) (b) \(18.7 \% \mathrm{Li}, 16.3 \% \mathrm{C},\) and \(65.0 \% \mathrm{O}\) (c) \(60.0 \% \mathrm{C}, 4.4 \% \mathrm{H},\) and the remainder \(\mathrm{O}\)

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