Chapter 3: Problem 108
Consider a sample of calcium carbonate in the form of a cube measuring 2.005 in. on each edge. If the sample has a density of \(2.71 \mathrm{~g} / \mathrm{cm}^{3},\) how many oxygen atoms does it contain?
Short Answer
Expert verified
The cube contains approximately \(6.458 \times 10^{24}\) oxygen atoms.
Step by step solution
01
Calculate the Volume of the Cube
To find the volume of the cube, use the formula for the volume of a cube, which is given by side\(^3\). The side length is given as 2.005 inches. First, convert inches to centimeters, knowing that 1 inch = 2.54 cm: \[\text{Side length in cm} = 2.005 \, \text{in} \times 2.54 \, \frac{\text{cm}}{\text{in}} = 5.0937 \, \text{cm}.\]Now calculate the volume: \[V = (5.0937 \, \text{cm})^3 = 132.056 \, \text{cm}^3.\]
02
Calculate the Mass of the Cube
The volume of the cube is 132.056 cm\(^3\). Using the given density \( \rho = 2.71 \, \text{g/cm}^3 \), apply the density formula \( \text{Density} = \frac{\text{Mass}}{\text{Volume}} \) to find the mass:\[\text{Mass} = \text{Density} \times \text{Volume} = 2.71 \, \text{g/cm}^3 \times 132.056 \, \text{cm}^3 = 357.874 \, \text{g}.\]
03
Calculate Moles of Calcium Carbonate
Calcium carbonate (CaCO\(_3\)) has a molar mass of roughly 100.09 g/mol. Use this to find the number of moles of CaCO\(_3\):\[\text{Moles of CaCO}_3 = \frac{357.874 \, \text{g}}{100.09 \, \text{g/mol}} = 3.577 \, \text{mol}.\]
04
Find Moles of Oxygen Atoms
Each CaCO\(_3\) molecule contains 3 oxygen atoms. Therefore, the number of moles of oxygen atoms is 3 times the moles of calcium carbonate:\[\text{Moles of O atoms} = 3 \times 3.577 \, \text{mol} = 10.731 \, \text{mol}.\]
05
Calculate the Number of Oxygen Atoms
Use Avogadro's number, \(6.022 \times 10^{23}\), to find the number of oxygen atoms:\[\text{Number of O atoms} = 10.731 \, \text{mol} \times 6.022 \times 10^{23} \text{ atoms/mol} = 6.458 \times 10^{24} \text{ atoms}.\]
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Molar Mass
Molar mass is a crucial concept in chemistry. It refers to the mass of one mole of a substance, measured in grams per mole (g/mol). For any chemical compound, like calcium carbonate (CaCO\(_3\)), calculating its molar mass involves adding up the molar masses of its constituent elements.
\[ ext{Molar mass of CaCO}_3 = 40.08 ext{ g/mol (Ca)} + 12.01 ext{ g/mol (C)} + 3 \times 16.00 ext{ g/mol (O)} = 100.09 ext{ g/mol}.\]Understanding molar mass helps in converting between grams of a substance and moles, which is essential when working with chemical reactions and formulations.
- Calcium (Ca) has a molar mass of roughly 40.08 g/mol.
- Carbon (C) has a molar mass of approximately 12.01 g/mol.
- Oxygen (O) has a molar mass of about 16.00 g/mol.
\[ ext{Molar mass of CaCO}_3 = 40.08 ext{ g/mol (Ca)} + 12.01 ext{ g/mol (C)} + 3 \times 16.00 ext{ g/mol (O)} = 100.09 ext{ g/mol}.\]Understanding molar mass helps in converting between grams of a substance and moles, which is essential when working with chemical reactions and formulations.
Density Calculation
Density is a measure that relates the mass of an object to its volume. It is calculated by the formula:
\[ ext{Density} = \frac{\text{Mass}}{\text{Volume}}\]The unit for density is often grams per cubic centimeter (g/cm³) in chemistry. In the exercise, the density of calcium carbonate is given as 2.71 g/cm³. To use this information, you must know the volume of the object, which is calculated based on its physical dimensions. For a cube, the volume is determined by the formula:
\[ ext{Volume} = ext{Side length}^3\]Once the volume of the cube is known, multiplying the volume by the density will give you the mass:
\[ ext{Density} = \frac{\text{Mass}}{\text{Volume}}\]The unit for density is often grams per cubic centimeter (g/cm³) in chemistry. In the exercise, the density of calcium carbonate is given as 2.71 g/cm³. To use this information, you must know the volume of the object, which is calculated based on its physical dimensions. For a cube, the volume is determined by the formula:
\[ ext{Volume} = ext{Side length}^3\]Once the volume of the cube is known, multiplying the volume by the density will give you the mass:
- Volume: Convert side length from inches to centimeters (using 1 inch = 2.54 cm), then cube it.
- Mass: Multiply the volume in cm³ by the density (2.71 g/cm³).
Avogadro's Number
Avogadro's number is one of the fundamental concepts in chemistry. It is the number of atoms, ions, or molecules in one mole of a substance, approximately equal to \(6.022 \times 10^{23}\). This immense number helps scientists and students count particles in measurable quantities.
When dealing with molecules like calcium carbonate (CaCO\(_3\)), knowing the number of molecules or atoms involved is crucial for stoichiometry and reaction yield calculations.
When dealing with molecules like calcium carbonate (CaCO\(_3\)), knowing the number of molecules or atoms involved is crucial for stoichiometry and reaction yield calculations.
- The exercise involved determining the number of oxygen atoms, which required knowing the moles of CaCO\(_3\).
- By multiplying the moles of oxygen atoms by Avogadro's number, you can find how many oxygen atoms are present.